Enzymes’ Power for Plastics Degradation DOI
Vincent Tournier, Sophie Duquesne,

Frédérique Guillamot

et al.

Chemical Reviews, Journal Year: 2023, Volume and Issue: 123(9), P. 5612 - 5701

Published: March 14, 2023

Plastics are everywhere in our modern way of living, and their production keeps increasing every year, causing major environmental concerns. Nowadays, the end-of-life management involves accumulation landfills, incineration, recycling to a lower extent. This ecological threat environment is inspiring alternative bio-based solutions for plastic waste treatment toward circular economy. Over past decade, considerable efforts have been made degrade commodity plastics using biocatalytic approaches. Here, we provide comprehensive review on recent advances enzyme-based biocatalysis design related processes recycle or upcycle plastics, including polyesters, polyamides, polyurethanes, polyolefins. We also discuss scope limitations, challenges, opportunities this field research. An important message from that polymer-assimilating enzymes very likely part solution reaching

Language: Английский

Beyond Mechanical Recycling: Giving New Life to Plastic Waste DOI
Ina Vollmer, Michael J. F. Jenks, Mark Roelands

et al.

Angewandte Chemie International Edition, Journal Year: 2020, Volume and Issue: 59(36), P. 15402 - 15423

Published: March 11, 2020

Abstract Increasing the stream of recycled plastic necessitates an approach beyond traditional recycling via melting and re‐extrusion. Various chemical processes have great potential to enhance rates. In this Review, a summary various routes assessment life‐cycle analysis is complemented by extensive list developed companies active in recycling. We show that each currently available applicable for specific waste streams. Thus, only combination different technologies can address problem. Research should focus on more realistic, contaminated mixed streams, while collection sorting infrastructure will need be improved, is, stricter regulation. This Review aims inspire both science innovation production higher value quality products from suitable reuse or valorization create necessary economic environmental push circular economy.

Language: Английский

Citations

1274

Mechanical Recycling of Packaging Plastics: A Review DOI Creative Commons
Zoé O. G. Schyns, Michael P. Shaver

Macromolecular Rapid Communications, Journal Year: 2020, Volume and Issue: 42(3)

Published: Sept. 30, 2020

Abstract The current global plastics economy is highly linear, with the exceptional performance and low carbon footprint of polymeric materials at odds dramatic increases in plastic waste. Transitioning to a circular that retains its highest value condition essential reduce environmental impacts, promoting reduction, reuse, recycling. Mechanical recycling an tool environmentally economically sustainable plastics, but mechanical processes are limited by cost, degradation properties, inconsistent quality products. This review covers methods challenges for five main packaging plastics: poly(ethylene terephthalate), polyethylene, polypropylene, polystyrene, poly(vinyl chloride) through lens economy. Their reprocessing induced mechanisms introduced strategies improve their discussed. Additionally, this briefly examines approaches polymer blending mixed waste streams applications lower recyclate.

Language: Английский

Citations

1047

Critical advances and future opportunities in upcycling commodity polymers DOI
Coralie Jehanno, Jill W. Alty, Martijn Roosen

et al.

Nature, Journal Year: 2022, Volume and Issue: 603(7903), P. 803 - 814

Published: March 30, 2022

Language: Английский

Citations

776

Polyethylene upcycling to long-chain alkylaromatics by tandem hydrogenolysis/aromatization DOI
Fan Zhang,

Manhao Zeng,

Ryan Yappert

et al.

Science, Journal Year: 2020, Volume and Issue: 370(6515), P. 437 - 441

Published: Oct. 22, 2020

A new future for polyethylene Most current plastic recycling involves chopping up the waste and repurposing it in materials with less stringent engineering requirements than original application. Chemical decomposition at molecular level could, principle, lead to higher-value products. However, carbon-carbon bonds polyethylene, most common plastic, tend resist such approaches without exposure high-pressure hydrogen. F. Zhang et al. now report that a platinum/alumina catalyst can transform directly into long-chain alkylbenzenes, feedstock detergent manufacture, no need external hydrogen (see Perspective by Weckhuysen). Science , this issue p. 437 ; see also 400

Language: Английский

Citations

598

Closed-loop recycling of polyethylene-like materials DOI

Manuel Häußler,

Marcel Eck, Dario Rothauer

et al.

