Small,
Journal Year:
2023,
Volume and Issue:
20(5)
Published: Sept. 26, 2023
Abstract
Designing
reliable
and
energy‐efficient
memristors
for
artificial
synaptic
arrays
in
neuromorphic
computing
beyond
von
Neumann
architecture
remains
a
challenge.
Here,
based
on
emerging
layered
nickel
phosphorus
trisulfide
(NiPS
3
)
are
reported
that
exhibit
several
favorable
characteristics,
including
uniform
bipolar
nonvolatile
switching
with
small
operating
voltage
(<1
V),
fast
speed
(<
20
ns),
high
On/Off
ratio
(>10
2
),
the
ability
to
achieve
programmable
multilevel
resistance
states.
Through
direct
experimental
evidence
using
transmission
electron
microscopy
energy
dispersive
X‐ray
spectroscopy,
it
is
revealed
resistive
mechanism
Ti/NiPS
/Au
device
related
formation
dissolution
of
Ti
conductive
filaments.
Intriguingly,
further
investigation
into
microstructural
chemical
properties
NiPS
suggests
penetration
ions
accompanied
by
drift
phosphorus‐sulfur
ions,
leading
induced
P/S
vacancies
facilitate
Furthermore,
demonstrated
memristor,
when
quasi‐reset
mode,
effectively
emulates
long‐term
weight
plasticity.
By
utilizing
crossbar
array,
multipattern
memorization
multiply‐and‐accumulate
(MAC)
operations
successfully
implemented.
Moreover,
owing
highly
linear
symmetric
multiple
conductance
states,
pattern
recognition
accuracy
≈96.4%
neural
network
simulation
systems.
Two-dimensional
heterostructures
have
been
crucial
in
advancing
optoelectronic
devices
utilizing
van
der
Waals
materials.
Semiconducting
transition-metal
dichalcogenide
monolayers,
known
for
their
unique
optical
properties,
offer
extensive
possibilities
light-emitting
devices.
Recently,
a
memory-driven
device,
termed
Mem-emitter,
was
proposed
by
using
these
monolayers
atop
dielectric
substrates.
The
successful
realization
of
such
heavily
depends
on
the
selection
optimal
substrate.
Here,
we
report
pronounced
memory
effect
MoSe2/clinochlore
evidenced
an
electric
hysteresis
intensity
and
energy
MoSe2
monolayer
emissions.
This
demonstrates
both
population-
transition-rate-driven
Mem-emitter
abilities.
Our
theoretical
approach
correlates
effects
with
internal
state
variables
substrate,
emphasizing
that
clinochlore-layered
structure
is
robust
rich
response.
work
introduces
novel
two-dimensional
device
promising
applications
functionalities,
highlighting
importance
alternate
insulators
fabrication
heterostructures.
Chip,
Journal Year:
2023,
Volume and Issue:
2(4), P. 100059 - 100059
Published: July 20, 2023
With
the
advent
of
"Big
Data
Era",
rapid
growth
in
different
types
data
makes
it
urgent
to
improve
storage
density
and
computation
speed.
Flash
memory
with
a
floating
gate
(FG)
structure
is
attracting
attention
due
its
miniaturization,
low
power
consumption,
reliable
storage,
which
very
effective
solving
problems
large
capacity
high
integration
density.
Meanwhile,
FG
charge
principle
can
simulate
synaptic
plasticity
perfectly,
helps
break
traditional
von
Neumann
computing
architecture
used
as
an
artificial
synapse
for
neuromorphic
computations
inspired
by
human
brain.
Among
many
candidate
materials
manufacturing
devices,
van
der
Waals
(vdW)
have
attracted
widespread
their
atomic
thickness,
mobility,
sustainable
miniaturization
properties.
VdW
heterostructure
combines
rich
physics
potential
3D
arbitrary
stacking
ability,
opening
up
various
possibilities
new
functional
integrated
devices
consumption
flexible
applications.
This
paper
provides
comprehensive
review
based
on
vdW
structure,
including
working
principles
typical
structures
focusing
high-performance
memories
versatile
applications
computing.
Finally,
challenges
are
discussed.
will
shed
light
design
fabrication
material-based
engineering,
helping
advance
development
practical
promising
Small,
Journal Year:
2023,
Volume and Issue:
20(5)
Published: Sept. 26, 2023
Abstract
Designing
reliable
and
energy‐efficient
memristors
for
artificial
synaptic
arrays
in
neuromorphic
computing
beyond
von
Neumann
architecture
remains
a
challenge.
Here,
based
on
emerging
layered
nickel
phosphorus
trisulfide
(NiPS
3
)
are
reported
that
exhibit
several
favorable
characteristics,
including
uniform
bipolar
nonvolatile
switching
with
small
operating
voltage
(<1
V),
fast
speed
(<
20
ns),
high
On/Off
ratio
(>10
2
),
the
ability
to
achieve
programmable
multilevel
resistance
states.
Through
direct
experimental
evidence
using
transmission
electron
microscopy
energy
dispersive
X‐ray
spectroscopy,
it
is
revealed
resistive
mechanism
Ti/NiPS
/Au
device
related
formation
dissolution
of
Ti
conductive
filaments.
Intriguingly,
further
investigation
into
microstructural
chemical
properties
NiPS
suggests
penetration
ions
accompanied
by
drift
phosphorus‐sulfur
ions,
leading
induced
P/S
vacancies
facilitate
Furthermore,
demonstrated
memristor,
when
quasi‐reset
mode,
effectively
emulates
long‐term
weight
plasticity.
By
utilizing
crossbar
array,
multipattern
memorization
multiply‐and‐accumulate
(MAC)
operations
successfully
implemented.
Moreover,
owing
highly
linear
symmetric
multiple
conductance
states,
pattern
recognition
accuracy
≈96.4%
neural
network
simulation
systems.