Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(25)
Published: April 27, 2023
Hydrogen-bonded
organic
frameworks
(HOFs)
show
great
potential
in
energy-saving
C2
H6
/C2
H4
separation,
but
there
are
few
examples
of
one-step
acquisition
from
because
it
is
still
difficult
to
achieve
the
reverse-order
adsorption
and
.
In
this
work,
we
boost
separation
performance
two
graphene-sheet-like
HOFs
by
tuning
pore
polarization.
Upon
heating,
an
situ
solid
phase
transformation
can
be
observed
HOF-NBDA(DMA)
(DMA=dimethylamine
cation)
HOF-NBDA,
accompanied
with
electronegative
skeleton
into
neutral
one.
As
a
result,
surface
HOF-NBDA
has
become
nonpolar,
which
beneficial
selectively
adsorbing
The
difference
capacities
for
23.4
cm3
g-1
uptake
ratio
136
%,
much
higher
than
those
(5.0
108
%
respectively).
Practical
breakthrough
experiments
demonstrate
could
produce
polymer-grade
(1/99,
v/v)
mixture
high
productivity
29.2
L
kg-1
at
298
K,
about
five
times
as
(5.4
).
addition,
theoretical
calculations
indicate
preferentially
capture
thus
boosts
selective
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(2), P. 464 - 484
Published: Jan. 1, 2022
This
tutorial
review
highlights
the
key
aspects
of
nanotoxicity
and
importance
its
systematic
assessment
for
metal–organic
framework
(MOF)
nanoparticles
to
pave
way
towards
their
potential
applications
in
a
safe
sustainable
manner.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(11), P. 10438 - 10483
Published: April 15, 2022
This
review
gives
an
authoritative,
critical,
and
accessible
overview
of
emergent
class
fluorescent
materials
termed
"LG@MOF",
engineered
from
the
nanoscale
confinement
luminescent
guests
(LG)
in
a
metal-organic
framework
(MOF)
host,
realizing
myriad
unconventional
with
fascinating
photophysical
photochemical
properties.
We
begin
by
summarizing
synthetic
methodologies
design
guidelines
for
representative
LG@MOF
systems,
where
major
types
guest
encompass
organic
dyes,
metal
ions,
complexes,
nanoclusters,
quantum
dots,
hybrid
perovskites.
Subsequently,
we
discuss
methods
characterizing
resultant
guest-host
structures,
loading,
properties,
local-scale
techniques
recently
employed
to
elucidate
positions.
A
special
emphasis
is
paid
pros
cons
various
context
LG@MOF.
In
following
section,
provide
brief
tutorial
on
basic
phenomena,
focusing
excited
state
events
effects
underpinning
exceptional
behavior
systems.
The
finally
culminates
most
striking
applications
materials,
particularly
"turn-on"
type
fluorochromic
chemo-
mechano-sensors,
noninvasive
thermometry
optical
pH
sensors,
electroluminescence,
innovative
security
devices.
offers
comprehensive
coverage
general
interest
multidisciplinary
community
stimulate
frontier
research
vibrant
sector
light-emitting
MOF
composite
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(30)
Published: April 29, 2023
Optimizing
the
electronic
structure
of
covalent
organic
framework
(COF)
photocatalysts
is
essential
for
maximizing
photocatalytic
activity.
Herein,
we
report
an
isoreticular
family
multivariate
COFs
containing
chromenoquinoline
rings
in
COF
and
electron-donating
or
withdrawing
groups
pores.
Intramolecular
donor-acceptor
(D-A)
interactions
allowed
tuning
local
charge
distributions
carrier
separation
under
visible
light
irradiation,
resulting
enhanced
performance.
By
optimizing
optoelectronic
properties
COFs,
a
uranium
extraction
efficiency
8.02
mg/g/day
was
achieved
using
nitro-functionalized
multicomponent
natural
seawater,
exceeding
performance
all
reported
to
date.
Results
demonstrate
effective
design
strategy
towards
high-activity
with
intramolecular
D-A
structures
not
easily
accessible
traditional
synthetic
approaches.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(24), P. 17241 - 17338
Published: Nov. 1, 2022
Current
energy
and
environmental
challenges
demand
the
development
design
of
multifunctional
porous
materials
with
tunable
properties
for
catalysis,
water
purification,
conversion
storage.
Because
their
amenability
to
de
novo
reticular
chemistry,
metal-organic
frameworks
(MOFs)
have
become
key
in
this
area.
However,
usefulness
is
often
limited
by
low
chemical
stability,
conductivity
inappropriate
pore
sizes.
Conductive
two-dimensional
(2D)
robust
structural
skeletons
and/or
functionalized
surfaces
can
form
stabilizing
interactions
MOF
components,
enabling
fabrication
nanocomposites
characteristics.
Graphene
its
functional
derivatives
are
largest
class
2D
possess
remarkable
compositional
versatility,
diversity,
controllable
surface
chemistry.
Here,
we
critically
review
current
knowledge
concerning
growth,
structure,
graphene
derivatives,
MOFs,
graphene@MOF
composites
as
well
associated
structure-property-performance
relationships.
