Enantioselective Nickel-Catalyzed Electrochemical Reductive Conjugate Alkenylation of α,β-Unsaturated Ketones DOI Creative Commons
Siriphong Somprasong, Baonian Wan, Syuzanna R. Harutyunyan

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 20, 2024

We present an asymmetric electrochemical nickel-catalysed reductive conjugate addition of alkenyl bromides/aryl iodides to α,β-unsaturated ketones in undivided cell, which afforded β-alkenylate/arylate high yields with excellent enantioselectivities.

Language: Английский

Nickel/Photoredox-Catalyzed Asymmetric Three-Component Cross-Coupling To Access Enantioenriched 1,1-Diaryl(heteroaryl)alkanes DOI

Xueying Gao,

Tingzhi Lin,

Yan‐En Wang

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(41), P. 8792 - 8797

Published: Oct. 8, 2024

An enantioselective 1,2-dicarbofunctionalization of vinyl (hetero)arenes with alkyl bromides and aryl through nickel/photoredox catalysis is described. This three-component domino arylation could generate a diverse array enantioenriched 1,1-diaryl(heteroaryl)alkanes good to excellent yields (up 88%) high enantioselectivities 99%

Language: Английский

Citations

5
Enantioselective Nickel-Catalyzed Electrochemical Reductive Conjugate Alkenylation of α,β-Unsaturated Ketones DOI Creative Commons
Siriphong Somprasong, Baonian Wan, Syuzanna R. Harutyunyan

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 20, 2024

We present an asymmetric electrochemical nickel-catalysed reductive conjugate addition of alkenyl bromides/aryl iodides to α,β-unsaturated ketones in undivided cell, which afforded β-alkenylate/arylate high yields with excellent enantioselectivities.

Language: Английский

Citations

0