Mechanochemical-assisted decarboxylative sulfonylation of α,β-unsaturated carboxylic acids with sodium sulfinate salts DOI

Barakha Saxena,

Roshan I. Patel,

Shruti Sharma

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(5), P. 2721 - 2729

Published: Jan. 1, 2024

Herein, we report a mechanochemical-assisted decarboxylative sulfonylation of α,β-unsaturated carboxylic acids with sodium sulfinate salts using potassium iodide as an activator under water-assisted grinding conditions.

Language: Английский

The Direct Mechanocatalytic Suzuki–Miyaura Reaction of Small Organic Molecules DOI
Wilm Pickhardt,

Claudio Beaković,

Maike Mayer

et al.

Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 61(34)

Published: May 31, 2022

Abstract The molecular Suzuki cross‐coupling reaction was conducted mechanochemically, without solvents, ligands, or catalyst powders. Utilizing one catalytically active palladium milling ball, products could be formed in quantitative yield as little 30 min. In contrast to previous reports, the adjustment of parameters led complete elimination abrasion from thus enabling first reported systematic analysis. XPS, situ XRD, and reference experiments provided evidence that ball surface location catalysis, allowing a mechanism proposed. versatility approach demonstrated by extending substrate scope deactivated even sterically hindered aryl iodides bromides.

Language: Английский

Citations

40
Mechanically activated solid state radical polymerization and cross‐linking via piezocatalysis DOI Creative Commons
Mitchell D. Nothling, J. Daniels, Yen Vo

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(20)

Published: March 15, 2023

Abstract Piezocatalysis offers a means to transduce mechanical energy into chemical potential, harnessing physical force drive redox reactions. Working in the solid state, we show here that piezoelectric BaTiO 3 nanoparticles can load flux of reactive radical species capable initiating state free polymerization. Activation powder by ball milling, striking with hammer, or repeated compressive loading generates highly hydroxyl radicals (⋅OH), which readily initiate chain growth and crosslinking acrylamide, acrylate, methacrylate styrenic monomers. Control experiments indicate critical role for chemisorbed water on nanoparticle surface, is oxidized ⋅OH via mechanoredox catalysis. The force‐induced production compressing dry materials represents promising new route harness synthesis.

Language: Английский

Citations

28
Mechanochemistry enabling highly efficient Birch reduction using sodium lumps and d-(+)-glucose DOI Creative Commons

Keisuke Kondo,

Koji Kubota, Hajime Ito

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(12), P. 4452 - 4457

Published: Jan. 1, 2024

In this study, a mechanochemical protocol for highly efficient and ammonia-free sodium-based Birch reduction was developed, leveraging the use of cheap easy-to-handle sodium lumps d -(+)-glucose as proton source.

Language: Английский

Citations

16
Kinetics of primary mechanochemical covalent-bond-forming reactions DOI Creative Commons
Yerzhan S. Zholdassov, R. W. M. Kwok, Milan A. Shlain

et al.

RSC Mechanochemistry, Journal Year: 2024, Volume and Issue: 1(1), P. 11 - 32

Published: Jan. 1, 2024

Mechanical activation of reactions can reduce significantly the amounts solvent and energy required to form covalent organic bonds.

Language: Английский

Citations

14
Mechanochemical-assisted decarboxylative sulfonylation of α,β-unsaturated carboxylic acids with sodium sulfinate salts DOI

Barakha Saxena,

Roshan I. Patel,

Shruti Sharma

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(5), P. 2721 - 2729

Published: Jan. 1, 2024

Herein, we report a mechanochemical-assisted decarboxylative sulfonylation of α,β-unsaturated carboxylic acids with sodium sulfinate salts using potassium iodide as an activator under water-assisted grinding conditions.

Language: Английский

Citations

12