ACS Applied Materials & Interfaces,
Journal Year:
2024,
Volume and Issue:
16(6), P. 7826 - 7837
Published: Feb. 1, 2024
Conductive
hydrogels
have
garnered
significant
interest
in
the
realm
of
wearable
flexible
sensors
due
to
their
close
resemblance
human
tissue,
wearability,
and
precise
signal
acquisition
capabilities.
However,
concurrent
attainment
an
epidermal
hydrogel
sensor
incorporating
reliable
self-healing
capabilities,
biodegradability,
robust
adhesiveness,
ability
precisely
capture
subtle
electrophysiological
signals
poses
a
daunting
intricate
challenge.
Herein,
innovative
MXene-based
composite
(PBM
hydrogel)
with
exceptional
self-healing,
self-adhesive,
versatile
functionality
is
engineered
through
integration
conductive
MXene
nanosheets
into
well-structured
poly(vinyl
alcohol)
(PVA)
bacterial
cellulose
(BC)
three-dimensional
(3D)
network,
utilizing
multiple
dynamic
cross-linking
synergistic
repeated
freeze–thaw
strategy.
The
harnesses
presence
dynamically
reversible
borax
ester
bonds
hydrogen
between
its
constituents,
endowing
it
rapid
efficiency
(97.8%)
formidable
self-adhesive
capability.
assembled
PBM
possesses
response
time
(10
ms)
exhibits
versatility
detecting
diverse
external
stimuli
movements
such
as
vocalization,
handwriting,
joint
motion,
Morse
code
signals,
even
monitoring
infusion
status.
Additionally,
offers
added
advantage
swift
degradation
phosphate-buffered
saline
solution
(within
span
56
days)
H2O2
(in
just
53
min),
maintaining
eco-friendly
profile
devoid
any
environmental
pollution.
This
work
lays
groundwork
for
possible
uses
electronic
skins,
interactions
humans
machines,
individualized
healthcare.
Small,
Journal Year:
2023,
Volume and Issue:
19(27)
Published: March 25, 2023
Abstract
Due
to
their
potential
applications
in
physiological
monitoring,
diagnosis,
human
prosthetics,
haptic
perception,
and
human–machine
interaction,
flexible
tactile
sensors
have
attracted
wide
research
interest
recent
years.
Thanks
the
advances
material
engineering,
high
performance
been
obtained.
Among
representative
pressure
sensing
materials,
2D
layered
nanomaterials
many
properties
that
are
superior
those
of
bulk
more
suitable
for
sensors.
As
a
class
inorganic
compounds
materials
science,
MXene
has
excellent
electrical,
mechanical,
biological
compatibility.
MXene‐based
composites
proven
be
promising
candidates
due
stretchability
metallic
conductivity.
Therefore,
great
efforts
devoted
development
sensor
applications.
In
this
paper,
controllable
preparation
characterization
introduced.
Then,
progresses
on
fabrication
strategies,
operating
mechanisms,
device
composite‐based
sensors,
including
piezoresistive
capacitive
piezoelectric
triboelectric
reviewed.
After
that,
material‐based
electronics
motion
healthcare,
artificial
intelligence
discussed.
Finally,
challenges
perspectives
summarized.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(24)
Published: Feb. 21, 2024
In
the
past
decade,
with
rapid
development
of
wearable
electronics,
medical
health
monitoring,
Internet
Things,
and
flexible
intelligent
robots,
pressure
sensors
have
received
unprecedented
attention.
As
a
very
important
kind
electronic
component
for
information
transmission
collection,
gained
wide
application
prospect
in
fields
aerospace,
biomedical
skin,
human-machine
interface.
recent
years,
MXene
has
attracted
extensive
attention
because
its
unique
2D
layered
structure,
high
conductivity,
rich
surface
terminal
groups,
hydrophilicity,
which
brought
new
breakthrough
sensing.
Thus,
it
become
revolutionary
pressure-sensitive
material
great
potential.
this
work,
advances
MXene-based
are
reviewed
from
aspects
sensing
type,
mechanism,
selection,
structural
design,
preparation
strategy,
application.
The
methods
strategies
to
improve
performance
analyzed
details.
Finally,
opportunities
challenges
faced
by
discussed.
This
review
will
bring
research
level,
promoting
wider
exploitation
practical
materials
sensors.
