Electrospinning-assisted porous skeleton electrolytes for semi-solid Li–O2 batteries DOI

Jing Wu,

Minghui Li, Shasha Gao

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(38), P. 5070 - 5073

Published: Jan. 1, 2024

Solid-state lithium-oxygen batteries offer great promise in meeting the practical demand for high-energy-density and safe energy storage. We have developed fibrous gel polymer electrolytes (GPEs) using a polyacrylonitrile (PAN) matrix

Language: Английский

Directional Moisture-Wicking Triboelectric Materials Enabled by Laplace Pressure Differences DOI
Zhiwei Wang, Xuelian Zou, Tao Liu

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(23), P. 7125 - 7133

Published: May 29, 2024

Wearable sensors are experiencing vibrant growth in the fields of health monitoring systems and human motion detection, with comfort becoming a significant research direction for wearable sensing devices. However, weak moisture-wicking capability sensor materials leads to liquid retention, severely restricting sensors. This study employs pattern-guided alignment strategy construct microhill arrays, endowing triboelectric directional capability. Within 2.25 s, can quickly directionally remove droplets, driven by Laplace pressure differences wettability gradient. The exhibit excellent performance, enabling rapid response/recovery (29.1/37.0 ms), thereby achieving real-time online respiration movement states. work addresses long-standing challenge insufficient driving force flexible electronic materials, holding implications enhancing application potential skin

Language: Английский

Citations

30
Screening of transition metal oxides for electrocatalytic nitrate reduction to ammonia at large currents DOI

Qiongfei Wu,

Weijie Zhu,

Dongxu Ma

et al.

Nano Research, Journal Year: 2024, Volume and Issue: 17(5), P. 3902 - 3910

Published: Jan. 12, 2024

Language: Английский

Citations

29
Engineering a Dynamic Solvent‐Phobic Liquid Electrolyte Interphase for Long‐Life Lithium Metal Batteries DOI
Qi Kang, Yong Li, Zechao Zhuang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(18)

Published: Jan. 25, 2024

Abstract The heterogeneity, species diversity, and poor mechanical stability of solid electrolyte interphases (SEIs) in conventional carbonate electrolytes result the irreversible exhaustion lithium (Li) during cycling, hindering practical applications Li metal batteries (LMBs). Herein, this work proposes a solvent‐phobic dynamic liquid interphase (DLEI) on (Li–PFbTHF (perfluoro‐butyltetrahydrofuran)) surface that selectively transports salt induces salt‐derived SEI formation. DLEI with C–F‐rich groups dramatically reduces side reactions between Li, solvents, humid air, forming LiF/Li 3 PO 4 ‐rich SEI. In situ electrochemical impedance spectroscopy Ab‐initio molecular dynamics demonstrate effectively stabilizes interface electrolyte. Specifically, LiFePO ||Li–PFbTHF cells deliver 80.4% capacity retention after 1000 cycles at 1.0 C, excellent rate (108.2 mAh g −1 5.0 C), 90.2% 550 C full‐cells (negative/positive (N/P) ratio 8) high loadings (15.6 mg cm −2 ) addition, 0.55 Ah pouch cell 252.0 Wh kg delivers stable cycling. Hence, study provides an effective strategy for controlling to improve cycling performances carbonate‐based LMBs.

Language: Английский

Citations

26
Computational approach inspired advancements of solid-state electrolytes for lithium secondary batteries: from first-principles to machine learning DOI
Zhuoyuan Zheng, Jie Zhou, Yusong Zhu

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(6), P. 3134 - 3166

Published: Jan. 1, 2024

The utilization of computational approaches at various scales, including first-principles calculations, MD simulations, multi-physics modeling, and machine learning techniques, has been instrumental in expediting the advancement SSEs.

Language: Английский

Citations

20
Designing metal sulfide-based cathodes and separators for suppressing polysulfide shuttling in lithium-sulfur batteries DOI
Guoyin Zhu,

Qingzhu Wu,

Xianghua Zhang

et al.

Nano Research, Journal Year: 2023, Volume and Issue: 17(4), P. 2574 - 2591

Published: Nov. 3, 2023

Language: Английский

Citations

28
Solid-state polymer electrolytes in lithium batteries: latest progress and perspective DOI
Jingbo Mu,

Shimin Liao,

Linlin Shi

et al.

Polymer Chemistry, Journal Year: 2024, Volume and Issue: 15(6), P. 473 - 499

Published: Jan. 1, 2024

This review provides a comprehensive overview of solid-state polymer electrolytes performance characteristics various chemical structures such as ethers, esters, nitrile and vinylidene fluoride.

Language: Английский

Citations

17
Composite polymer electrolyte with vertically aligned garnet scaffolds for quasi solid-state lithium batteries DOI
Qiwen Chen,

Cheng Ouyang,

Yitong Liang

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 69, P. 103418 - 103418

Published: April 21, 2024

Language: Английский

Citations

17
Electron delocalization-enhanced sulfur reduction kinetics on an MXene-derived heterostructured electrocatalyst DOI
Yunmeng Li, Yinze Zuo, Xiang Li

et al.

Nano Research, Journal Year: 2024, Volume and Issue: 17(8), P. 7153 - 7162

Published: May 15, 2024

Language: Английский

Citations

17
Engineering High-Performance Li Metal Batteries through Dual-Gradient Porous Cu-CuZn Host DOI Creative Commons
Jianyu Chen, Guanyu Liu,

Xuran Han

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(21), P. 13662 - 13674

Published: May 16, 2024

Porous copper (Cu) current collectors show promise in stabilizing Li metal anodes (LMAs). However, insufficient lithiophilicity of pure Cu and limited porosity three-dimensional (3D) porous structures led to an inefficient Li–Cu composite preparation poor electrochemical performance anodes. Herein, we propose a Cu-CuZn (DG-CCZ) host for tackle these issues. This architecture features pore size distribution lithiophilic-lithiophobic characteristics designed gradient from the inside outside anode structure. dual-gradient exhibits exceptional capillary wettability molten provides high up 66.05%. design promotes preferential deposition interior structure during battery operation, effectively inhibiting dendrite formation. Consequently, all cell systems achieve significantly improved cycling stability, including half-cells, Li–Li symmetric cells, Li-LFP full cells. When paired synergistically with double-coated LiFePO4 cathode, pouch configured multiple electrodes demonstrates impressive discharge capacity 159.3 mAh g–1 at 1C. We believe this study can inspire future 3D enhanced utilization efficiency facilitate development high-energy batteries.

Language: Английский

Citations

17
High Fire‐Safety and Multifunctional Eutectogel for Flexible Quasi‐Solid‐State Supercapacitors DOI

Qingtao Zeng,

Xuejun Lai, Hongqiang Li

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 10, 2024

Abstract The preparation of high‐performance and fire‐safe electrolytes for flexible quasi‐solid‐state supercapacitors is challenging. In this work, a novel multifunctional deep eutectic solvent gel (DESG) fabricated using acrylic acid urea as hydrogen bond donors choline chloride acceptor. DESG shows high ionic conductivity (0.552 S m −1 ), good electrochemical performance (specific capacitance: 106.8 F g wide operating temperature range (−20–90 °C), being promising candidate solid‐state supercapacitors. Furthermore, it exhibits thermoelectric conversion capability (Seebeck coefficient: 1.56 mV K ideal capacitors fire‐warning sensors. prepared rapidly self‐extinguishes after removal from fire, reaching limiting oxygen index value 38.0% demonstrating its excellent flame retardancy. addition, has self‐healing (healing efficiency 84.3%). work provides new insights into the application fire‐safety eutectogels

Language: Английский

Citations

16