Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(25)
Published: April 27, 2023
Hydrogen-bonded
organic
frameworks
(HOFs)
show
great
potential
in
energy-saving
C2
H6
/C2
H4
separation,
but
there
are
few
examples
of
one-step
acquisition
from
because
it
is
still
difficult
to
achieve
the
reverse-order
adsorption
and
.
In
this
work,
we
boost
separation
performance
two
graphene-sheet-like
HOFs
by
tuning
pore
polarization.
Upon
heating,
an
situ
solid
phase
transformation
can
be
observed
HOF-NBDA(DMA)
(DMA=dimethylamine
cation)
HOF-NBDA,
accompanied
with
electronegative
skeleton
into
neutral
one.
As
a
result,
surface
HOF-NBDA
has
become
nonpolar,
which
beneficial
selectively
adsorbing
The
difference
capacities
for
23.4
cm3
g-1
uptake
ratio
136
%,
much
higher
than
those
(5.0
108
%
respectively).
Practical
breakthrough
experiments
demonstrate
could
produce
polymer-grade
(1/99,
v/v)
mixture
high
productivity
29.2
L
kg-1
at
298
K,
about
five
times
as
(5.4
).
addition,
theoretical
calculations
indicate
preferentially
capture
thus
boosts
selective
Journal of Functional Biomaterials,
Journal Year:
2022,
Volume and Issue:
13(4), P. 215 - 215
Published: Nov. 3, 2022
Bacterial
infections
pose
a
serious
threat
to
people’s
health.
Efforts
are
being
made
develop
antibacterial
agents
that
can
inhibit
bacterial
growth,
prevent
biofilm
formation,
and
kill
bacteria.
In
recent
years,
materials
based
on
metal
organic
frameworks
(MOFs)
have
attracted
significant
attention
for
various
applications
due
their
high
specific
surface
area,
enzyme-like
activity,
continuous
release
of
ions.
This
paper
reviews
the
progress
MOFs
as
agents,
focusing
preparation
methods,
fundamental
mechanisms,
strategies
enhance
effects.
Finally,
several
prospects
related
application
proposed,
aiming
provide
possible
research
directions
in
this
field.
ACS Materials Letters,
Journal Year:
2022,
Volume and Issue:
4(4), P. 751 - 757
Published: March 23, 2022
In
the
past
decade,
scientists
sought
to
engineer
nanomaterials
with
natural
enzymes-like
biological
function,
and
searched
for
newfangled
applications.
Herein,
we
show
first
example
of
utilizing
a
bimetal
metal–organic
framework
(MOF-818)
platform
mimicking
Cu/Zn-superoxide
dismutase
(Cu/Zn-SOD),
an
important
antioxidant
enzyme
that
specifically
scavenges
superoxide
anions.
Experimental
data
theoretical
calculations
reveal
high
Cu/Zn-SOD-like
activity
MOF-818
results
from
synergistic
catalysis,
which
is
analogous
Cu/Zn-SOD.
Such
biomimetic
process
allows
much
higher
SOD-like
activity,
compared
reported
monometallic
MOFs
mimics.
Moreover,
displays
excellent
stability
against
heating,
organic
solvents,
denaturant
treatments,
should
inactivate
enzymes.
Based
on
catalytic
mechanism,
also
construct
MOF-818-based
colorimetric
sensing
phosphorylated
peptides
proteins
detection.
This
work
provides
new
insight
engineering,
may
expedite
scale-up
applications
nanozymes
in
various
fields.
Analytical and Bioanalytical Chemistry,
Journal Year:
2023,
Volume and Issue:
415(11), P. 2005 - 2023
Published: Jan. 4, 2023
Abstract
The
deployment
of
metal–organic
frameworks
(MOFs)
in
a
plethora
analytical
and
bioanalytical
applications
is
growing
research
area.
Their
unique
properties
such
as
high
but
tunable
porosity,
well-defined
channels
or
pores,
ease
post-synthetic
modification
to
incorporate
additional
functional
units
make
them
ideal
candidates
for
sensing
applications.
This
possible
because
the
interaction
analytes
with
MOF
often
results
change
its
structure,
eventually
leading
intrinsic
physicochemical
which
then
transduced
into
measurable
signal.
porosity
allows
adsorption
very
efficiently,
while
pore
sizes/nature
and/or
installation
specific
recognition
groups
allow
modulating
affinity
towards
different
classes
compounds,
turn
lead
good
sensor
sensitivity
selectivity,
respectively.
Some
figures
are
given
illustrate
potential
MOF-based
sensors
most
relevant
application
fields,
future
challenges
opportunities
their
translation
from
academia
(i.e.,
laboratory
testing
properties)
industry
real-world
devices)
critically
discussed.
Graphical
abstract
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(25)
Published: April 27, 2023
Hydrogen-bonded
organic
frameworks
(HOFs)
show
great
potential
in
energy-saving
C2
H6
/C2
H4
separation,
but
there
are
few
examples
of
one-step
acquisition
from
because
it
is
still
difficult
to
achieve
the
reverse-order
adsorption
and
.
In
this
work,
we
boost
separation
performance
two
graphene-sheet-like
HOFs
by
tuning
pore
polarization.
Upon
heating,
an
situ
solid
phase
transformation
can
be
observed
HOF-NBDA(DMA)
(DMA=dimethylamine
cation)
HOF-NBDA,
accompanied
with
electronegative
skeleton
into
neutral
one.
As
a
result,
surface
HOF-NBDA
has
become
nonpolar,
which
beneficial
selectively
adsorbing
The
difference
capacities
for
23.4
cm3
g-1
uptake
ratio
136
%,
much
higher
than
those
(5.0
108
%
respectively).
Practical
breakthrough
experiments
demonstrate
could
produce
polymer-grade
(1/99,
v/v)
mixture
high
productivity
29.2
L
kg-1
at
298
K,
about
five
times
as
(5.4
).
addition,
theoretical
calculations
indicate
preferentially
capture
thus
boosts
selective
