Synergistic Polarization Loss of MoS2‐Based Multiphase Solid Solution for Electromagnetic Wave Absorption DOI
Zhenguo Gao, Zhenhui Ma, Di Lan

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(18)

Published: Jan. 24, 2022

Abstract Given tunable hybridization structures in solid solutions, fascinating electromagnetic (EM) properties can be achieved for regulating EM wave (EMW) absorption. Herein, a novel metal–organic cooperative interactions method is proposed to manipulate the vacancy, interstitial, substitutional, and heterointerface molybdenum disulfide (MoS 2 ) solution simultaneously, thence meeting synergistic polarization loss on various point face sites. Assisted by coordination between Cu 2+ polydopamine (PDA), effect of modification MoS highly improved, which further lead S interstitial Cu, substitutional N, carbon . Contributing synergetic among multiple polarizations, Cu/C@MoS exhibit ultrahigh EMW absorption performance, EMA with twice PDA delivers effective bandwidth 7.12 GHz minimum reflection −48.22 dB (2.5 mm). The energy attenuation improved almost 266.7% 222.2% than C@MoS Cu@MoS , respectively. Finally, this work reveals structural dependency materials establishes an entirely new model.

Language: Английский

Dielectric Loss Mechanism in Electromagnetic Wave Absorbing Materials DOI Creative Commons
Ming Qin, Limin Zhang, Hongjing Wu

et al.

Advanced Science, Journal Year: 2022, Volume and Issue: 9(10)

Published: Feb. 7, 2022

Electromagnetic (EM) wave absorbing materials play an increasingly important role in modern society for their multi-functional military stealth and incoming 5G smart era. Dielectric loss EM absorbers underlying mechanism investigation are of great significance to unveil attenuation behaviors guide novel dielectric design. However, current researches focus more on synthesis rather than in-depth study. Herein, comprehensive views toward mechanisms including interfacial polarization, dipolar conductive loss, defect-induced polarization provided. Particularly, some misunderstandings ambiguous concepts each highlighted. Besides, study emphasized. Moreover, new regulation strategies instead regular components compositing summarized provide inspiring thoughts simple effective behavior modulation.

Language: Английский

Citations

891

Dimensional Design and Core–Shell Engineering of Nanomaterials for Electromagnetic Wave Absorption DOI

Zhengchen Wu,

Han‐Wen Cheng, Chen Jin

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 34(11)

Published: Nov. 10, 2021

Abstract Electromagnetic (EM) wave absorption materials possess exceptionally high EM energy loss efficiency. With vigorous developments in nanotechnology, such have exhibited numerous advanced functions, including radiation prevention and antiradar stealth. To achieve improved performance multifunctionality, the elaborate control of microstructures has become an attractive research direction. By designing them as core–shell structures with different dimensions, combined effects, interfacial polarization, conduction networks, magnetic coupling, magnetic–dielectric synergy, can significantly enhance performance. Herein, advances low‐dimensional are outlined a selection most remarkable examples is discussed. The derived key information regarding dimensional design, structural engineering, performance, structure–function relationship comprehensively summarized. Moreover, investigation cutting‐edge mechanisms given particular attention. Additional applications, oxidation resistance self‐cleaning also introduced. Finally, insight into what may be expected from this rapidly expanding field future challenges presented.

Language: Английский

Citations

817

Heterointerface Engineering in Electromagnetic Absorbers: New Insights and Opportunities DOI
Liang Leilei, Weihua Gu, Yue Wu

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 34(4)

Published: Oct. 4, 2021

Electromagnetic (EM) absorbers play an increasingly essential role in the electronic information age, even toward coming "intelligent era". The remarkable merits of heterointerface engineering and its peculiar EM characteristics inject a fresh infinite vitality for designing high-efficiency stimuli-responsive absorbers. However, there still exist huge challenges understanding reinforcing these interface effects from micro macro perspectives. Herein, response mechanisms interfacial are dissected depth, with focus on advanced characterization as well theoretical techniques. Then, representative optimization strategies systematically discussed emphasis component selection structural design. More importantly, most cutting-edge smart functional devices based reported. Finally, current concrete suggestions proposed, future perspectives this promising field also predicted.

