Structural Stability of Formamidinium- and Cesium-Based Halide Perovskites DOI
Yu An, Juanita Hidalgo, Carlo A. R. Perini

et al.

ACS Energy Letters, Journal Year: 2021, Volume and Issue: 6(5), P. 1942 - 1969

Published: April 28, 2021

The certified power conversion efficiency of state-of-the-art organic–inorganic hybrid perovskite solar cells has surpassed 25%, showing promising potential for commercialization. Compared with volatile methylammonium-based perovskites, formamidinium- and cesium-based halide perovskites have attracted attention due to their resistance thermal degradation. However, the photoactive phases these materials suffer from limited phase stability at room temperature are prone spontaneous transformation into photoinactive phases. This Review sheds light onto fundamental understanding origin instability both intrinsic structure extrinsic factors. We highlight methodologies used suppress undesired transitions an emphasis on structure–property relationships.

Language: Английский

The 2D Halide Perovskite Rulebook: How the Spacer Influences Everything from the Structure to Optoelectronic Device Efficiency DOI
Xiaotong Li, Justin M. Hoffman, Mercouri G. Kanatzidis

et al.

Chemical Reviews, Journal Year: 2021, Volume and Issue: 121(4), P. 2230 - 2291

Published: Jan. 21, 2021

Two-dimensional (2D) halide perovskites have emerged as outstanding semiconducting materials thanks to their superior stability and structural diversity. However, the ever-growing field of optoelectronic device research using 2D requires systematic understanding effects spacer on structure, properties, performance. So far, many studies are based trial-and-error tests random spacers with limited ability predict resulting structure these synthetic experiments, hindering discovery novel be incorporated into high-performance devices. In this review, we provide guidelines successfully choosing incorporating them crystalline We first a summary various methods act tutorial for groups interested in pursuing synthesis perovskites. Second, our insights what kind cations can stabilize followed by an extensive review cations, which been shown emphasis optical properties. Next, similar explanation used fabricate films desired Like section, will then focus that devices how they influence film With comprehensive effects, rational selection made, accelerating already exciting field.

Language: Английский

Citations

768
Inverted perovskite solar cells using dimethylacridine-based dopants DOI
Qin Tan, Zhaoning Li, Guangfu Luo

et al.

Nature, Journal Year: 2023, Volume and Issue: 620(7974), P. 545 - 551

Published: May 24, 2023

Language: Английский

Citations

425
Materials and Methods for Interface Engineering toward Stable and Efficient Perovskite Solar Cells DOI
Jiangzhao Chen, Nam‐Gyu Park

ACS Energy Letters, Journal Year: 2020, Volume and Issue: 5(8), P. 2742 - 2786

Published: July 27, 2020

Because interfacial nonradiative recombination (NRR) has a significant influence on device performance, the minimization of NRR losses through interface engineering especially for perovskite-related interfaces is key to achieving efficient, stable, and hysteresis-free perovskite solar cells (PSCs). In light important contributions rapid development PSCs, systematic investigation analysis latest research advancements urgently needed. This Review aims at providing innovative insights into further improvement in power conversion efficiency (PCE) toward Shockley–Queisser limit stability fulfilling commercially available standard protocols as well reduction hysteresis. this Review, roles importance PSCs are first highlighted from viewpoint structure, working principles, carrier dynamics. The main origins (i.e., defects, imperfect energy level alignment (ELA), reactions) then discussed detail along with characterization techniques. Subsequently, effects PCE, stability, hysteresis investigated. Strategies mitigating provided terms defect passivation, ELA modulation, suppression reaction, where critical functional groups modifiers emphasized. Finally, we provide an outlook hysteresis-free, long-term operationally stable achievable via engineering.

Language: Английский

Citations

420
From Defects to Degradation: A Mechanistic Understanding of Degradation in Perovskite Solar Cell Devices and Modules DOI Creative Commons
Sean P. Dunfield,

Lyle Bliss,

Fei Zhang

et al.

