Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(47)
Published: Oct. 9, 2024
Abstract
The
emerging
non‐fullerene
acceptors
with
low
voltage
losses
have
pushed
the
power
conversion
efficiency
of
organic
solar
cells
(OSCs)
to
≈20%
auxiliary
morphology
optimization.
Thermal
annealing
(TA),
as
most
widely
adopted
post‐treatment
method,
has
been
playing
an
essential
role
in
realizing
potential
various
material
systems.
However,
procedure
TA,
i.e.,
way
that
TA
is
performed,
almost
identical
among
thousands
OSC
papers
since
≈30
years
ago
other
than
changes
temperature
and
time.
Herein,
a
reverse
thermal
(RTA)
technique
developed,
which
can
enhance
dielectric
constant
active
layer
film,
thereby
producing
smaller
Coulomb
capture
radius
(14.93
nm),
meanwhile,
forming
moderate
nano‐scale
phase
aggregation
more
favorable
face‐on
molecular
stacking
orientation.
Thus,
this
method
reduce
decline
open
circuit
conventional
by
achieving
decreased
radiative
(0.334
eV)
non‐radiative
(0.215
recombination
loss.
RTA
PM6:L8‐BO‐X
device
increases
19.91%
(certified
19.42%)
compared
(18.98%).
It
shown
exhibits
superb
universality
4
systems,
revealing
its
dramatic
be
employed
wide
range
OSCs.
Coatings,
Journal Year:
2023,
Volume and Issue:
13(9), P. 1657 - 1657
Published: Sept. 21, 2023
Inorganic
semiconductors
like
silicon
and
germanium
are
the
foundation
of
modern
electronic
devices.
However,
they
have
certain
limitations,
such
as
high
production
costs,
limited
flexibility,
heavy
weight.
Additionally,
depletion
natural
resources
required
for
inorganic
semiconductor
raises
concerns
about
sustainability.
Therefore,
exploration
development
organic
offer
a
promising
solution
to
overcome
these
challenges
pave
way
new
era
electronics.
New
applications
optoelectronic
devices
been
made
possible
by
recent
emergence
semiconductors.
Numerous
innovative
results
on
performance
charge
transport
discovered
with
growth
These
discoveries
opened
up
possibilities
devices,
solar
cells,
light-emitting
diodes,
field-effect
transistors.
The
use
materials
in
has
potential
revolutionise
electronics
industry
providing
low-cost,
flexible,
lightweight
alternatives
traditional
materials.
understanding
carrier
is
crucial
efficient
This
review
offers
thorough
overview
phenomenon
focus
underlying
physical
mechanisms
how
it
affects
device
performance.
processes
generation
recombination
given
special
attention.
Furthermore,
this
provides
valuable
insights
into
fundamental
principles
that
govern
behaviour
carriers
materials,
which
can
inform
design
optimisation
future
Journal of the American Chemical Society,
Journal Year:
2024,
Volume and Issue:
146(20), P. 14287 - 14296
Published: May 8, 2024
PEDOT:PSS
has
been
widely
used
as
a
hole
extraction
layer
(HEL)
in
organic
solar
cells
(OSCs).
However,
their
acidic
nature
can
potentially
corrode
the
indium
tin
oxide
(ITO)
electrode
over
time,
leading
to
adverse
effects
on
longevity
of
OSCs.
Herein,
we
have
developed
class
biphosphonic
acid
molecules
with
tunable
dipole
moments
for
self-assembled
monolayers
(SAMs),
namely,
3-BPIC(i),
3-BPIC,
and
3-BPIC-F,
which
exhibit
an
increasing
moment
sequence.
Compared
centrosymmetric
axisymmetric
3-BPIC
3-BPIC-F
higher
adsorption
energies
(Eads)
ITO,
shorter
interface
spacing,
more
uniform
coverage
ITO
surface,
better
interfacial
compatibility
active
layer.
Thanks
incorporation
fluorine
atoms,
exhibits
deeper
highest
occupied
molecular
orbital
(HOMO)
energy
level
larger
compared
resulting
enlarged
work
function
(WF)
ITO/3-BPIC-F
substrate.
These
advantages
could
not
only
improve
within
device
but
also
lower
impedance
reduce
nonradiative
recombination
at
interface.