Language: Английский

Citations

519

Environmentally Friendly and Multifunctional Shaddock Peel-Based Carbon Aerogel for Thermal-Insulation and Microwave Absorption DOI Creative Commons
Weihua Gu,

Jiaqi Sheng,

Qianqian Huang

et al.

Nano-Micro Letters, Journal Year: 2021, Volume and Issue: 13(1)

Published: April 5, 2021

Highlights The eco-friendly shaddock peel-derived carbon aerogels were prepared by a freeze-drying method. Multiple functions such as thermal insulation, compression resistance and microwave absorption can be integrated into one material-carbon aerogel. Novel computer simulation technology strategy was selected to simulate significant radar cross-sectional reduction values under real far field condition. . Abstract Eco-friendly electromagnetic wave absorbing materials with excellent infrared stealth property, heat-insulating ability are highly attractive in practical applications. Meeting the aforesaid requirements simultaneously is formidable challenge. Herein, ultra-light fabricated via fresh peel facile method calcination process, forming porous network architecture. With heating platform temperature of 70 °C, upper surface temperatures as-prepared aerogel present slow upward trend. color sample images similar that surroundings. maximum compressive stress 2.435 kPa, provide favorable endurance. peel-based possess minimum reflection loss value ( RL min ) − 29.50 dB X band. Meanwhile, effective bandwidth covers 5.80 GHz at relatively thin thickness only 1.7 mm. detection theta 0°, (RCS) 16.28 m 2 achieved. Theoretical simulations RCS have aroused extensive interest owing their ingenious design time-saving feature. This work paves way for preparing multi-functional absorbers derived from biomass raw guidance simulations.

Language: Английский

Citations

444

A Review on Graphene‐Based Electromagnetic Functional Materials: Electromagnetic Wave Shielding and Absorption DOI

Yuxing Xia,

Weiwei Gao, Chao Gao

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(42)

Published: July 1, 2022

Abstract Electromagnetic (EM) functional materials play an increasingly important role in solving EM wave pollution both modern military and civil fields. Graphene‐based are the most promising candidates applications of shielding absorption owing to their remarkable structures enhanced properties. Designing graphene‐based with elaborately controlled microstructures optimized properties can effectively improve energy attenuation conversion. Herein, study begins mechanism, multiscale design strategies outlined, including molecular‐scale, micro/nanoscale structure, macroscale integration assembly strategies. Applications fields reviewed, focusing on latest advances assemblies such as films, fabrics, composites. Finally, current challenges future directions this fast‐growing field predicted.

Language: Английский

Citations

439

Diverse Metal–Organic Framework Architectures for Electromagnetic Absorbers and Shielding DOI

Jin‐Cheng Shu,

Wen‐Qiang Cao, Mao‐Sheng Cao

et al.

Advanced Functional Materials, Journal Year: 2021, Volume and Issue: 31(23)

Published: March 24, 2021

Abstract Metal–organic frameworks (MOFs) and their derivatives, featuring unique 3D microstructures enhanced electromagnetic properties, are illuminating infinite possibilities for functional materials devices, receiving significant attention from domestic foreign researchers. Herein, the design strategy of MOF monomer is investigated, response mechanism systematically analyzed. Research emphatically introduced regarding MOF‐based in microwave absorption interference shielding. Finally, a clear insight on quickly growing field given, current challenges future research directions summarized predicted.

Language: Английский

Citations

395

Recent progress on carbon-based composite materials for microwave electromagnetic interference shielding DOI
Rajesh Kumar, Sumanta Sahoo, Ednan Joanni

et al.

