Tunable multicolor supramolecular assemblies based on phosphorescence cascade energy transfer for photocatalytic organic conversion and anti-counterfeiting DOI

Rongxin Zhu,

Hui-Cong Ge,

Kaikai Niu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 675, P. 893 - 903

Published: July 9, 2024

Language: Английский

Phosphorescence resonance energy transfer from purely organic supramolecular assembly DOI
Xianyin Dai,

Man Huo,

Yu Liu

et al.

Nature Reviews Chemistry, Journal Year: 2023, Volume and Issue: 7(12), P. 854 - 874

Published: Nov. 22, 2023

Language: Английский

Citations

102
Stimuli-fluorochromic smart organic materials DOI
Yinjuan Huang, Lijian Ning,

Xiaomin Zhang

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(3), P. 1090 - 1166

Published: Jan. 1, 2024

This review highlights the developments in stimuli-fluorochromic π-conjugated solids beyond organometallic and organic light-responsive compounds, addressing design strategies, mechanisms, limitations, challenges, opportunities.

Language: Английский

Citations

80
Dynamic organic room-temperature phosphorescent systems DOI
Qian Zhou, Chaolong Yang,

Yanli Zhao

et al.

Chem, Journal Year: 2023, Volume and Issue: 9(9), P. 2446 - 2480

Published: June 20, 2023

Language: Английский

Citations

78
Substrate-Responsive Pillar[5]arene-Based Organic Room-Temperature Phosphorescence DOI
Huangtianzhi Zhu, Junkai Liu, Yitao Wu

et al.

Journal of the American Chemical Society, Journal Year: 2023, Volume and Issue: 145(20), P. 11130 - 11139

Published: May 8, 2023

Room-temperature phosphorescence (RTP) is a photophysical phenomenon typically associated with long-lived emission that can be detected by the unaided eye. Several natural proteins display RTP, as do certain artificial polymers. In both cases, RTP ascribed to effective intramolecular through-space electronic communication. However, small molecules internal communication enable are relatively rare. Herein, we describe an alkyl halide-responsive system consisting of meta-formylphenyl-bearing pillar[5]arene derivative supports charge transfer (TSCT) within pillararene cavity. Treatment bromoethane, heavy atom-containing guest for host, serves enhance emission. An isomeric para-formylphenyl-bearing proved ineffective in producing effect. Quantum chemical calculations based on single-crystal X-ray diffraction analyses provided insights into structural determinants governing TSCT between 1,4-dimethoxybenzene donor units and formylphenyl groups pillar[5]arene, well energy gaps intersystem crossing channels. We believe present mechanistic analysis provide foundation design new molecule tunable features.

Language: Английский

Citations

51
Multi‐stimulus Room Temperature Phosphorescent Polymers Sensitive to Light and Acid cyclically with Energy Transfer DOI
Yuqi Yang, Aisen Li, Yujie Yang

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(44)

Published: Aug. 19, 2023

Abstract The stimulus‐responsive room temperature phosphorescent (RTP) materials have endowed wide potential applications. In this work, by introducing naphthalene and spiropyran (SP) into polyacrylamide as the energy donor acceptor respectively, a new kind of brilliant dynamic color‐tunable amorphous copolymers were prepared with good stability processibility, afterglow emissions from green to orange in response stimulus photo or acid, thanks multi‐responsibility SP transfer between SP. addition deeply exploring inherent mechanism, these been successfully applied dynamically controllable applications information protection delivery.

Language: Английский

Citations

45
Supramolecular systems for bioapplications: recent research progress in China DOI
Yue‐Yang Liu, Xiao-Yong Yu, Yu‐Chen Pan

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: 67(5), P. 1397 - 1441

Published: March 22, 2024

Language: Английский

Citations

28
Targeting Compact and Ordered Emitters by Supramolecular Dynamic Interactions for High‐performance Organic Ambient Phosphorescence DOI
Guang‐Qiang Yin,

Jiayin Zhou,

Wei Lü

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(37)

Published: Feb. 9, 2024

Purely organic room-temperature phosphorescence (RTP) materials have received intense attention due to their fascinating optical properties and advanced optoelectronic applications. The promotion of intersystem crossing (ISC) minimalization nonradiative dissipation under ambient conditions are key prerequisites for realizing high-performance RTP; However, the ISC process is generally inefficient fluorogens populated triplet excitons always too susceptible be well stabilized by conventional means. Particularly, organizing fluorophores into compact ordered entities supramolecular dynamic interactions has proven a newly-emerged strategy boost greatly suppress non-radiative relaxations immensely, facilitating population stabilization access RTP. Consequently, well-defined emitters enable robust RTP emission even in solution state, thus extending Here, this review focused on timely brief introduction recent progress tailoring interactions. Their typical preparation strategies, properties, applications thoroughly summarized. In summary section, challenges perspectives field highlighted suggest potential directions future study.

Language: Английский

Citations

25
Engineering Tunable Ratiometric Dual Emission in Single Emitter‐based Amorphous Systems DOI
Hao Sun,

Menglu He,

Glib Baryshnikov

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(10)

Published: Jan. 8, 2024

Molecular emitters with multi-emissive properties are in high demand numerous fields, while these basically depend on specific molecular conformation and packing. For amorphous systems, special arrangement is unnecessary, but it remains challenging to achieve such luminescent behaviors. Herein, we present a general strategy that takes advantage of rigidity S

Language: Английский

Citations

17
Mechanical Stretch α‐Cyclodextrin Pseudopolyrotaxane Elastomer with Reversible Phosphorescence Behavior DOI Creative Commons
Yi Zhang, Yong Chen,

Jian‐Qiu Li

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(14)

Published: Feb. 4, 2024

Abstract Polyethylene glycol chains in two terminals of the naphthalene functional group are threaded into α‐cyclodextrin cavities to form pseudopolyrotaxane (NPR), which not only effectively induces phosphorescence by cyclodextrin macrocycle confinement, but also provides interfacial hydrogen bonding assembly function between polyhydroxy groups and waterborne polyurethane (WPU) construct elastomers. The introduction NPR endows elastomer with enhanced mechanical properties excellent room temperature phosphorescent (RTP) emission (phosphorescence remains water, acid, alkali, organic solvents, even at 160 °C high temperatures). Especially, reversible mechanically responsive behavior intensity increased three times under 200% strain) can be observed stretch recover process, owing strain‐induced microstructural changes further inhibiting non‐radiative transition vibration NPR. Therefore, changing supramolecular elastomers through stretching a new approach for luminescent materials.

Language: Английский

Citations

16
Revisiting organic charge-transfer cocrystals for wide-range tunable, ambient phosphorescence DOI Creative Commons

Anju Ajayan Kongasseri,

Shagufi Naz Ansari,

Swadhin Garain

et al.

Chemical Science, Journal Year: 2023, Volume and Issue: 14(44), P. 12548 - 12553

Published: Jan. 1, 2023

A wide-range tunable triplet charge-transfer ( 3 CT) phosphorescence emission is achieved by an intermolecular through-space cocrystallization approach using pyromellitic diimide as the acceptor and different donors.

Language: Английский

Citations

25