As
result,
OSCs
using
SAM
based
obtained
record
high
efficiency
19.71%,
is
than
that
achieved
from
3-BPIC(i)
(13.54%)
(19.34%).
Importantly,
3-BPIC-F-based
significantly
enhanced
stability
utilizing
HEL.
Our
offers
guidance
future
design
functional
SAMs
realize
even
performance
cells.
ACS Energy Letters,
Journal Year:
2024,
Volume and Issue:
9(4), P. 1880 - 1887
Published: April 2, 2024
Carbazole-based
self-assembled
monolayers
(SAMs)
at
the
interface
between
metal-halide
perovskite
(MHP)
and
transparent
conducting
oxide
(TCO)
serve
function
of
hole-transport
layers
in
p-i-n
"inverted"
solar
cells
(PSCs).
Here
we
show
that
use
an
iodine-terminated
carbazole-based
SAM
increases
interfacial
mechanical
adhesion
dramatically
(2.6-fold)
this
is
responsible
for
substantial
improvements
morphology,
photocarrier
transport,
operational
stability.
While
improved
morphology
optoelectronic
properties
impart
high
efficiency
(up
to
25.39%)
PSCs,
enhanced
suppresses
nucleation
propagation
pores/cracks
during
PSC
operation,
resulting
retention
96%
initial
after
1000
h
continuous-illumination
testing
maximum
power-point.
This
demonstrates
strong
connection
judicious
toughening
simultaneous
enhancement
stability
with
broader
implications
reliability
durability
photovoltaics
before
they
can
be
commercialized.
Advanced Energy Materials,
Journal Year:
2024,
Volume and Issue:
14(22)
Published: March 11, 2024
Abstract
Trap
states
in
organic
solar
cells
(OSCs)
can
capture
free
charges,
leading
to
a
reduction
current
density
and
significant
energy
loss.
Since
charge
collection
is
primarily
dependent
on
the
interface
layer,
minimizing
trap
at
interfaces
effectively
suppress
losses,
topic
that
has
been
rarely
explored.
Herein,
an
strategy
proposed
by
combining
Me‐4PACz
PEDOT:PSS
mitigate
trap‐assisted
nonradiative
recombination
hole
transport
layer
(HTL).
OSCs
based
Me‐4PACz/PEDOT:PSS
exhibit
reduced
densities
low
losses
compared
devices
fabricated
with
single‐layer
HTL.
This
be
attributed
lower
rate
during
interface.
Changes
work
function
of
two
interlayers
due
contact
result
existence
built‐in
potential
inside
composite
interlayer,
promoting
reducing
loss
from
recombination.
Furthermore,
HTL
induces
vertical
phase
separation
active
improvements
fill
factor
for
OSCs.
As
result,
high
power
conversion
efficiencies
(PCEs)
18.70%
19.02%
are
achieved
binary
all‐polymer
polymer
donor/small
molecule
acceptor
cells,
respectively.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(33)
Published: June 21, 2024
Abstract
Self‐assembled
molecules
(SAMs)
have
shown
great
potential
in
the
application
of
optoelectronic
devices
due
to
their
unique
molecular
properties.
Recently,
emerging
phosphonic
acid‐based
SAMs,
2‐(9Hcarbazol‐9‐yl)ethyl]phosphonic
acid
(2PACz),
successfully
applied
perovskite
solar
cells
(PSCs),
organic
(OSCs)
and
light
emitting
diodes
(PeLEDs).
More
importantly,
impressive
results
based
on
2PACz
SAMs
are
reported
recently
succession.
Therefore,
it
is
essential
provide
an
insightful
summary
promote
further
development.
In
this
review,
molecule
design
strategies
about
first
concluded.
Subsequently,
work
systematically
reviews
recent
advances
its
derivatives
for
single
junction
PSCs,
tandem
OSCs
PeLEDs.
Finally,
concludes
discusses
future
challenges
develop
devices.
Advanced Energy Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 5, 2025
Abstract
The
efficiency
of
organic
solar
cells
has
raised
drastically
in
the
past
years.
However,
there
is
an
undeniable
lack
hole
transport
layers
that
can
provide
high
carrier
selectivity,
low
defect
density,
and
processing
robustness,
simultaneously.
In
this
work,
issue
addressed
by
studying
generation
surface
passivation
nickel
oxide
(NiO
x
).
It
revealed
oxidation
state
species
on
NiO
lowers
contact
resistance
but
hinders
charge
extraction
when
employed
as
layer
cells.
