Rational Design of Electrode–Electrolyte Interphase and Electrolytes for Rechargeable Proton Batteries DOI Creative Commons
Zhen Su, Haocheng Guo, Chuan Zhao

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: April 10, 2023

Abstract Rechargeable proton batteries have been regarded as a promising technology for next-generation energy storage devices, due to the smallest size, lightest weight, ultrafast diffusion kinetics and negligible cost of charge carriers. Nevertheless, battery possessing both high power density is yet achieved. In addition, poor cycling stability another major challenge making lifespan unsatisfactory. These issues motivated extensive research into electrode materials. Nonetheless, design electrode–electrolyte interphase electrolytes underdeveloped solving challenges. this review, we summarize development elaborate on their importance in enhancing density, lifespan. The fundamental understanding reviewed with respect desolvation process, interfacial reaction kinetics, solvent-electrode interactions, analysis techniques. We categorize currently used according physicochemical properties analyze electrochemical potential window, solvent (e.g., water) activities, ionic conductivity, thermal stability, safety. Finally, offer our views challenges opportunities toward future achieving high-performance storage.

Language: Английский

Multi‐Ion Engineering Strategies toward High Performance Aqueous Zinc‐Based Batteries DOI

Jiasheng Yue,

Shi Chen, Jingjing Yang

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(2)

Published: July 18, 2023

Abstract As alternatives to batteries with organic electrolytes, aqueous zinc‐based (AZBs) have been intensively studied. However, the sluggish kinetics, side reactions, structural collapse, and dissolution of cathode severely compromise commercialization AZBs. Among various strategies accelerate their practical applications, multi‐ion engineering shows great feasibility maintain original structure provide sufficient energy density for high‐performance Though could solve most problems encountered by AZBs show potential in achieving AZBs, comprehensive summaries undergo electrochemical reactions involving more than one charge carrier is still deficiency. The ambiguous nomenclature classification are becoming fountainhead confusion chaos. In this circumstance, review overviews all battery configurations corresponding reaction mechanisms investigated batteries. By combing through reported works, first nomenclate different according additional ions, laying foundation future unified discussions. performance enhancement, fundamental challenges, developing direction accordingly proposed, aiming further pace achieve high performance.

Language: Английский

Citations

58
Recent progress of dendrite‐free stable zinc anodes for advanced zinc‐based rechargeable batteries: Fundamentals, challenges, and perspectives DOI Creative Commons
Xiao Wang,

Chenglin Sun,

Zhong‐Shuai Wu

et al.

SusMat, Journal Year: 2023, Volume and Issue: 3(2), P. 180 - 206

Published: March 2, 2023

Abstract Zinc‐based batteries are a very promising class of next‐generation electrochemical energy storage systems, with high safety, eco‐friendliness, abundant resources, and the absence rigorous manufacturing conditions. However, practical applications zinc‐based rechargeable impeded by low Coulombic efficiency, inferior cyclability, poor rate capability, due to instability zinc anode. Herein, effective strategies for dendrite‐free anode symmetrically reviewed, especially highlighting specific mechanisms, delicate design electrode current collectors, controlled electrode|electrolyte interface, ameliorative electrolytes, advanced separators design. First, particular mechanisms dendrites formation associated fundamentals stable Zn metal anodes presented elaborately. Then, recent key prevention hydrogen evolution reaction suppression categorized, discussed, analyzed in detail view electrodes, separators. Finally, challenging perspectives major directions briefly discussed further industrialization commercialization batteries.

Language: Английский

Citations

56
Recent Advances in Structural Optimization and Surface Modification on Current Collectors for High-Performance Zinc Anode: Principles, Strategies, and Challenges DOI Creative Commons
Yuxin Gong, Bo Wang, Huaizheng Ren

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: Aug. 31, 2023

The last several years have witnessed the prosperous development of zinc-ion batteries (ZIBs), which are considered as a promising competitor energy storage systems thanks to their low cost and high safety. However, reversibility availability this system blighted by problems such uncontrollable dendritic growth, hydrogen evolution, corrosion passivation on anode side. A functionally structurally well-designed current collectors (CCs) is believed viable solution for those problems, with lack summarization according its working mechanisms. Herein, review focuses challenges zinc mechanisms modified CCs, can be divided into zincophilic modification, structural design, steering preferred crystal facet orientation. possible prospects directions research design proposed at end hopefully promote practical application ZIBs.

