Chem,
Journal Year:
2023,
Volume and Issue:
10(2), P. 504 - 543
Published: Oct. 16, 2023
Metal-organic
frameworks
(MOFs)
have
emerged
as
a
potential
platform
for
biomedical
applications
due
to
their
highly
tunable
porosities,
structural
diversity,
and
multi-functionality.
MOFs'
external
surface
modifications
endow
them
with
new
properties
functions,
such
hydrophilicity,
colloidal
stability,
controlled
payload
release,
specific
targeted
delivery,
biocompatibility.
These
attributes
greatly
improve
the
performance
use
of
MOFs
diagnosis
treatment
several
diseases.
In
this
review,
we
aim
offer
an
up-to-date
comprehensive
assessment
current
advances
in
development
functionalization
MOFs,
from
design
application.
This
review
summarizes
engineering
approaches,
highlighting
representative
examples
successful
healthcare
applications.
Finally,
discuss
remaining
challenges
limitations
field
while
foresighted
ideas
future
research
directions.
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(16), P. 7138 - 7169
Published: Jan. 1, 2022
MOFs
can
kill
the
bacteria
efficiently
by
multiple
mechanisms,
such
as
releasing
metal
ions
and/or
antibacterial
micro-molecules;
performing
catalytically
active
site;
acting
photosensitizers;
mimicking
enzymes;
based
on
gas
therapy
and
so
on.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(24), P. 17241 - 17338
Published: Nov. 1, 2022
Current
energy
and
environmental
challenges
demand
the
development
design
of
multifunctional
porous
materials
with
tunable
properties
for
catalysis,
water
purification,
conversion
storage.
Because
their
amenability
to
de
novo
reticular
chemistry,
metal-organic
frameworks
(MOFs)
have
become
key
in
this
area.
However,
usefulness
is
often
limited
by
low
chemical
stability,
conductivity
inappropriate
pore
sizes.
Conductive
two-dimensional
(2D)
robust
structural
skeletons
and/or
functionalized
surfaces
can
form
stabilizing
interactions
MOF
components,
enabling
fabrication
nanocomposites
characteristics.
Graphene
its
functional
derivatives
are
largest
class
2D
possess
remarkable
compositional
versatility,
diversity,
controllable
surface
chemistry.
Here,
we
critically
review
current
knowledge
concerning
growth,
structure,
graphene
derivatives,
MOFs,
graphene@MOF
composites
as
well
associated
structure-property-performance
relationships.
Synthetic
strategies
preparing
tuning
also
comprehensively
reviewed
together
applications
gas
storage/separation,
catalysis
(organo-,
electro-,
photocatalysis),
electrochemical
storage
conversion.
hybrids
practical
addressed,
revealing
areas
future
investigation.
We
hope
that
will
inspire
further
exploration
new
energy,
electronic,
biomedical,
photocatalysis
studies
on
previously
unreported
known
reveal
potential
"diamonds
rough".
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(14), P. 6065 - 6086
Published: Jan. 1, 2022
This
review
critically
evaluates
the
recent
advancements
in
understanding
of
endocytosis
nano-sized
metal–organic
frameworks
and
importance
biological
context
aiding
MOF
rational
design
synthesis
for
drug
delivery
applications.
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
34(43)
Published: Nov. 12, 2023
Abstract
Metal–organic
frameworks
(MOFs)
show
captivating
performances
in
many
large‐scale
applications
including
gas
adsorption
and
separation,
heat
reallocation,
water
production,
or
remediation
which
can
overcome
important
drawbacks
of
the
conventionally
used
porous
materials
industry.
This
raises,
therefore,
commercial
interest
MOFs
brings
necessity
to
decrease
cost
their
calling
for
synthesis
optimization
from
small‐scale
large‐scale.
However,
availability,
yet
very
limited,
is
highly
dependent
on
production
cost.
Thus,
promote
development
availability
MOFs,
steps
be
taken.
In
this
work,
state‐of‐art
first
outlined,
before
discussing
criteria
greener
MOF
processes.
Besides,
a
critical
evaluation
available
routes
given,
taking
into
consideration
cost,
environmental
impact,
safety,
feasibility.
Moreover,
since
there
are
strong
limitations
use
powder
form,
shaping
procedures
thus
discussed
briefly
outline
prospects
different
industrial
applications.
Finally,
importantly,
perspective
commercialization
highlighted
with
an
emphasis
techno‐economic
analyses
life‐cycle
assessments.
Chemical Engineering Journal,
Journal Year:
2023,
Volume and Issue:
471, P. 144400 - 144400
Published: June 25, 2023
Metal-organic
frameworks
(MOFs)
are
a
novel
class
of
crystalline
porous
materials,
consisting
metal
ions
and
organic
linkers.
These
hybrid
materials
possess
exceptional
porosity
specific
surface
area,
which
have
recently
garnered
significant
interest
due
to
their
potential
applications
in
gas
separation
storage,
energy
biomedical
imaging,
drug
delivery.
As
MOFs
being
explored
for
applications,
it
is
essential
comprehensively
assess
toxicity.
Although
nearly
ninety
thousand
been
investigated,
evaluating
optimizing
physico-chemical
properties
relevant
biological
systems
remain
critical
clinical
translation.
In
this
review
article,
we
first
provide
brief
classification
based
on
chemical
structures.
We
then
conduct
comprehensive
evaluation