Advanced Energy Materials, Journal Year: 2020, Volume and Issue: 10(26)

Published: March 1, 2020

Abstract Metal halide perovskite solar cells (PSCs) have risen in efficiency from just 3.81% 2009 to over 25.2% today. While metal perovskites excelled efficiency, advances stability are significantly more complex and progressed slowly. The advance of which is readily measured, stability, can require literally thousands hours demonstrate, be expected given the rapid rate innovation field. In face changing absorber composition, synthetic approaches, device stack components it necessary understand basic material properties rationalize how enable devices. this article aim present an in‐depth review current understanding devices module by focusing on what known retarding intrinsic extrinsic degradation mechanisms at material, device, level. Once these considerations presented discussion then moves connecting different stresses anticipated operation they impact ultimately modules time.

Language: Английский

Citations

366
Molecular engineering of contact interfaces for high-performance perovskite solar cells DOI
Furkan H. Isikgor, Shynggys Zhumagali,

Luis Victor Torres Merino

et al.

Nature Reviews Materials, Journal Year: 2022, Volume and Issue: 8(2), P. 89 - 108

Published: Nov. 4, 2022

Language: Английский

Citations

349
Perovskite Light‐Emitting Diodes with External Quantum Efficiency Exceeding 22% via Small‐Molecule Passivation DOI
Zema Chu, Qiufeng Ye, Yang Zhao

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 33(18)

Published: April 1, 2021

Abstract Perovskite light‐emitting diodes (PeLEDs) are considered as particularly attractive candidates for high‐quality lighting and displays, due to possessing the features of wide gamut real color expression. However, most PeLEDs made from polycrystalline perovskite films that contain a high concentration defects, including point extended imperfections. Reducing mitigating non‐radiative recombination defects in materials still crucial prerequisites achieving performance applications. Here, ethoxylated trimethylolpropane triacrylate (ETPTA) is introduced functional additive dissolved antisolvent passivate surface bulk during spinning process. The ETPTA can effectively decrease charge trapping states by passivation and/or suppression defects. Eventually, sufficiently passivated make devices achieve maximum external quantum efficiency (EQE) 22.49%. To our knowledge, these efficient green up now. In addition, threefold increase T 50 operational time was observed, compared control samples. These findings provide simple effective strategy highly their optoelectronics devices.

Language: Английский

Citations

273
Passivation and process engineering approaches of halide perovskite films for high efficiency and stability perovskite solar cells DOI
Abd. Rashid bin Mohd Yusoff, Maria Vasilopoulou, Dimitra G. Georgiadou

et al.

Energy & Environmental Science, Journal Year: 2021, Volume and Issue: 14(5), P. 2906 - 2953

Published: Jan. 1, 2021

Recent advances on passivation and morphology engineering approaches adopted to obtain high efficiency stability in perovskite solar cells are thoroughly reviewed.

Language: Английский

Citations

255
Efficient and stable inverted perovskite solar cells with very high fill factors via incorporation of star-shaped polymer DOI Creative Commons
Qi Cao, Yongjiang Li, Hong Zhang

et al.

Science Advances, Journal Year: 2021, Volume and Issue: 7(28)

Published: July 7, 2021

A star-shaped polymer enables inverted perovskite solar cells with efficiency over 22% and a very high fill factor of 0.862.

Language: Английский

Citations

255
Two birds with one stone: dual grain-boundary and interface passivation enables >22% efficient inverted methylammonium-free perovskite solar cells DOI Creative Commons
Saba Gharibzadeh, Paul Faßl, Ihteaz M. Hossain

et al.

Energy & Environmental Science, Journal Year: 2021, Volume and Issue: 14(11), P. 5875 - 5893

Published: Jan. 1, 2021

We present a dual passivation approach for p–i–n perovskite solar cells using phenethylammonium chloride that simultaneously passivates defects at the grain boundaries and perovskite/C 60 interface, thus substantially enhancing both V OC FF.

Language: Английский

Citations

230
Recent progress in morphology optimization in perovskite solar cell DOI Open Access
Naveen Kumar Tailor, Mojtaba Abdi‐Jalebi, Vinay Gupta

et al.

Journal of Materials Chemistry A, Journal Year: 2020, Volume and Issue: 8(41), P. 21356 - 21386

Published: Jan. 1, 2020

Hybrid organic–inorganic halide perovskite based solar cell technology has passed through a phase of unprecedented growth in the efficiency scale from 3.8% to above 25% within decade.

Language: Английский

Citations

217