By
using
them
coordination
centers,
a
straightforward
modification
strategy
implemented
(2‐(9H‐carbazol‐9‐yl)ethyl)phosphonic
acid
(2PACz)
enhances
increases
cell
from
11.46%
to
17.12%.
Additionally,
robustness
across
different
deposition
methods
carbazole
molecule
demonstrated.
Finally,
fine‐tuning
Fermi
level
various
carbazole‐based
molecules,
particular
with
((4‐(7H‐dibenzo[c,g]carbazol‐7‐yl)butyl)phosphonic
(4PADCB),
power
conversion
17.29%
achieved,
outstanding
combination
V
OC
0.888
fill
factor
80%.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 26, 2025
Heterojunction
interfaces
play
a
crucial
role
in
charge
carrier
transport,
influencing
the
overall
photovoltaic
performance
of
organic
solar
cells
(OSCs).
Despite
importance,
advancements
interfacial
engineering,
especially
optimizing
microstructure
and
nanomorphology,
have
not
kept
pace
with
research
on
photoactive
layers.
In
study,
strategy
is
explored
to
control
self-assembly
growth
alcohol-soluble
Me-4PACz
(4P)
used
as
hole
transport
layer
(HTL)
OSCs.
The
surface
architecture
modified
inorganic
Co
salts
via
Cu
doping
UV-ozone
treatments,
creating
smooth
top
an
increased
Co3+/Co2+
ratio
hydroxyl
groups.
This
meticulous
design
fine-tuned
assembly
behavior
self-assembled
molecules,
resulting
transition
from
spherical
aggregates
more
uniform
worm-like
morphology.
Additionally,
electrical
optical
properties
are
optimized
passivate
defects
enhance
wettability
solvents,
leading
improved
extraction
reduced
recombination
losses.
Consequently,
OSC
Cu-Co/4P
HTL
exhibited
highest
power
conversion
efficiency
20.42%
(certified
20.20%).
characteristic
universality
stability
make
potential
candidate
for
widespread
applications,
particularly
providing
rationalized
guidance
further
Solar RRL,
Journal Year:
2023,
Volume and Issue:
7(20)
Published: Aug. 24, 2023
Organic
solar
cells
(OSCs)
are
a
promising
emerging
photovoltaic
technology
for
energy
conversion.
Recently,
the
power
conversion
efficiencies
of
OSCs
have
been
improved
to
get
closer
their
Schottky–Queisser
limit.
However,
operational
stability
remains
as
major
challenge
ahead
deployment
practical
applications.
The
main
causes
OSC
instability
stem
from
poor
intrinsic
materials,
metastable
morphology
multicomponent
active
layer,
unstable
interfaces,
and
sensitivity
moisture
oxygen.
To
address
these
issues,
it
is
necessary
comprehensive
in‐depth
understanding
fundamentals
develop
an
integrated
solution
overcome
them.
Herein,
state‐of‐art
strategies
used
improve
aspects
material
design,
device
processing,
encapsulation
techniques,
in
hope
delivering
rational
solutions,
summarized.
In
end,
prospects
toward
future
development
efficient
stable
provided.
ACS Energy Letters,
Journal Year:
2023,
Volume and Issue:
8(10), P. 4104 - 4112
Published: Sept. 11, 2023
Molecular
doping
has
become
a
valuable
technique
for
enhancing
the
efficiency
of
high-performance
organic
photovoltaic
systems
(OPVs).
However,
number
known
dopant
molecules,
especially
n-type
ones,
that
enhance
PCE
OPVs
remains
limited.
In
this
study,
two
dopants,
ethyl
viologen
(EV)
and
methyl
(MV),
are
synthesized
incorporated
into
ternary
PM6:BTP-eC9:PC71BM
bulk
heterojunction
(BHJ)
OPVs.
Both
dopants
found
to
OPV
performance,
yielding
maximum
values
19.03%
18.61%,
respectively.
We
show
EV
MV
function
as
microstructure
modifiers,
π–π
stacking
while
increasing
absorption
coefficient
BHJs.
Moreover,
n-doping
balances
carrier
mobility
lifetime
reducing
bimolecular
recombination.
Our
results
demonstrate
potential
improve
performance
highly
efficient
levels
beyond
those
achievable
by
pristine
BHJ.