Nature, Journal Year: 2021, Volume and Issue: 590(7846), P. 423 - 427

Published: Feb. 17, 2021

Language: Английский

Citations

541

Plastic waste and its management strategies for environmental sustainability DOI Creative Commons
Evode Niyitanga, Sarmad Ahmad Qamar, Muhammad Bilal

et al.

Case Studies in Chemical and Environmental Engineering, Journal Year: 2021, Volume and Issue: 4, P. 100142 - 100142

Published: Sept. 27, 2021

The massive consumption of a wide range plastic products has generated huge amount waste. There is need to provide awareness their uses and routine management as part our lifestyle. Nowadays, plastics are increasingly being used in daily life activities, including the packaging different food brewing companies, cosmetics, pharmaceutical, other production sectors pack end for efficient safer product's delivery community. Plastics produced through biochemical process polymerization or polycondensation. post-use waste many adverse impacts on environment if not processed managed proper way. This review aims discuss lifecycle according categories, polyvinyl chloride (PVC–U), polystyrene styrofoam (PS), polypropylene (PP), high-density polyethylene (HDPE), terephthalate (PETE), others. Herein, we have also discussed problems caused by inadequate processing possible solutions that can be provided ensure good atmosphere reduce causes climate changes, which challenging this planet.

Language: Английский

Citations

494

Toward polymer upcycling—adding value and tackling circularity DOI
LaShanda T. J. Korley, Thomas H. Epps, Brett A. Helms

et al.

Science, Journal Year: 2021, Volume and Issue: 373(6550), P. 66 - 69

Published: July 1, 2021

Plastics have revolutionized modern life, but created a global waste crisis driven by our reliance and demand for low-cost, disposable materials. New approaches are vital to address challenges related plastics heterogeneity, along with the property reductions induced mechanical recycling. Chemical recycling upcycling of polymers may enable circularity through separation strategies, chemistries that promote closed-loop inherent macromolecular design, transformative processes shift life-cycle landscape. Polymer schemes lower-energy pathways minimal environmental impacts compared traditional chemical The emergence industrial adoption is encouraging, solidifying critical role these strategies in addressing fate driving advances next-generation materials design.

Language: Английский

Citations

468

Managing Plastic Waste─Sorting, Recycling, Disposal, and Product Redesign DOI Creative Commons
Jean‐Paul Lange

ACS Sustainable Chemistry & Engineering, Journal Year: 2021, Volume and Issue: 9(47), P. 15722 - 15738

Published: Nov. 12, 2021

Over the years, petrochemical industry has developed a plethora of polymers that are contributing to well-being humanity. Irresponsible disposal used plastics has, however, led buildup litter, which is fouling environment, harming wildlife, and wasting valuable resources. This paper critically reviews challenge opportunities in converting plastic waste into feedstock for industry. It discusses (a) amount, quality, sorting waste; (b) mechanical recycling extraction or dissolution/precipitation; (c) chemical monomers other chemicals; (d) by incineration, biodegradation, landfill, microplastics. will, finally, broaden circularity discussion with life-cycle analyses (LCA), design recycling, future role renewable carbon as feedstock.

Language: Английский

Citations

416

Chemolytic depolymerisation of PET: a review DOI Creative Commons

Elaine Barnard,

Jose Jonathan Rubio Arias, Wim Thielemans

et al.

Green Chemistry, Journal Year: 2021, Volume and Issue: 23(11), P. 3765 - 3789

Published: Jan. 1, 2021

We reviewed the current state of art poly(ethylene terephthalate) (PET) chemolysis used in chemical recycling PET.

Language: Английский

Citations

412

Catalytic processing of plastic waste on the rise DOI Creative Commons
Antonio J. Martín, Cecilia Mondelli, Shibashish D. Jaydev

et al.

Chem, Journal Year: 2021, Volume and Issue: 7(6), P. 1487 - 1533

Published: Jan. 10, 2021

Language: Английский

Citations

397