Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(21), P. 8905 - 8909
Published: Jan. 1, 2024
A new crystal compound, ([CdCl 2 (1-methyl-2-pyridone)] n ), shows exceptional flexibility and optical properties due to its chiral structure, making it a promising material for combining mechanical features.
Language: Английский
Chemical Society Reviews, Journal Year: 2023, Volume and Issue: 52(9), P. 3098 - 3169
Published: Jan. 1, 2023
Molecular crystals have shown remarkable adaptability in response to a range of external stimuli. Here, we survey this emerging field and provide critical overview the experimental, computational instrumental tools being used design apply such materials.
Language: Английский
Citations
184
Journal of Materials Chemistry C, Journal Year: 2023, Volume and Issue: 11(6), P. 2026 - 2052
Published: Jan. 1, 2023
Stimuli-responsive flexible organic crystals are a new generation of smart devices aimed towards functionalization, integration, and intelligence.
Language: Английский
Citations
52
Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(8), P. 3687 - 3713
Published: Jan. 1, 2024
The cornerstones of the advancement flexible optoelectronics are design, preparation, and utilization novel materials with favorable mechanical advanced optoelectronic properties. Molecular crystalline have emerged as a class underexplored yet promising due to reduced grain boundaries defects anticipated provide enhanced photoelectric characteristics. An inherent drawback that has precluded wider implementation molecular crystals thus far, however, been their brittleness, which renders them incapable ensuring compliance required for even simple elastic or plastic deformation device. It is perplexing despite plethora reports in meantime become available underpinning flexibility crystals, "discovery" elastically plastically deformable remains limited cases serendipitous laborious trial-and-error approaches, situation calls systematic thorough assessment these properties correlation structure. This review provides comprehensive concise overview current understanding origins crystal flexibility, working mechanisms deformations such bending behaviors, insights into examples specifically concerning photoelectronic changes occur deformed crystals. We hope this summary will reference future experimental computational efforts aimed towards improving behavior properties, ultimately intending advance technology.
Language: Английский
Citations
28
JACS Au, Journal Year: 2024, Volume and Issue: 4(2), P. 279 - 300
Published: Jan. 16, 2024
Flexible crystals have gained significant attention owing to their remarkable pliability, plasticity, and adaptability, making them highly popular in various research application fields. The main challenges developing flexible lie the rational design, preparation, performance optimization of such crystals. Therefore, a comprehensive understanding fundamental origins crystal flexibility is crucial for establishing evaluation criteria design principles. This Perspective offers retrospective analysis development over past two decades. It summarizes elastic standards possible plastic bending mechanisms tailored diverse analyzes assessment theoretical basis applicability. Meanwhile, compatibility between elasticity plasticity has been discussed, unveiling immense prospects elastic/plastic applications biomedicine, electronic devices, optics. Furthermore, this presents state-of-the-art experimental avenues methods investigating molecular interactions crystals, which vital future exploration flexibility.
Language: Английский
Citations
21
Aggregate, Journal Year: 2024, Volume and Issue: 5(3)
Published: Jan. 23, 2024
Abstract The emergence of flexible organic crystals changed the perception molecular that were regarded as brittle entities over a long period time, and sparked great interest in exploring mechanically compliant crystalline materials toward next‐generation smart during past decade. Schiff base compounds are considered to be one most promising candidates for owing their easy synthesis, high yield, stimuli responsiveness good mechanical properties. This paper gives an overview recent development (including elastic crystals, plastic integrating elasticity plasticity) from serendipitous discovery design strategies versatile applications such responses, optical waveguides, optoelectronic devices, biomimetic soft robots, photonic integrated circuits. Notably, atomic force microscopy‐micromanipulation technique has been utilized bring multifunctional macroscopic level microscopic world. Since understanding flexibility at through crystal engineering can assist us trace down structural origin properties, we focus on packing structures various driven by non‐covalent intermolecular interactions close correlation with behaviors. We hope information given here will help novel combined other unique promote further research into area applications.
