Functional Fiber Materials to Smart Fiber Devices

Chemical Reviews, Journal Year: 2022, Volume and Issue: 123(2), P. 613 - 662

Published: Aug. 17, 2022

The development of fiber materials has accompanied the evolution human civilization for centuries. Recent advances in science and chemistry offered fibers new applications with various functions, including energy harvesting, storing, displaying, health monitoring treating, computing. unique one-dimensional shape devices endows them advantages to work as human-interfaced electronics due small size, lightweight, flexibility, feasibility integration into large-scale textile systems. In this review, we first present a discussion basics design principles devices, followed by comprehensive analysis on recently developed devices. Finally, provide current challenges facing field give an outlook future research directions. With novel continuing be discovered after two decades research, envision that could have important impact our life near future.

Language: Английский

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Bioadhesive polymer semiconductors and transistors for intimate biointerfaces

Science, Journal Year: 2023, Volume and Issue: 381(6658), P. 686 - 693

Published: Aug. 10, 2023

The use of bioelectronic devices relies on direct contact with soft biotissues. For transistor-type devices, the semiconductors that need to have interfacing biotissues for effective signal transduction do not adhere well wet tissues, thereby limiting stability and conformability at interface. We report a bioadhesive polymer semiconductor through double-network structure formed by brush redox-active semiconducting polymer. resulting film can form rapid strong adhesion tissue surfaces together high charge-carrier mobility ~1 square centimeter per volt second, stretchability, good biocompatibility. Further fabrication fully transistor sensor enabled us produce high-quality stable electrophysiological recordings an isolated rat heart in vivo muscles.

Language: Английский

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Synthetic Nuances to Maximize n-Type Organic Electrochemical Transistor and Thermoelectric Performance in Fused Lactam Polymers

Journal of the American Chemical Society, Journal Year: 2022, Volume and Issue: 144(10), P. 4642 - 4656

Published: March 8, 2022

A series of fully fused n-type mixed conduction lactam polymers p(g7NCnN), systematically increasing the alkyl side chain content, are synthesized via an inexpensive, nontoxic, precious-metal-free aldol polycondensation. Employing these as channel materials in organic electrochemical transistors (OECTs) affords state-of-the-art performance with p(g7NC10N) recording OECT electron mobility 1.20 × 10-2 cm2 V-1 s-1 and a μC* figure merit 1.83 F cm-1 s-1. In parallel to high performance, upon solution doping (4-(1,3-dimethyl-2,3-dihydro-1H-benzoimidazol-2-yl)phenyl)dimethylamine (N-DMBI), highest thermoelectric is observed for p(g7NC4N), maximum electrical conductivity 7.67 S power factor 10.4 μW m-1 K-2. These results among reported polymers. Importantly, while this polylactam ionic-electronic conductors (OMIECs) highlights that synthetic molecular design strategies bolster can be translated also achieve (OTE) nuanced approach must used optimize performance. Herein, we outline metrics provide new insights into guidelines next generation high-performance applications, presenting first time single polymer within both OTE applications.

Language: Английский

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Soft Fiber Electronics Based on Semiconducting Polymer

Chemical Reviews, Journal Year: 2023, Volume and Issue: 123(8), P. 4693 - 4763

Published: Feb. 8, 2023

Fibers, originating from nature and mastered by human, have woven their way throughout the entire history of human civilization. Recent developments in semiconducting polymer materials further endowed fibers textiles with various electronic functions, which are attractive applications such as information interfacing, personalized medicine, clean energy. Owing to ability be easily integrated into daily life, soft fiber electronics based on polymers gained popularity recently for wearable implantable applications. Herein, we present a review previous current progress polymer-based electronics, particularly focusing smart-wearable areas. First, provide brief overview viewpoint basic concepts functionality requirements different devices. Then analyze existing associated devices interfaces, healthcare energy conversion storage. The working principle performance summarized. Furthermore, focus fabrication techniques Based continuous one-dimensional yarn, introduce two- three-dimensional fabric fabricating methods. Finally, challenges relevant perspectives potential solutions address related problems.

