Journal of Environmental Sciences, Journal Year: 2024, Volume and Issue: 155, P. 858 - 888
Published: Nov. 9, 2024
Language: Английский
Journal of Environmental Sciences, Journal Year: 2024, Volume and Issue: 155, P. 858 - 888
Published: Nov. 9, 2024
Language: Английский
Journal of Molecular Liquids, Journal Year: 2025, Volume and Issue: unknown, P. 127497 - 127497
Published: April 1, 2025
Language: Английский
Citations
2Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125036 - 125036
Published: Jan. 1, 2025
Language: Английский
Citations
1Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125125 - 125125
Published: Feb. 1, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160580 - 160580
Published: Feb. 1, 2025
Language: Английский
Citations
1ACS Omega, Journal Year: 2025, Volume and Issue: unknown
Published: March 25, 2025
Toluene, a highly stable aromatic hydrocarbon, is utilized as benchmark molecule for thermal mineralization by the catalytic community. Mostly, catalysts used toluene either use platinum group metals (PGM) or are regulated plasma incinerator. Though these catalysts/processes promise better efficiency and lower reaction temperature, they neither cost-effective nor do produce thermally byproducts. However, most of metal-oxide degradation less efficient owing to incomplete formation intermediates, which results in higher temperature. The present work showcases tungsten- molybdenum-based Scheelites [BaXO4 (X = W, Mo, Mo0.5W0.5)], have been at ∼200 °C. intermediates formed during adsorption deciphered function temperature using situ FT-IR studies including their kinetic behavior. These surface over Scheelite under an oxidative/inert atmosphere elucidate mechanism temperature/time. active sites oxide both detailed X-ray photoelectron spectroscopy (XPS) studies. It shows effective role oxidation states constituent oxides M-O (M Mo/ W) mechanism. Mineralization nonoxidative Mars Van Krevelen (MVK) type mechanism, suggesting participation lattice oxygen reaction. To best our knowledge, this represents one lowest temperatures achieved catalysts. identification can guide further optimization efforts minimize
Language: Английский
Citations
1Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 480, P. 136111 - 136111
Published: Oct. 22, 2024
Language: Английский
Citations
5Renewable Energy, Journal Year: 2024, Volume and Issue: unknown, P. 121428 - 121428
Published: Sept. 1, 2024
Language: Английский
Citations
3Langmuir, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 21, 2025
Mass transfer governs the overall catalytic performance of heterogeneous catalysts considerably; however, this fundamental research has often been ignored. Here, macroporous SiO2-supported Pt nanoparticle (Pt/SiO2-M) and mesoporous (Pt/SiO2-m) were specifically fabricated by a facile thermal reduction step to engineer resultant nanoparticles showing similar physiochemical properties while possessing completely different porous microstructures exclusively originating from SiO2 supports. On basis, platform explore crucial mass difference affecting activity is then established systematically practicing industry-important benzene oxidation measurements. State-of-the-art characterization techniques confirmed that all as-synthesized Pt/SiO2 indeed exhibited almost identical sites, excluding discrepancies raised nanoparticles. Importantly, Pt/SiO2-M displayed complete capabilities at lower temperature than for Pt/SiO2-m, accrediting macroporosity-induced faster desorption rate H2O CO2, thus making it capable enhancing high utilization sites. This work highlights importance improving capability toward supported nanoparticulate catalysts, demonstrating significance designing novel supports catalysis implications.
Language: Английский
Citations
0ACS ES&T Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 21, 2025
Language: Английский
Citations
0Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 116643 - 116643
Published: April 1, 2025
Language: Английский
Citations
0