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
33(15)
Published: Jan. 29, 2023
Abstract
Electronic
skins
(e‐skins),
which
are
mechanically
compliant
with
human
skin,
regarded
as
ideal
electronic
devices
for
noninvasive
human–machine
interaction
and
wearable
devices.
In
order
to
fully
mimic
e‐skins
should
possess
reliable
mechanical
properties
be
able
resist
external
environmental
factors
like
heat,
cold,
desiccation,
bacteria,
while
perceiving
multiple
stimuli,
such
temperature,
humidity,
strain.
Here,
a
transparent,
robust,
environmentally
stable,
versatile
natural
skin‐derived
organohydrogel
(NSD‐Gel)
is
nanoengineered
through
the
integration
of
betaine,
silver
nanoparticles,
sodium
chloride
in
glycerol/water
binary
solvent.
The
transparent
NSD‐Gel
e‐skin
exhibits
outstanding
tensile
strength
(7.33
MPa),
puncture
resistance,
moisture
retention,
self‐regeneration,
antibacterial
properties.
Additionally,
possesses
enhanced
cold/heat
resistance
stimuli‐responsive
characteristics
that
effectively
sense
temperature
humidity
changes,
well
physiological
body
motion
signals.
vitro
vivo
experiments
show
confers
desired
biocompatibility
tissue
protective
even
extremely
harsh
environments
(−196
°C
100
°C).
has
great
potential
applications
multidimensional
devices,
human‐machine
interfaces,
artificial
intelligence,
generating
platform
development
high‐performance
on‐demand
Bioactive Materials,
Journal Year:
2022,
Volume and Issue:
22, P. 1 - 17
Published: Sept. 23, 2022
The
electrical
microenvironment
plays
an
important
role
in
bone
repair.
However,
the
underlying
mechanism
by
which
stimulation
(ES)
promotes
regeneration
remains
unclear,
limiting
design
of
microenvironment-specific
electroactive
materials.
Herein,
simple
co-incubation
aqueous
suspensions
at
physiological
temperatures,
biocompatible
regenerated
silk
fibroin
(RSF)
is
found
to
assemble
into
nanofibrils
with
a
β-sheet
structure
on
MXene
nanosheets,
has
been
reported
inhibit
restacking
and
oxidation
MXene.
An
hydrogel
based
RSF
bioencapsulated
thus
prepared
promote
efficient
regeneration.
This
MXene/RSF
also
acts
as
piezoresistive
pressure
transducer,
can
potentially
be
utilized
monitor
electrophysiological
microenvironment.
RNA
sequencing
performed
explore
mechanisms,
activate
Ca2+/CALM
signaling
favor
direct
osteogenesis
process.
ES
facilitate
indirect
promoting
polarization
M2
macrophages,
well
stimulating
neogenesis
migration
endotheliocytes.
Consistent
improvements
angiogenesis
are
observed
hydrogels
under
vivo.
Collectively,
provides
distinctive
promising
strategy
for
osteogenesis,
regulating
immune
neovascularization
ES,
leading
re-establish
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
36(11)
Published: Dec. 14, 2023
Human-machine
interaction
(HMI)
technology
shows
an
important
application
prospect
in
rehabilitation
medicine,
but
it
is
greatly
limited
by
the
unsatisfactory
recognition
accuracy
and
wearing
comfort.
Here,
this
work
develops
a
fully
flexible,
conformable,
functionalized
multimodal
HMI
interface
consisting
of
hydrogel-based
sensors
self-designed
flexible
printed
circuit
board.
Thanks
to
component
regulation
structural
design
hydrogel,
both
electromyogram
(EMG)
forcemyography
(FMG)
signals
can
be
collected
accurately
stably,
so
that
they
are
later
decoded
with
assistance
artificial
intelligence
(AI).
Compared
traditional
multichannel
EMG
signals,
human-machine
method
based
on
combination
FMG
significantly
improves
efficiency
increasing
information
entropy
signals.
The
decoding
from
only
two
channels
for
different
gestures
reaches
91.28%.
resulting
AI-powered
active
system
control
pneumatic
robotic
glove
assist
stroke
patients
completing
movements
according
recognized
human
motion
intention.
Moreover,
further
generalized
applied
other
remote
sensing
platforms,
such
as
manipulators,
intelligent
cars,
drones,
paving
way
future
robot
systems.