Carbon, Journal Year: 2021, Volume and Issue: 177, P. 304 - 331

Published: March 2, 2021

Language: Английский

Citations

342

Lightweight Ni Foam‐Based Ultra‐Broadband Electromagnetic Wave Absorber DOI
Ming Qin, Limin Zhang, Xiaoru Zhao

et al.

Advanced Functional Materials, Journal Year: 2021, Volume and Issue: 31(30)

Published: May 18, 2021

Abstract Skin effect and high density are the main reasons that restrict search of lightweight high‐performance metal‐based electromagnetic (EM) wave absorbing materials. Although nanostructured metal materials have been fabricated to solve above problems, poor dispersibility chemical stability issues brought about by surface energy due existing nano‐size effect. In this work, Ni foam with NiO/NiFe 2 O 4 in situ growth composites a facile universal route as an effective alternative EM absorber. Impressively, it is found structure /Ni components can synergistically boost absorption capacity. detail, impedance matching from dissipation interfacial polarization defect induced provided mainly contributes its ultra‐broadband performance. As result, as‐prepared sample (0.06 g·cm −3 ) delivers wide bandwidth 14.24 GHz thin thickness 0.6 mm, well as, specific 19444.4 GHz·g −1 ·cm −2 . This work sheds light on novel view synergistic behaviors demonstrates new pathway for preparation absorbers.

Language: Английский

Citations

333

Growth of NiAl‐Layered Double Hydroxide on Graphene toward Excellent Anticorrosive Microwave Absorption Application DOI

Xuefei Xu,

Shaohua Shi,

Yulin Tang

et al.

Advanced Science, Journal Year: 2021, Volume and Issue: 8(5)

Published: Jan. 6, 2021

High-performance microwave absorbers with special features are desired to meet the requirements of more complex modern service environments, especially corrosive environments. Therefore, high-efficiency corrosion resistance should be developed urgently. Herein, a 3D NiAl-layered double hydroxide/graphene (NiAl-LDH/G) composite synthesized by atomic-layer-deposition-assisted in situ growth is presented as an anticorrosive absorber. The content NiAl-LDH optimized achieve impedance matching. Furthermore, under cooperative effects interface polarization loss, conduction and porous sandwich-like structure, optimal NiAl-LDH/G shows excellent absorption performance minimum reflection loss -41.5 dB maximum effective bandwidth 4.4 GHz at loading only 7 wt% epoxy. Remarkably, encapsulation effect can restrain galvanic owing graphene. epoxy coating absorber on carbon steel exhibits long-term resistance, synergetic superior impermeability graphene chloridion-capture capacity NiAl-LDH. promising absorber, findings this study may motivate development functional that demands coatings.

Language: Английский

Citations

314

A Nano-Micro Engineering Nanofiber for Electromagnetic Absorber, Green Shielding and Sensor DOI Creative Commons
Min Zhang, Han Chen, Wen‐Qiang Cao

et al.

Nano-Micro Letters, Journal Year: 2020, Volume and Issue: 13(1)

Published: Nov. 20, 2020

Highlights The role of electron transport characteristics in electromagnetic (EM) attenuation can be generalized to other EM functional materials. integrated functions efficient absorption and green shielding open the view multifunctional A novel sensing mechanism based on intrinsic performance resonance coupling effect is revealed. Abstract It extremely unattainable for a material simultaneously obtain performance, which has not been reported due competition between conduction loss reflection. Herein, by tailoring internal structure through nano-micro engineering, NiCo 2 O 4 nanofiber with absorbing as well strain obtained. With improvement charge capability nanofiber, converted from shielding, or even coexist. Particularly, conductivity rising, reflection declines − 52.72 10.5 dB, while interference effectiveness increases 13.4 suggesting coexistence two functions. Furthermore, high absorption, sensor designed patterned structure. These strategies tuning constructing devices extended materials promote development driven devices. Graphic

Language: Английский

Citations

258