Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
Language: Английский
Environmental Research, Journal Year: 2024, Volume and Issue: 246, P. 118144 - 118144
Published: Jan. 6, 2024
Language: Английский
Citations
16
Organic Process Research & Development, Journal Year: 2022, Volume and Issue: 26(9), P. 2564 - 2613
Published: Sept. 1, 2022
An emerging interest for the application of periodate in synthesis active pharmaceutical ingredients (APIs) and valorization renewable feedstock is eminent. However, exhibits a high molecular mass, expensive compared to other common bulk-oxidizers used only reluctantly technical applications. Recently, new green electrochemical was established. The preparation regeneration method lowers costs enables use regulated products. This review will briefly introduce key innovations survey most important applications production fine chemicals.
Language: Английский
Citations
23
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(10), P. 5862 - 5868
Published: Jan. 1, 2024
Peroxodicarbonate, a sustainable electrochemically generated oxidizer, provides the means to transform abundant hydroxybenzaldehydes into valuable phenols in safe and effective manner.
Language: Английский
Citations
6
Organic Letters, Journal Year: 2024, Volume and Issue: 26(8), P. 1607 - 1611
Published: Feb. 16, 2024
Electrochemically generated green platform oxidizers like peroxodicarbonate (PODIC) constitute a game-changing technology in terms of sustainable chemistry while serving as an alternative counterreaction the electrochemical hydrogen evolution. Peroxodicarbonate avoids storage and shipping concentrated peroxide solution. We herein disclose efficient method for N-oxidation quinolines, pyridines, complex tertiary amines. The use phenoyloxy succinimide (POSI) is decisive factor obtaining N-oxides (28 examples) isolated yields up to 98%.
Language: Английский
Citations
6
European Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 26(17)
Published: March 14, 2023
Abstract Peroxodicarbonate represents a green and largely underexplored oxidizer generated electrochemically from aqueous carbonate solutions. Through state‐of‐the‐art electrolyzer technology, highly concentrated solutions have now become accessible. These were successfully employed as in deborolative hydroxylations. A plethora of phenols alcohols thus been synthesized up to 99 % organoboron compounds using only non‐toxic solvents. This transformation was scaled‐up multi‐gram batch sizes.
Language: Английский
Citations
12
ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(20), P. 7755 - 7764
Published: May 9, 2023
A novel electrosynthetic protocol for the direct conversion of easily accessible 4-hydroxybenzaldehydes into valuable benzoquinones is reported. The transformation enabled through anodic oxidation and performed in a reagent-free manner devoid terminal oxidants redox mediators to effectively minimize waste. Environmentally benign inexpensive graphite serves as metal-free anode material. broad range substituents, including halogens, are tolerated this electrochemical protocol, quinones selectively yields up 99%. Furthermore, compatibility with flow synthesis demonstrated. Moreover, successfully applied biopolymer lignosulfonate provides 7.6 wt%. mechanistic proposal Dakin-type reaction offered. sustainability synthetic utility evaluated quantitatively compared established protocols by application different green chemistry metrics.
Language: Английский
Citations
12
Chemical Communications, Journal Year: 2024, Volume and Issue: 60(56), P. 7136 - 7147
Published: Jan. 1, 2024
Peroxodicarbonate, accessible from direct anodic conversion of alkali carbonates, has experienced a renaissance in the past two decades. An overview its history, synthesis, characteristics and reactivity is provided.
Language: Английский
Citations
4
ACS Sustainable Chemistry & Engineering, Journal Year: 2024, Volume and Issue: 12(30), P. 11283 - 11296
Published: July 18, 2024
A pilot scale plant at Technology Readiness Level (TRL) 6 comprising an electrochemical ex-cell continuous production of sodium peroxodicarbonate and a thermal depolymerization plug flow reactor for kraft lignin conversion is established. Due to the labile nature "green" oxidizer peroxodicarbonate, special attention must be paid parameters in order optimize its use. simplified design model describing steady-state transient operations formulated finally validated against experimental data from electrolysis setup. Design trade-offs are visualized, their impact on specific energy consumption evaluated. The was operated 20-month period more than 1200 h on-stream. Optimized process conditions result vanillin yields 8 wt % thus prove successful scale-up.
Language: Английский
Citations
4
Chemie Ingenieur Technik, Journal Year: 2025, Volume and Issue: unknown
Published: March 18, 2025
Abstract Organic electrosynthesis is a potential enabler for the energy and resource transition in chemical industry as it offers sustainable alternative to homogeneous or heterogeneous processes producing fine commodity chemicals. It utilizes electricity instead of hazardous reagents and, thus, also allows reducing product's carbon footprint waste production. enables dynamic operation safe due galvanostatic process control. Electro‐organic are not yet widespread. Engineering tools have been tailored electro‐organic processes, more quantitative model‐based insight needed. Extensive adoption requires efforts regarding electrode material performance stability, scalable reactor design, digitization. Addressing these issues interdisciplinary collaboration, particularly between chemists engineers, accelerate implementation with high efficiency economic feasibility.
Language: Английский
Citations
0
ChemSusChem, Journal Year: 2024, Volume and Issue: 17(22)
Published: May 31, 2024
Abstract A new and practical method for the thermal degradation of technically relevant bio‐based lignin is presented. By heating a solution in highly concentrated caustic potash, vanillic acid almost exclusively obtained yields up to 10.6 wt %. altering reaction parameters, selectivity can be shifted towards demethylation product, protocatechuic acid, which yield 6.9 Furthermore, procedure was applicable different types Kraft organosolv lignin. To create an economically feasible process, ion exchange resins were used work‐up media without neutralizing complete mixture. selective removal desired from this alkaline could directly reused at least 5 further degradations significant loss yield.
Language: Английский
Citations
3