ACS Applied Polymer Materials,
Journal Year:
2024,
Volume and Issue:
6(7), P. 3966 - 3974
Published: April 1, 2024
The
development
of
soft
eutectogels
that
are
highly
transparent,
stretchable,
self-healing,
self-adhesive,
recyclable,
and
can
be
used
for
underwater
sensing
applications
is
desirable.
Here,
with
multiple
functionalities
prepared
by
the
one-step
copolymerization
rigid
polymerizable
ionic
liquids
acrylate
monomers
in
a
hydrophobic
deep
eutectic
solvent
consisting
thymol/coumarin.
Poly(ionic
liquids)/polyacrylates
to
construct
tough
backbone
eutectogel
networks,
whereas
components
introduced
into
polymer
matrix
impart
dynamic
cross-linking
properties.
Overall,
network
has
excellent
hydrophobicity
intermolecular
interactions,
resulting
water
resistance,
mechanical
strength,
self-adhesion
behavior
even
aqueous
environments.
as
an
sensor
good
capability
detect
strain,
touch,
changes
surrounding
environment.
Moreover,
dynamically
cross-linked
easily
recycled
through
solvent.
methodology
proposed
this
study
holds
promise
future
fields
sensors,
wet
adhesives,
flexible
electronics.
Russian Chemical Reviews,
Journal Year:
2023,
Volume and Issue:
92(12), P. RCR5104 - RCR5104
Published: Dec. 1, 2023
After
the
appearance
of
green
chemistry
concept,
which
was
introduced
in
vocabulary
early
1990s,
its
main
statements
have
been
continuously
developed
and
modified.
Currently,
there
are
10–12
cornerstones
that
should
form
basis
for
an
ideal
chemical
process.
This
review
analyzes
accumulated
experience
achievements
towards
design
products
processes
reduce
or
eliminate
use
generation
hazardous
substances.
The
presents
views
leading
Russian
scientists
specializing
various
fields
this
subject,
including
homogeneous
heterogeneous
catalysis,
fine
basic
organic
synthesis,
electrochemistry,
polymer
chemistry,
based
on
bio-renewable
feedstocks
energetic
compounds
materials.
A
new
approach
to
quantitative
evaluation
environmental
friendliness
by
authors
is
described.
<br>
bibliography
includes
1761.
AIChE Journal,
Journal Year:
2023,
Volume and Issue:
69(11)
Published: Aug. 16, 2023
Abstract
This
article
proposes
for
the
first
time
preparation
of
a
series
amino
acid
ionic
liquids
(AAILs)
via
one‐step
hydrolysis
cheap
lactams
capture
CO
2
.
The
structures
prepared
AAILs
are
confirmed
using
NMR,
FTIR,
and
ESI‐MS,
their
physical
properties
also
determined.
It
is
found
that
these
reversible
absorbents
with
very
high
absorption
capacities
(0.15
to
0.18
g·g
−1
at
313.2
K
1.0
bar),
better
than
almost
all
task‐specific
reported
in
literatures.
mechanism
elucidated
be
combination
1:1
2:1
stoichiometric
reaction
from
equilibrium
thermodynamical
modeling
quantum
calculations.
have
advantages
simple
synthesis,
yield,
available
raw
materials.
believed
this
kind
great
potentials
used
as
efficient
absorbents.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(19), P. 11235 - 11265
Published: Jan. 1, 2024
A
green
solvent
hybrid
system
will
bring
about
sustainable
development
in
the
battery
industry
by
efficiently
and
environmentally
friendly
recycling
of
valuable
resources
contained
waste
batteries.
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(10), P. 5708 - 5743
Published: Jan. 1, 2024
Bio-upcycling
of
monomers
recovered
from
poly(ethylene
terephthalate)
(PET)
waste
is
a
novel
alternative
to
turn
recycling
process
more
economically
attractive
by
obtaining
several
products
with
higher
added
value.
Trends in Chemistry,
Journal Year:
2024,
Volume and Issue:
6(3), P. 100 - 114
Published: Feb. 5, 2024
Plastics
possess
highly
unsustainable
linear
life
cycles
that
are
environmentally
damaging.
With
low
recycling
rates
worldwide,
plastics
upcycling
is
emerging
as
a
promising
alternative
by
using
these
abundant
waste
products
chemical
feedstock
for
the
production
of
materials
and
essential
chemicals
higher
economic
value.
However,
saturated
C–C
polymer
backbones
polymers
constituting
~60%
all
plastic
unreactive
challenging
to
upcycle,
often
necessitating
energy-intensive
processes.
This
review
examines
state-of-the-art
sustainable
approaches
employing
Principles
Green
Chemistry
functionalize
or
cleave
backbones,
including
solvents,
Earth-abundant
metal
catalysis,
low-energy
approaches,
biocatalysis.
Such
strategies
will
enhance
attractiveness
practical
feasibility
achieve
circular
economy.