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
33(21)
Published: Feb. 26, 2023
Abstract
Conductive
hydrogel‐based
epidermal
sensors
are
regarded
with
broad
prospects
in
bridging
the
gap
between
human
and
machine
for
personalized
healthcare.
However,
it
is
still
challenging
to
simultaneously
achieve
high
sensitivity,
wide
sensing
range,
reliable
cycling
stability
ultrasensitive
human–machine
interfacing,
along
brilliant
antiswelling
capability,
near‐infrared
(NIR)
light‐triggered
dissociation
drug
release
further
smart
on‐demand
photothermal
therapy.
Herein,
facile
preparation
of
a
flexible
multifunctional
sensor
from
elaborately
fabricated,
highly
stretchable,
MXene
hydrogel
presented.
It
exhibits
range
(up
350%
strain),
reproducibility
enabling
human‐machine
interfacing.
displays
excellent
capability
avoid
expanding
wound
due
excessive
swelling
Furthermore,
possesses
good
biocompatibility
robust
performance
therapy
after
healthcare
monitoring.
Meanwhile,
can
be
triggered
softened
partly
dissociated
under
prolonged
NIR
light
irradiation
transformation
temperature‐sensitive
low‐melting‐point
Agar
into
sol
state
partial
loaded
on
demand
synergistically
sterilizing
bacteria
efficiently
promoting
healing.
ACS Nano,
Journal Year:
2023,
Volume and Issue:
17(16), P. 16036 - 16047
Published: Aug. 14, 2023
Although
skin-like
sensors
that
can
simultaneously
detect
various
physical
stimuli
are
of
fair
importance
in
cutting-edge
human-machine
interaction,
robotic,
and
healthcare
applications,
they
still
face
challenges
facile,
scalable,
cost-effective
production
using
conventional
active
materials.
The
emerging
two-dimensional
transition
metal
carbide,
Ti3C2Tx
MXene,
integrated
with
favorable
thermoelectric
properties,
metallic-like
conductivity,
a
hydrophilic
surface,
is
promising
for
solving
these
problems.
Herein,
multifunctional
designed
to
precisely
distinguish
temperature
pressure
without
cross-talk
by
decorating
elastic
porous
substrates
MXene
sheets.
Because
the
combination
conductive
thermally
insulating,
elastic,
substrate
integrates
efficient
Seebeck
piezoresistive
effects,
resultant
sensor
exhibits
not
only
an
ultralow
detection
limit
(0.05
K),
high
signal-to-noise
ratio,
excellent
cycling
stability
but
also
sensitivity,
fast
response
time,
outstanding
durability
detection.
Based
on
impressive
dual-mode
sensing
properties
independent
detections,
multimode
input
terminal
electronic
skin
created,
exhibiting
great
potential
robotic
interaction
applications.
This
work
provides
scalable
fabrication
tactile
detecting
distinguishing
stimuli.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(31)
Published: March 29, 2024
Wearable
epidermic
electronics
assembled
from
conductive
hydrogels
are
attracting
various
research
attention
for
their
seamless
integration
with
human
body
conformally
real-time
health
monitoring,
clinical
diagnostics
and
medical
treatment,
human-interactive
sensing.
Nevertheless,
it
remains
a
tremendous
challenge
to
simultaneously
achieve
bioadhesive
remarkable
self-adhesiveness,
reliable
ultraviolet
(UV)
protection
ability,
admirable
sensing
performance
high-fidelity
epidermal
electrophysiological
signals
along
timely
photothermal
therapeutic
performances
after
diagnostic
sensing,
as
well
efficient
antibacterial
activity
hemostatic
effect
potential
therapy.
Herein,
hydrogel-based
sensor,
featuring
superior
self-adhesiveness
excellent
UV-protection
performance,
is
developed
by
dexterously
assembling
conducting
MXene
nanosheets
network
biological
hydrogel
polymer
stably
attaching
onto
skin
high-quality
recording
of
high
signal-to-noise
ratios
(SNR)
low
interfacial
impedance
intelligent
diagnosis
smart
human-machine
interface.
Moreover,
sign
language
gesture
recognition
platform
based
on
collected
electromyogram
(EMG)
designed
hassle-free
communication
hearing-impaired
people
the
help
advanced
machine
learning
algorithms.
Meanwhile,
possesses
capability,
biocompatibility,
effective
hemostasis
properties
promising
bacterial-infected
wound
bleeding.