Pristine metal-organic frameworks for next-generation batteries

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 494, P. 215361 - 215361

Published: Aug. 2, 2023

Language: Английский

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Unlocking Double Redox Reaction of Metal–Organic Framework for Aqueous Zinc‐Ion Battery

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(17)

Published: March 6, 2024

Abstract Metal–organic frameworks (MOFs) show wide application as the cathode of aqueous zinc‐ion batteries (AZIBs) in future owning to their high porosity, diverse structures, abundant species, and controllable morphology. However, low energy density poor cycling stability hinder feasibility practical application. Herein, an innovative strategy organic/inorganic double electroactive sites is proposed demonstrated obtain extra capacity enhance a manganese‐based metal–organic framework (Mn‐MOF‐74). Simultaneously, its storage mechanism systematically investigated. Moreover, profiting from coordination effect, Mn‐MOF‐74 features with stable structure ZnSO 4 electrolyte. Therefore, Zn/Mn‐MOF‐74 exhibit superior stability. This work aids development MOFs AZIBs.

Language: Английский

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A roadmap of recent advances in MXene@MOF hybrids, its derived composites: Synthesis, properties, and their utilization as an electrode for supercapacitors, rechargeable batteries and electrocatalysis

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 80, P. 110293 - 110293

Published: Jan. 5, 2024

Language: Английский

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Cutting-edge advancements in MXene-derived materials: Revolutionary electrocatalysts for hydrogen evolution and high-performance energy storage

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 506, P. 215722 - 215722

Published: Feb. 16, 2024

Language: Английский

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Boosting Ion Diffusion and Charge Transfer by Zincophilic Accordion Arrays to Achieve Ultrafast Aqueous Zinc Metal Batteries

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(14)

Published: Jan. 28, 2024

Abstract A key challenge to apply aqueous zinc metal batteries (AZMBs) as next‐generation energy storage device is improve the rechargeability at high current densities, which needed circumvent slowly ion diffusion in anode and sluggish charge transfer of Zn 2+ . Herein, a zincophilic accordion array derived from MOF developed host for simultaneously boosted transfer. The designed prepared by etching disproportionation reactions, abundant Sn sites with nano‐size uniform disperse on arrays nanosheets (Sn‐AA). Then composite (Sn‐AA@Zn) obtained compacting Sn‐AA power (Zn‐P). Sn‐AA@Zn has an ultra‐low activation (37.1 kJ mol −1 ) nucleation overpotential (10 mV), achieving fast Zinc deposition. In addition, cycle life symmetric cell exceeds 13 000 cycles 50 mA cm −2 , 32 times than that Zn‐P anode. And full MnO 2 cathode maintains capacity 122 mAh g after 5000 5 Ag Hopefully, 3D based significantly improved AZMB density.

Language: Английский

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Design strategies and energy storage mechanisms of MOF-based aqueous zinc ion battery cathode materials

Energy storage materials, Journal Year: 2024, Volume and Issue: 69, P. 103436 - 103436

Published: April 27, 2024

Language: Английский

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Metal-organic framework/mxene heterostructure and its derivatives as electrode materials for rechargeable Zn-based batteries: Design strategies and perspectives

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 484, P. 149624 - 149624

Published: Feb. 15, 2024

Language: Английский

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MOF/MXene Composites: Synthesis, Application and Future Perspectives

Advanced Sustainable Systems, Journal Year: 2024, Volume and Issue: 8(8)

Published: March 19, 2024

Abstract 2D MXenes family creates an interest in environmental cleaning and energy conversion. It shows large surface functional groups, electronic transmission, electrical conductivity. This research focuses on Metal Organic Framework‐based Ti 3 C 2 heterojunctions, directing morphology control, customizable structure, high performance ‐based electrocatalytic devices, storage as a supercapacitor. In addition, future development obstacles viable possibilities are presented. MXene detailed analysis reveals fundamental study, structure‐activity connections, potential paths for applications. Specially developed MOF/MXene nanoarchitectures with remarkable features highlighted several study fields, including the chemical sciences, engineering, physics, catalysis, nanotechnology. They represent new class of cutting‐edge developing materials. Mainly, presented review describes multiple synthesis approaches by adjusting conditions varying morphologies, intriguing properties can also be electrochemical conversion storage.

Language: Английский

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Channel engineering strategy of precisely modified MOF/nanofiber composite separator for advanced aqueous zinc ion batteries

Composites Part B Engineering, Journal Year: 2024, Volume and Issue: 272, P. 111227 - 111227

Published: Jan. 11, 2024

Language: Английский

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Metal-organic frameworks (MOFs) in aqueous batteries (ABs): unlocking potential through innovative materials design

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 8, 2025

Language: Английский

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