Language: Английский

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Organic electrochemical transistors as on-site signal amplifiers for electrochemical aptamer-based sensing

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: March 25, 2023

Abstract Electrochemical aptamer-based sensors are typically deployed as individual, passive, surface-functionalized electrodes, but they exhibit limited sensitivity especially when the area of electrode is reduced for miniaturization purposes. We demonstrate that organic electrochemical transistors (electrolyte gated with volumetric gating) can serve on-site amplifiers to improve sensors. By monolithically integrating an Au working/sensing electrode, on-chip Ag/AgCl reference and Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) counter — also serving channel transistor— we simultaneously perform testing traditional electroanalytical measurement on including cyclic voltammetry square-wave voltammetry. This device directly amplify current from sensor via in-plane modulation in electrode/transistor channel. The integrated sense transforming growth factor beta 1 3 4 orders magnitude enhancement compared (292 μA/dec vs. 85 nA/dec). approach believed be universal, applied a wide range tethered reporter-based enhance sensitivity, aiding easing burden backend signal processing.

Language: Английский

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Organic mixed conductors for bioinspired electronics

Nature Reviews Materials, Journal Year: 2023, Volume and Issue: 9(2), P. 134 - 149

Published: Dec. 22, 2023

Language: Английский

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Emerging Iontronic Neural Devices for Neuromorphic Sensory Computing

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(39)

Published: March 9, 2023

Living organisms have a very mysterious and powerful sensory computing system based on ion activity. Interestingly, studies iontronic devices in the past few years proposed promising platform for simulating sensing functions of living organisms, because: 1) can generate, store, transmit variety signals by adjusting concentration spatiotemporal distribution ions, which analogs to how brain performs intelligent alternating flux polarization; 2) through ionic-electronic coupling, bridge biosystem with electronics offer profound implications soft electronics; 3) diversity be designed recognize specific ions or molecules customizing charge selectivity, ionic conductivity capacitance adjusted respond external stimuli schemes, more difficult electron-based devices. This review provides comprehensive overview emerging neuromorphic devices, highlighting representative concepts both low-level high-level introducing important material device breakthroughs. Moreover, as means are discussed regarding pending challenges future directions.

Language: Английский

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Polyaniline-Based Biological and Chemical Sensors: Sensing Mechanism, Configuration Design, and Perspective

ACS Applied Electronic Materials, Journal Year: 2023, Volume and Issue: 5(2), P. 593 - 611

Published: Jan. 31, 2023

By virtue of its tunable electrical conductivity, remarkable solution processing capability, and great biocompatibility, polyaniline (PANI) has been recognized as an attractive active material for use in biological chemical ("bio/chemical") sensors. This Spotlight article focuses on the structure characteristics PANI-based materials corresponding device-level sensing performance. bio/chemical sensors, such chemi-resistive electrochemical transistor-based are systematically elucidated based device architecture mechanism. The structure–function relationships among PANI doping state, microscopic structure, local crystallinity, their functionalities three types sensors have elaborated. Finally, state-of-the-art progress applications these breakthroughs a broader context outlined from challenges to strategies.

Language: Английский

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Fully 3D-printed organic electrochemical transistors

npj Flexible Electronics, Journal Year: 2023, Volume and Issue: 7(1)

Published: March 7, 2023

Abstract Organic electrochemical transistors (OECTs) are being researched for various applications, ranging from sensors to logic gates and neuromorphic hardware. To meet the requirements of these diverse device fabrication process must be compatible with flexible scalable digital techniques. Here, we report a direct-write additive fabricate fully 3D-printed OECTs, using 3D printable conducting, semiconducting, insulating, electrolyte inks. These which operate in depletion mode, can fabricated on substrates, resulting high mechanical environmental stability. The OECTs have good dopamine biosensing capabilities (limit detection down 6 µM without metal gate electrodes) show long-term (~1 h) synapse response, indicating their potential applications such as This manufacturing strategy is suitable that require rapid design changes digitally enabled

Language: Английский

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Organic Electrochemical Transistors for Biomarker Detections

Advanced Science, Journal Year: 2024, Volume and Issue: 11(27)

Published: Jan. 23, 2024

The improvement of living standards and the advancement medical technology have led to an increased focus on health among individuals. Detections biomarkers are feasible approaches obtaining information about status, disease progression, response treatment individual. In recent years, organic electrochemical transistors (OECTs) demonstrated high electrical performances effectiveness in detecting various types biomarkers. This review provides overview working principles OECTs their performance multiple biomarkers, with a advances representative applications wearable implantable biomarker detections, perspective for future development OECT-based sensors.

Language: Английский

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