Direct Restoration of Photocurable Cross-linkers for Repeated Light-based 3D Printing of Covalent Adaptable Networks DOI Creative Commons
Loc Tan Nguyen, Filip Du Prez

Materials Horizons, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Photocurable dynamic cross-linkers based on β-amino esters have been successfully synthesized. The direct restoration of such cross-linkers, enabled by a catalyst- and solvent-free protocol, is established for repeated DLP 3D printing.

Language: Английский

Recent Developments in Stimuli-Responsive Polymer for Emerging Applications: A Review DOI Creative Commons
Abdelrahman K. A. Khalil, Yeit Haan Teow, Mohd Sobri Takriff

et al.

Results in Engineering, Journal Year: 2025, Volume and Issue: unknown, P. 103900 - 103900

Published: Jan. 1, 2025

Language: Английский

Citations

7

Recyclable fire-retardant bio-based thermosets: From molecular engineering to performances and applications DOI Creative Commons
Yong Guo, Qingshan Yang, Siqi Huo

et al.

Progress in Polymer Science, Journal Year: 2025, Volume and Issue: unknown, P. 101935 - 101935

Published: March 1, 2025

Language: Английский

Citations

7

Lignin‐Based Vitrimer for High‐Resolution and Full‐Component Rapidly Recycled Liquid Metal Printed Circuit DOI

Yanfan Yang,

Yan Li, Yong Zheng

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Abstract Room‐temperature liquid metals (RTLMs) exhibit inherent fluidity, metallic conductivity, remarkable stability, and recyclability, which indicate significant potential for applications in improving the efficiency of electronics recycling reducing costs. However, low viscosity RTLMs their poor interfacial adhesion to substrates typically necessitate utilization intricate fabrication processes. Here, a viscosity‐tunable, photothermal repairable, full‐component recyclable eutectic gallium–indium/epoxy‐modified lignin/polyethylene glycol diacid/ethylene vitrimer (EGaIn‐LPEv) is presented printed circuits. The system displays good stability tunable at room temperature because ultra‐high reactive site content modified lignin dual dynamic bonding by introduction ethylene glycol. EGaIn‐LPEv‐based circuit exhibits high resolution full component recovery up 7.6 µm 98.3 wt.%, respectively. As principal component, not only enhances system's green credentials but also endows it with an efficient repairable capability. reconnection damaged can be achieved 15 s through 808 nm infrared activation. This study opens new avenue development manufacturing processes sustainable application advanced, high‐resolution, fully recycled electronic devices.

Language: Английский

Citations

3

Three-dimensional cross-linked network deep eutectic gel polymer electrolyte with the self-healing ability enable by hydrogen bonds and dynamic disulfide bonds DOI
Kai Chen, Jun Liu, Xiaorong Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 669, P. 529 - 536

Published: May 4, 2024

Language: Английский

Citations

12

Flexible multifunctional Janus film towards self-healing, self-adhesive and streachable EMI shielding DOI
Jing An,

Guiqiang Fei,

Haijian Chen

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 685, P. 1056 - 1067

Published: Jan. 23, 2025

Language: Английский

Citations

2

High-performance poly(thioctic acid)-based thermosets featuring upcycling ability for in situ foaming enabled by dual-dynamic networks DOI

Yaning Ma,

Zihan Zhao,

Zhiran Zheng

et al.

Matter, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 1, 2024

Language: Английский

Citations

7

Reversibly Cross‐Linked Plastics Meet Carbon Fibers: Closed‐Loop Recyclable Composites with Enhanced Mechanical Strength and Stability DOI Open Access
Xingyuan Lu, Liwei Guo, Yubo Wang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 24, 2025

Abstract Efficient recycling of carbon fiber‐reinforced polymer composites (CFRCs) into their original monomers and fibers (CFs) in a non‐destructive manner remains significant challenge. In this study, high‐performance, closed‐loop recyclable aromatic polyamide (APAD) plastics are synthesized via polycondensation amines aldehydes through dynamic imine bonds. Due to fully structure as well interchain hydrogen bonds π–π interactions, APAD exhibit tensile strength ≈78.3 MPa, glass transition temperature ( T g ) ≈200.4 °C, excellent chemical resistance. The can be depolymerized mixture polar organic solvents acids at ambient temperature, enabling high‐purity recovery precipitation selective solvents. Water‐resistant CF/APAD fabricated complexation with CF cloths. These mechanical properties comparable those CF/epoxy thermoset superior thermal stability. mild depolymerization conditions for enable the efficient disintegration composites. Therefore, CFs realized. recovered cloths used re‐manufacture This study presents an effective method CFRCs, offering environmental economic benefits.

Language: Английский

Citations

1

Fatigue-resistant, Self-Healable and Thermally Conductive Polyurethane Composites Based on the Intrinsic π-π stacking Interactions between Boron Nitrides and Hard Segments DOI

Pei Huan Wu,

Chao Xie,

Yun Qi Li

et al.

Materials Today Communications, Journal Year: 2025, Volume and Issue: unknown, P. 112228 - 112228

Published: March 1, 2025

Language: Английский

Citations

1

Covalent Adaptable Networks Containing Nitrogen-Coordinated Boronic Ester and Imine Bonds DOI
Yuhan Ding,

Ruoxuan Miao,

Jie Liu

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: 6(15), P. 9008 - 9016

Published: July 31, 2024

Covalent adaptable networks (CANs) are supposed to address the reprocessing and recycling issues of epoxy resins via their reversible cross-linking structures. However, development CANs simultaneously exhibiting high mechanical strength fast-reprocessing ability is still a huge challenge. Herein, with fabricated by modifying linear polymers nitrogen-coordinated boronic ester imine bonds. Owing densities rigid network structures, obtained show breaking ∼76.0 MPa, yield stress ∼81.5 Young's modulus ∼1.67 GPa, respectively. Because fast exchange reaction bonds, as-prepared can be easily processed into desirable shapes within only 1 min at 150 °C under pressure 10 MPa. Moreover, owing this unique feature, quickly reprocessed least three times without losing original properties. Finally, prepared exhibit shape fixed ratio recovery more than ∼90% when used as shape-memory polymers. This study provides feasible solution for constructing mechanically strong thermosets ability, which will contribute next-generation sustainable resins.

Language: Английский

Citations

6

Epoxy-based multifunctional re-bondable polymer with self-healing, shape memory and superb bonding properties DOI
Peixin Niu, Zhiying Zhao, Jun Zhu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 30 - 39

Published: Sept. 2, 2024

Language: Английский

Citations

6