Language: Английский

Citations

48
Polymers for Aqueous Zinc‐Ion Batteries: From Fundamental to Applications Across Core Components DOI

Ben Niu,

Jia Wang,

Yalan Guo

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(12)

Published: Feb. 19, 2024

Abstract Aqueous zinc‐ion batteries (AZIBs) comprising zinc anodes hold intrinsic safety and high energy density ideally for distributed large‐scale storage, thus have generated intriguing properties increasing research interests. Unlike organic batteries, AZIBs require different, sometimes even opposite design principles preparation strategies in solvent, electrolyte, separator. This is especially true the polymer materials that are widely used as critical components stabilizing metal functioning high‐performance safe cathode materials. review discusses explicit compositional structural requisite of polymeric AZIBs, with an emphasis on exclusive molecular structure–property relationship governs stability, reversibility, capacity these devices. The usage polymers classified into five categories aligning primary architecture AZIBs: separators, additives, hydrogel electrolytes, coatings, electrode most recent advances structure/property interplay by novel synthesis techniques targeting stable summarized discussed. challenges perspectives multifunctional developing also proposed.

Language: Английский

Citations

38
Metal organic framework-based cathode materials for aqueous zinc-ion batteries: Recent advances and perspectives DOI
Xiudong Chen,

Jin‐Hang Liu,

Huixiong Jiang

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 65, P. 103168 - 103168

Published: Jan. 6, 2024

Language: Английский

Citations

36
Recent Advances in Functional Cellulose-Based Materials: Classification, Properties, and Applications DOI

Yijia Deng,

Tianxue Zhu,

Yan Cheng

et al.

Advanced Fiber Materials, Journal Year: 2024, Volume and Issue: 6(5), P. 1343 - 1368

Published: June 26, 2024

Language: Английский

Citations

32
Hydrophilic‐Zincophobic Separator Enabling by Crystal Structure Regulation toward Stabilized Zn Metal Anode DOI

Shujun Lv,

Mingyu Su,

Zhuo Li

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(27)

Published: March 4, 2024

Abstract Aqueous zinc‐ion batteries (ZIBs) hold significant promise for large‐scale energy storage. While considerable strides have been made in modifying separators, the challenge of developing dendrite‐free, corrosion‐resistant, and cost‐effective separators achieving extended cycling performance Zn anodes persists. In light this, a TiO 2 coating separator to mitigate interfacial corrosion passivation reactions, thereby facilitating high‐performance ZIBs is designed. This study delves into influence loading amount crystal phase layers on modification. symmetric cells employing anatase ‐modified glass fiber (A‐TiO @GF) demonstrate superior 2+ ion transport kinetics mild ZnSO 4 electrolyte, ensuring sustained long‐term stability uniform deposition. Furthermore, reduced hydrogen evolution reaction (HER) activity A‐TiO coatings curbs H + migration, minimizing HER. Consequently, assembled Zn||CaV 8 O 20 full outstanding durability impressive specific capacity, boasting discharge capacity 142 mAh g −1 after 1000 cycles. work introduces straightforward interface engineering strategy creating efficient batteries, promoting

Language: Английский

Citations

28
Maintaining the concentration equilibrium of proton and hydroxide ions by construction of bis(2-aminoethyl)amine-based inner helmholtz plane toward long-life zinc metal anodes DOI
Zhijian Wang,

Zuyang Hu,

Minghui Ye

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 481, P. 148511 - 148511

Published: Jan. 4, 2024

Language: Английский

Citations

21
Blocking the passivation reaction via localized acidification and cation selective interface towards highly stable zinc anode DOI
Jingjing Yang, Ran Zhao, Zhifan Hu

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103449 - 103449

Published: May 10, 2024

Language: Английский

Citations

16
Zinc‐Ion Battery Chemistries Enabled by Regulating Electrolyte Solvation Structure DOI Creative Commons
Wenjing Deng, Ge Li, Xiaolei Wang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: May 11, 2024

Abstract Designing next‐generation alternative energy storage devices that feature high safety, low cost, and long operation lifespan is of the utmost importance for future wide range applications. Aqueous zinc‐ion batteries play a vital part in promoting development portability, sustainability, diversification rechargeable battery systems. Based on theory electrolyte solvation chemistry, deep understanding interaction between components their impact chemical properties has achieved series research progress. Analyzing shell or structure–performance relationship, establishing more stable high‐energy chemistries are inevitable requirements to suppress electrolyte–electrode interphase side reaction realize functional use batteries. In this critical review, attempt overview current comprehension regarding structure zinc technology. Advanced methodology toward interactions cations, solvent molecules, anions aqueous electrolytes general rules design from atomic level summarized. Methods viable modification then introduced overcoming remained challenges transferring laboratory results practical Possible direction with aim investigating ultimate choice high‐performance construction also outlined.

Language: Английский

Citations

16