Synthetic
strategies
preparing
tuning
also
comprehensively
reviewed
together
applications
gas
storage/separation,
catalysis
(organo-,
electro-,
photocatalysis),
electrochemical
storage
conversion.
hybrids
practical
addressed,
revealing
areas
future
investigation.
We
hope
that
will
inspire
further
exploration
new
energy,
electronic,
biomedical,
photocatalysis
studies
on
previously
unreported
known
reveal
potential
"diamonds
rough".
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(17), P. 7427 - 7508
Published: Jan. 1, 2022
Fluorinated
metal-organic
frameworks
(F-MOFs)
as
fast-growing
porous
materials
have
revolutionized
the
field
of
gas
separation
due
to
their
tunable
pore
apertures,
appealing
chemical
features,
and
excellent
stability.
A
deep
understanding
structure-performance
relationships
is
critical
for
synthesis
development
new
F-MOFs.
This
review
has
focused
on
several
strategies
precise
design
F-MOFs
with
structures
tuned
specific
purposes.
First,
basic
principles
concepts
well
structure,
modification
structure
property
are
studied.
Then,
applications
in
adsorption
membrane
discussed.
detailed
account
capabilities
various
gases
governing
provided.
In
addition,
exceptional
characteristics
highly
stable
engineered
size
put
into
perspective
fabricate
selective
membranes
separation.
Systematic
analysis
position
revealed
that
benchmark
most
challenging
separations.
The
outlook
future
directions
science
engineering
challenges
highlighted
tackle
issues
overcoming
trade-off
between
capacity/permeability
selectivity
a
serious
move
towards
industrialization.
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(7), P. 2544 - 2582
Published: Jan. 1, 2022
Metal
complexes
are
extensively
used
for
cancer
therapy.
The
multiple
variables
available
tuning
(metal,
ligand,
and
metal-ligand
interaction)
offer
unique
opportunities
drug
design,
have
led
to
a
vast
portfolio
of
metallodrugs
that
can
display
higher
diversity
functions
mechanisms
action
with
respect
pure
organic
structures.
Clinically
approved
metallodrugs,
such
as
cisplatin,
carboplatin
oxaliplatin,
treat
many
types
play
prominent
roles
in
combination
regimens,
including
immunotherapy.
However,
generally
suffer
from
poor
pharmacokinetics,
low
levels
target
site
accumulation,
metal-mediated
off-target
reactivity
development
resistance,
which
all
limit
their
efficacy
clinical
translation.
Nanomedicine
has
arisen
powerful
tool
help
overcome
these
shortcomings.
Several
nanoformulations
already
significantly
improved
the
reduced
toxicity
(chemo-)therapeutic
drugs,
some
promising
metallodrug-containing
nanomedicines
currently
trials.
In
this
critical
review,
we
analyse
challenges
assess
advantages
limitations
metallodrug
delivery,
both
nanocarrier
metal-nano
interaction
perspective.
We
describe
latest
most
relevant
nanomedicine
formulations
developed
metal
complexes,
discuss
how
rational
coordination
chemistry
technology
assist
promoting
translation
metallodrugs.
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(51)
Published: Oct. 21, 2022
Abstract
Metal‐organic
frameworks
(MOFs),
an
emerging
class
of
porous
organic‐inorganic
hybrid
materials,
have
shown
great
potential
for
water
and
wastewater
treatment
applications.
However,
pure
MOF
powders
limited
practical
applications
in
due
to
their
insolubility,
poor
processability,
brittleness,
safety
hazard
from
dust
formation,
difficult
separation
aqueous
solutions.
Thus,
exploring
MOFs
composites
with
improved
performance
is
importance.
The
marriage
electrospun
nanofiber
forethought
into
the
final
product's
morphology,
structure,
chemistry
has
opened
up
new
opportunities
efficient
treatment.
present
review
exhaustively
summarizes
strategies
integrate
nanofibers
via
electrospinning
remove
various
pollutants
(i.e.,
organic
dyes,
heavy
metal
ions,
pharmaceuticals,
personal
care
products,
oily
compounds,
solvents,
etc.)
adsorption,
photodegradation,
membrane
filtration.
Besides,
most
recent
advances
current
challenges
future
outlook
are
delineated.
Journal of the American Chemical Society,
Journal Year:
2021,
Volume and Issue:
143(48), P. 20055 - 20058
Published: Nov. 23, 2021
New
membrane
materials
with
excellent
water
permeability
and
high
ion
rejection
are
needed.
Metal-organic
frameworks
(MOFs)
promising
candidates
by
virtue
of
their
diversity
in
chemistry
topology.
In
this
work,
continuous
aluminum
MOF-303
membranes
were
prepared
on
α-Al2O3
substrates
via
an
situ
hydrothermal
synthesis
method.
The
exhibit
satisfying
divalent
ions
(e.g.,
93.5%
for
MgCl2
96.0%
Na2SO4)
the
basis
a
size-sieving
electrostatic-repulsion
mechanism
unprecedented
(3.0
L·m-2·h-1·bar-1·μm).
outperforms
typical
zirconium
MOF,
zeolite,
commercial
polymeric
reverse
osmosis
nanofiltration
membranes.
Additionally,
material
exhibits
good
stability
low
production
costs.
These
merits
recommend
as
next-generation
softening.
