Journal of the American Chemical Society,
Journal Year:
2022,
Volume and Issue:
144(11), P. 4699 - 4715
Published: March 9, 2022
Stretchable
polymer
semiconductors
have
advanced
rapidly
in
the
past
decade
as
materials
required
to
realize
conformable
and
soft
skin-like
electronics
become
available.
Through
rational
molecular-level
design,
stretchable
semiconductor
films
are
now
able
retain
their
electrical
functionalities
even
when
subjected
repeated
mechanical
deformations.
Furthermore,
charge-carrier
mobilities
on
par
with
best
flexible
semiconductors,
some
exceeding
that
of
amorphous
silicon.
The
key
advancements
molecular-design
concepts
allow
multiple
strain
energy-dissipation
mechanisms,
while
maintaining
efficient
charge-transport
pathways
over
length
scales.
In
this
perspective
article,
we
review
recent
approaches
confer
stretchability
high
charge
carrier
mobilities,
emphasis
control
both
polymer-chain
dynamics
thin-film
morphology.
Additionally,
present
molecular
design
considerations
toward
intrinsically
elastic
needed
for
reliable
device
operation
under
reversible
deformation.
A
general
approach
involving
inducing
nanoconfinement
allows
incorporation
several
other
desired
functionalities,
such
biodegradability,
self-healing,
photopatternability,
enhancing
transport.
Lastly,
point
out
future
directions,
including
advancing
fundamental
understanding
morphology
evolution
its
correlation
change
transport
strain,
needs
strain-resilient
mobility
retention.
Scientific Reports,
Journal Year:
2020,
Volume and Issue:
10(1)
Published: Feb. 12, 2020
Abstract
Facile
fabrication
and
high
ambient
stability
are
strongly
desired
for
the
practical
application
of
temperautre
sensor
in
real-time
wearable
healthcare.
Herein,
a
fully
printed
flexible
temperature
based
on
cross-linked
poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)
(PEDOT:PSS)
was
developed.
By
introducing
crosslinker
(3-glycidyloxypropyl)trimethoxysilane
(GOPS)
fluorinated
polymer
passivation
(CYTOP),
significant
enhancements
humidity
sensitivity
PEDOT:PSS
film
were
achieved.
The
prepared
exhibited
excellent
environmental
ranged
from
30%
RH
to
80%
RH,
−0.77%
°C
−1
sensing
between
25
50
°C.
Moreover,
wireless
platform
obtained
by
integrating
hybrid
circuit,
which
performed
stable
healthcare
monitoring.
Materials Chemistry Frontiers,
Journal Year:
2020,
Volume and Issue:
4(11), P. 3130 - 3152
Published: Jan. 1, 2020
Recent
progress
on
PEDOT:PSS
composites
by
incorporating
various
polymers
and
fillers
through
blending
mixing
methods
main
focus
is
put
onto
the
electrical
conductivity,
stretchability
thermoelectric
properties.
Advanced Functional Materials,
Journal Year:
2020,
Volume and Issue:
31(11)
Published: Dec. 18, 2020
Abstract
The
progressive
development
of
flexible
transparent
portable
electronic
devices
is
in
urgent
need
matching
power
sources.
Flexible
supercapacitors
(FTSCs)
are
the
core
resources
due
to
their
high
optical
transmittance,
endurable
mechanical
flexibility,
excellent
electrochemical
performance,
and
facilely
accessible
device
configuration.
This
review
organizes
rational
design
nanostructured
electrode
materials
toward
FTSCs.
First,
structure,
mechanism,
property
FTSCs
introduced.
Then,
principles
diverse
discussed
achieve
conductive
electrodes
(FTCEs)
with
different
figure
merits
(both
electrical
FoMe
capacitive
FoMc),
strength,
environmental
stability.
Following
achievements
multifunctional
focusing
on
film‐supercapacitors,
micro‐supercapacitors,
electrochromic
supercapacitors,
photo‐supercapacitors,
battery‐like
also
highlighted.
Finally,
current
challenges
future
perspectives
viable
construction
electronics
outlined.
Advanced Materials,
Journal Year:
2022,
Volume and Issue:
34(44)
Published: June 30, 2022
Abstract
Hole‐transporting
layers
(HTLs)
are
an
essential
component
in
inverted,
p–i–n
perovskite
solar
cells
(PSCs)
where
they
play
a
decisive
role
extraction
and
transport
of
holes,
surface
passivation,
crystallization,
device
stability,
cost.
Currently,
the
exploration
efficient,
stable,
highly
transparent
low‐cost
HTLs
is
vital
importance
for
propelling
PSCs
toward
commercialization.
Compared
to
their
inorganic
counterparts,
organic
offer
multiple
advantages
such
as
tunable
bandgap
energy
level,
easy
synthesis
purification,
solution
processability,
overall
low
Here,
recent
progress
HTLs,
including
conductive
polymers,
small
molecules,
self‐assembled
monolayers,
utilized
inverted
systematically
reviewed
summarized.
Their
molecular
structure,
hole‐transport
properties,
levels,
relevant
properties
resulting
performances
presented
analyzed.
A
summary
design
principles
future
outlook
efficient
proposed.
This
review
aims
inspire
further
innovative
development
novel
more
scalable
PSCs.
Journal of the American Chemical Society,
Journal Year:
2022,
Volume and Issue:
144(11), P. 4699 - 4715
Published: March 9, 2022
Stretchable
polymer
semiconductors
have
advanced
rapidly
in
the
past
decade
as
materials
required
to
realize
conformable
and
soft
skin-like
electronics
become
available.
Through
rational
molecular-level
design,
stretchable
semiconductor
films
are
now
able
retain
their
electrical
functionalities
even
when
subjected
repeated
mechanical
deformations.
Furthermore,
charge-carrier
mobilities
on
par
with
best
flexible
semiconductors,
some
exceeding
that
of
amorphous
silicon.
The
key
advancements
molecular-design
concepts
allow
multiple
strain
energy-dissipation
mechanisms,
while
maintaining
efficient
charge-transport
pathways
over
length
scales.
In
this
perspective
article,
we
review
recent
approaches
confer
stretchability
high
charge
carrier
mobilities,
emphasis
control
both
polymer-chain
dynamics
thin-film
morphology.
Additionally,
present
molecular
design
considerations
toward
intrinsically
elastic
needed
for
reliable
device
operation
under
reversible
deformation.
A
general
approach
involving
inducing
nanoconfinement
allows
incorporation
several
other
desired
functionalities,
such
biodegradability,
self-healing,
photopatternability,
enhancing
transport.
Lastly,
point
out
future
directions,
including
advancing
fundamental
understanding
morphology
evolution
its
correlation
change
transport
strain,
needs
strain-resilient
mobility
retention.
