Synlett,
Journal Year:
2024,
Volume and Issue:
35(16), P. 1906 - 1908
Published: March 20, 2024
Abstract
An
attempted
aryl
selenium-catalyzed
formation
of
cis-chlorohydrins
from
alkenes
was
unsuccessful
but
led
to
an
electrochemical
investigation
for
the
trans-selective
chloroformyloxylation
cyclic
and
acyclic
in
moderate
good
yields.
Interestingly,
when
1,1-disubstituted
were
used,
corresponding
vinyl
chloride
derivatives
obtained,
application
1-phenylcyclohex-1-ene
allyl
derivative.
ACS Agricultural Science & Technology,
Journal Year:
2023,
Volume and Issue:
3(9), P. 720 - 724
Published: Aug. 17, 2023
Tetramethylthiuram
disulfide
(TMTD,
thiram)
is
one
of
the
most
important
fungicides
and
widely
used
in
agriculture
for
seed
treatment
crop
protection.
TMTD
produced
by
a
number
plants.
Its
annual
sales
are
estimated
at
tens
millions
US
dollars.
Traditional
chemical
synthesis
thiram
accompanied
formation
significant
amount
waste,
including
inorganic
salts,
thioacids,
polysulfides,
etc.
Herein,
we
report
an
advanced
method
its
structural
analogues
production,
which
based
on
usage
electric
current
as
key
participant.
Such
electrochemical
approach
avoids
application
oxidant
required
previous
processes
can
be
efficiently
scaled
up.
All
these
characteristics
make
developed
synthetic
quite
promising
both
economically
ecologically.
Organic Chemistry Frontiers,
Journal Year:
2024,
Volume and Issue:
11(9), P. 2566 - 2571
Published: Jan. 1, 2024
A
general,
efficient,
and
mild
Dha
electrochemical
modification
strategy
is
reported,
which
enables
a
divergent
route
to
various
α,α-disubstituted
amino
esters
via
anodic
cascade
oxidation
nucleophilic
attack.
Applied Organometallic Chemistry,
Journal Year:
2024,
Volume and Issue:
38(5)
Published: March 15, 2024
This
research
introduces
an
eco‐friendly
and
innovative
technique
for
efficiently
producing
p‐tolylmethanol
derivatives
4(a–k)
using
electro‐organic
synthesis
based
on
the
Grignard
reaction.
By
employing
electrochemical
methods,
this
approach
offers
several
advantages,
including
enhanced
reaction
efficiency
reduced
environmental
impact.
The
process
involves
generation
of
reagent,
followed
by
its
with
appropriate
substrates
to
yield
desired
derivatives.
Our
team
optimized
various
parameters
like
choice
solvent,
electrode
material,
conditions
achieve
high
yields
selectivity.
developed
method
demonstrated
outstanding
presents
a
fresh
environmentally
conscious
synthesizing
from
benzaldehyde
1(a–e)
bromobenzene
2(a–h)
via
reaction,
yielding
excellent
results
(85–93%).
resulting
compounds
were
comprehensively
characterized
melting
point,
1
H
NMR
spectroscopy,
CHN
analysis
verify
their
structures.
holds
significant
potential
as
sustainable
strategy
valuable
organic
compounds.
Synlett,
Journal Year:
2024,
Volume and Issue:
35(16), P. 1906 - 1908
Published: March 20, 2024
Abstract
An
attempted
aryl
selenium-catalyzed
formation
of
cis-chlorohydrins
from
alkenes
was
unsuccessful
but
led
to
an
electrochemical
investigation
for
the
trans-selective
chloroformyloxylation
cyclic
and
acyclic
in
moderate
good
yields.
Interestingly,
when
1,1-disubstituted
were
used,
corresponding
vinyl
chloride
derivatives
obtained,
application
1-phenylcyclohex-1-ene
allyl
derivative.