Language: Английский
Citations
17
Nature Communications, Journal Year: 2022, Volume and Issue: 13(1)
Published: Sept. 8, 2022
Operation of temperature sensors over extended ranges, and particularly in extreme conditions, poses challenges with both the mechanical integrity sensing material operational range sensor. With an emissive bendable organic crystalline material, here we propose that crystals can be used as mechanically robust compliant fluorescence-based thermal wide coverage complete retention elasticity. The exemplary described remains elastically shows highly linear correlation emission wavelength intensity between 77 K to 277 K, while it also transduces its own fluorescence active waveguiding mode. This universal new approach expands materials available for optical a vast number class engineering opens opportunities design lightweight, operate under conditions such are ones will encountered future space exploration missions.
Language: Английский
Citations
70
Nature Communications, Journal Year: 2022, Volume and Issue: 13(1)
Published: Dec. 22, 2022
Hybrid materials capitalize on the properties of individual to attain a specific combination performance assets that is not available with components alone. We describe straightforward approach preparation sandwich-type hybrid dynamic combine metals as electrically conductive and polymers bending, momentum-inducing flexible organic crystals mechanically compliant optically transducive medium. The resulting are both electricity light, while they also respond changes in temperature by deformation. Depending metal, their conductivity ranges from 7.9 21.0 S µm‒1. elements rapidly curling or uncurling about 0.2 s, which one typical case corresponds exceedingly fast deformation recovery rates 2187.5° s‒1 1458.3° s‒1, respectively. In cyclic operation mode, decreases less than 1% after 10,000 thermal cycles. mechanothermal robustness dual functionality favors these candidates for variety applications organic-based optics electronics, expands prospects application beyond natural limits performance.
Language: Английский
Citations
42
Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(17)
Published: Feb. 10, 2023
Visible light guiding optical fibers with underwater operational capability are highly desired for subaquatic communication and sensing technologies. Herein, we present mechanically flexible, blue-violet fluorescent (4,4'-bis(2,6-di(1H-pyrazol-1-yl)pyridin-4-yl)biphenyl) (BPP) crystal waveguides high-aspect ratio. These milli-meter-long BPP crystals guide actively passively in ambient conditions demonstrating their amphibian-like character. Due to the crystal's high flexibility, fiber's output direction submerged states can be altered high-precision lighting applications. The development of such multi-environment-compatible flexible organic acting as materials possess enormous potential short-range photonic
Language: Английский
Citations
29
Aggregate, Journal Year: 2023, Volume and Issue: 4(6)
Published: June 23, 2023
Abstract Flexible molecular crystal waveguides based on elastic crystals (EMCs) are essential in flexible and compact optical materials. An increased loss coefficient α due to self‐absorption is often a problem (OWGs) of fluorescent chemical materials waveguiding photons active mode. Herein, the development anthracene‐based mixed (EMMCs) reported for Förster Resonance Energy Transfer (FRET)‐assisted OWG. To yield FRET system crystals, 1%–5% acceptor doping 9,10‐dibromoanthracene 1 was successful by selecting same regioisomer having electron‐withdrawing group, 9,10‐diformylanthracene 2 , as dopant. In addition conversion system, there difference modulus hardness EMC C1 EMMC C2@1 . However, behaviour also shown few percent acceptor. The value this EMMC, composed including 1% (0.0077 dB/μm), much lower than that (0.1258 dB/μm) because reducing system. efficient OWG successfully developed an appropriate molecule its low rate construction. This method practical approach various functional systems.
Language: Английский
Citations
23
Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(28)
Published: April 25, 2024
The dense and ordered molecular arrangements endow dynamic crystals with fast response, rapid energy conversion, low dissipation, strong coupling between heat/light mechanical energy. Most of the known can only respond to a single stimulus, materials that multiple stimuli are rare. Here, we report an organic crystalline material be bent plastically is also thermosalient, as its move when they undergo reversible phase transition. transmit light regardless their shape or phase. combination transduction thermomechanical deformation provides opportunity switch waveguiding capability in narrow temperature range, which holds tremendous potential for applications heat-averse electronic components, such central processing units. Unlike existing electronics, here completely therefore much lighter, potentially reducing overall weight circuits.
Language: Английский
Citations
9