Molecules, Journal Year: 2024, Volume and Issue: 29(23), P. 5561 - 5561
Published: Nov. 25, 2024
The catalyst is the pivotal component in CO
Language: Английский
Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
This review examines the strategies of symmetry breaking (charge/coordination/geometric) in single-atom catalysts to regulate active site electronic structures, greatly enhancing catalytic performance.
Language: Английский
Citations
1
EnergyChem, Journal Year: 2024, Volume and Issue: 6(6), P. 100137 - 100137
Published: Oct. 30, 2024
Language: Английский
Citations
4
Advanced Science, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 27, 2025
Abstract The electrocatalytic conversion of CO 2 into valuable multi‐carbon (C 2+ ) products using Cu‐based catalysts has attracted significant attention. This review provides a comprehensive overview recent advances in catalyst design to improve C selectivity and operational stability. It begins with an analysis the fundamental reaction pathways for formation, encompassing both established emerging mechanisms, which offer critical insights design. In situ techniques, essential validating these by real‐time observation intermediates material evolution, are also introduced. A key focus this is placed on how enhance through manipulation, particularly emphasizing catalytic site construction promote C─C coupling via increasing * coverage optimizing protonation. Additionally, challenge maintaining activity under conditions discussed, highlighting reduction active charged Cu species materials reconstruction as major obstacles. To address these, describes strategies preserve sites control including novel utilization mitigation reconstruction. By presenting developments challenges ahead, aims guide future conversion.
Language: Английский
Citations
0
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 19, 2025
Abstract Currently, thermal catalysis is the predominant method for achieving reverse water–gas shift (RWGS) reaction reduction of carbon dioxide (CO 2 ) to monoxide (CO), which a crucial intermediate in synthesis other high value‐added chemicals via Fischer–Tropsch synthesis. To extend applicability CO RR) CO, researchers have explored RR that utilizes external fields addition fields. This review commences by providing an overview research background pertinent and then primary mechanisms potential pathways associated with process are summarized. Furthermore, impact various fields, including traditional light photothermal coupling solar thermochemical laser electric photoelectric electromagnetic plasma on investigated. Finally, summary future perspectives as influenced presented. It anticipated this will provide valuable insights focused preparation high‐value‐added through enhanced
Language: Английский
Citations
0
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 14, 2025
Abstract Single‐atom site electrocatalysts (SACs), with maximum atom efficiency, fine‐tuned coordination structure, and exceptional reactivity toward catalysis, energy, environmental purification, have become the emerging frontier in recent decade. Along significant breakthroughs activity selectivity, limited stability durability of SACs are often underemphasized, posing a grand challenge meeting practical requirements. One pivotal obstacle to construction highly stable is heavy reliance on empirical rather than rational design methods. A comprehensive review urgently needed offer concise overview progress stability/durability, encompassing both deactivation mechanism mitigation strategies. Herein, this first critically summarizes degradation induction factors at atomic‐, meso‐ nanoscale, mainly based but not oxygen reduction reaction. Subsequently, potential stability/durability improvement strategies by tuning catalyst composition, morphology surface delineated, including robust substrate metal‐support interaction, optimization active stability, fabrication porosity modification. Finally, challenges prospects for discussed. This facilitates fundamental understanding provides efficient principles aimed overcoming difficulties beyond.
Language: Английский
Citations
0
ACS Nano, Journal Year: 2025, Volume and Issue: unknown
Published: May 4, 2025
Energy materials are essential for addressing global energy challenges, and their design, recycling, performance optimization critical sustainable development. To efficiently rise to this occasion, advanced technology should be explored address these challenges. This review focuses on the potential of ultrafast thermal engineering as an innovative approach design recycling systematically examines ultrahigh temperature shock's origins, mechanisms, developmental progress, clarifying fundamental differences between Joule heating carbothermal shock modes. Recent advancements in lithium/sodium battery electrode fabrication, catalyst synthesis, by comprehensively summarized highlight processing parameters, structural modulation underlying principles. The also explores mechanisms processes, scalability, environmental economic implications. Notably, a mechanistic insight into dynamic coexistence UTS is proposed, which may synergistically govern evolution poor conductivity/insulating materials. ultimately aims drive development application field.
Language: Английский
Citations
0
Molecules, Journal Year: 2024, Volume and Issue: 29(23), P. 5561 - 5561
Published: Nov. 25, 2024
The catalyst is the pivotal component in CO
Language: Английский
Citations
0