A Bio‐Inspired Multifunctional Hydrogel Network with Toughly Interfacial Chemistry for Highly Reversible Flexible Zinc Batteries DOI
Song Yang,

Qing Wu,

Yue Li

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(44)

Published: Aug. 8, 2024

Abstract Flexible and high‐performance aqueous zinc‐ion batteries (ZIBs), coupled with low cost safe, are considered as one of the most promising energy storage candidates for wearable electronics. Hydrogel electrolytes present a compelling alternative to liquid due their remarkable flexibility clear advantages in mitigating parasitic side reactions. However, hydrogel suffer from poor mechanical properties interfacial chemistry, which limits them suppressed performance levels flexible ZIBs, especially under harsh strains. Herein, bio‐inspired multifunctional electrolyte network (polyacrylamide (PAM)/trehalose) improved adhesive was developed via simple trehalose network‐repairing strategy stabilize chemistry dendrite‐free long‐life ZIBs. As result, trehalose‐modified PAM exhibits superior strength stretchability up 100 kPa 5338 %, respectively, well strong various substrates. Also, PAM/trehalose provides anti‐corrosion capability Zn anode regulates nucleation/growth, resulting achieving high Coulombic efficiency 98.8 long‐term stability over 2400 h. Importantly, Zn//MnO 2 pouch cell excellent cycling different bending conditions, offers great potential energy‐related applications beyond.

Language: Английский

Recent Progress in Using Covalent Organic Frameworks to Stabilize Metal Anodes for Highly‐Efficient Rechargeable Batteries DOI Creative Commons
Jianlu Sun, Fangyuan Kang,

Dongbo Yan

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(28)

Published: May 7, 2024

Abstract Alkali metals (e.g. Li, Na, and K) multivalent Zn, Mg, Ca, Al) have become star anodes for developing high‐energy‐density rechargeable batteries due to their high theoretical capacity excellent conductivity. However, the inevitable dendrites unstable interfaces of metal pose challenges safety stability batteries. To address these issues, covalent organic frameworks (COFs), as emerging materials, been widely investigated regular porous structure, flexible molecular design, specific surface area. In this minireview, we summarize research progress COFs in stabilizing anodes. First, present origins delve into advantages based on physical/chemical properties alkali metals. Then, special attention has paid application host design anodes, artificial solid electrolyte interfaces, additives, solid‐state electrolytes, separator modifications. Finally, a new perspective is provided from pore modulation, synthesis COFs.

Language: Английский

Citations

10
Lanternarene‐Based Self‐Sorting Double‐Network Hydrogels for Flexible Strain Sensors DOI

Zi‐Qi Gao,

Chuan‐Hong Liu,

Shuang‐Long Zhang

et al.

Small, Journal Year: 2024, Volume and Issue: 20(43)

Published: June 29, 2024

Conductive flexible hydrogels have attracted immense attentions recently due to their wide applications in wearable sensors. However, the poor mechanical properties of most conductive polymer limit utilizations. Herein, a double network hydrogel is fabricated via self-sorting process with cationic polyacrylamide as first and lantern[3

Language: Английский

Citations

10
Ultra-Thin Amphiphilic Hydrogel Electrolyte for Flexible Zinc-ion Paper Batteries DOI
Huan Xia, Wei Zhang, Chunyang Miao

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(18), P. 6507 - 6520

Published: Jan. 1, 2024

The paper-like ZIBs can be folded and unfolded using the Miura folding technique, enhancing areal energy density by a factor of 18.

Language: Английский

Citations

10
Hydrogels loaded with MSC‐derived small extracellular vesicles: A novel cell‐free tissue engineering system for diabetic wound management DOI Creative Commons
Weicheng Zhong,

Hao Meng,

Liqian Ma

et al.

View, Journal Year: 2024, Volume and Issue: 5(4)

Published: July 18, 2024

Abstract With the aging and obesity era, increasing incidence of diabetes diabetic complications, especially non‐healing wounds, imposes a serious economic burden on both patients society. The complex microenvironments, including hyperglycemia, bacterial infection, ischemia, nerve damage, lead to prolonged inflammation proliferation phase wounds. Mesenchymal stem cell‐derived small extracellular vesicles (MSC‐sEVs), which contain rich variety therapeutic molecules, have been chased for decades because their potential roles in cellular communication, tissue regeneration, drug delivery. As powerful tools controlled‐sustained release sEVs, biocompatible hydrogels applied wide range biomedical applications. Herein, we first summarize pathological features such as angiopathy, neuropathy, immune cell dysfunction. Then, discuss biological properties, performance, stability pure MSC‐sEVs. After that, components, application patterns, responsiveness hydrogels. Next, loading avenues MSC‐sEVs into hydrogel, behaviors sEVs from hydrogels, influence crosslinking method hydrogel‐sEV composites. Finally, provide an overview current applications loaded with novel cell‐free engineering system managing wounds propose critical unsolved issues. This review is expected meaningful guidance developing wound management.

Language: Английский

Citations

10
In‐Situ Spontaneous Electropolymerization Enables Robust Hydrogel Electrolyte Interfaces in Aqueous Batteries DOI
Liangyuan Chen, Tuo Xiao, Jin‐Lin Yang

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(21)

Published: March 23, 2024

Abstract Hydrogels hold great promise as electrolytes for emerging aqueous batteries, which establishing a robust electrode‐hydrogel interface is crucial mitigating side reactions. Conventional hydrogel fabricated by ex situ polymerization through either thermal stimulation or photo exposure cannot ensure complete interfacial contact with electrodes. Herein, we introduce an in electropolymerization approach constructing electrolytes. The spontaneously generated during the initial cycling of battery, eliminating need additional initiators polymerization. involvement electrodes synthesis yields well‐bonded and deep infiltrated electrode‐electrolyte interfaces. As case study, attest that, situ‐formed polyanionic Zn‐MnO 2 battery substantially improves stability kinetics both Zn anode porous MnO cathode owing to This research provides insight function electrolyte interfaces constitutes critical advancement designing highly durable batteries.

Language: Английский

Citations

9
Highly‐Entangled Hydrogel Electrolyte for Fast Charging/Discharging Properties in Aqueous Zinc Ion Batteries DOI Creative Commons

Zhaoxi Shen,

Yu Liu, Zhongheng Li

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 5, 2024

Abstract Aqueous zinc ion batteries coupling with conventional hydrogel electrolyte have the advantages of high safety, low cost, and simple manufacturing process while they are difficult for fast charging/discharging application scenarios due to sluggish kinetics. Herein, a new strategy is developed synthesizing highly‐entangled polyacrylamide (HE‐PAM) dramatically enhance transportation mechanical stability. The has lower ionic resistance strong elastic modulus. After being assembled into Zn/MnO 2 batteries, HE‐PAM exhibits excellent cycling stability high‐rate capability under current densities. Specifically, Zn//HE‐PAM//MnO battery can resist highest 35 A g −1 , which outperforms previously reported works. Moreover, also support in proton capacity retention rate 50% 50 . This progress on electrolytes boost development quasi‐solid‐state aspect.

Language: Английский

Citations

9
Strategies of regulating Zn2+ solvation structures toward advanced aqueous zinc-based batteries DOI
Hengwei Wang, Keliang Wang,

Enze Jing

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103451 - 103451

Published: May 11, 2024

Language: Английский

Citations

8
High‐Performance Fatigue‐Resistant Dual‐ Polyrotaxane Hydrogel Electrolytes for Flexible Aqueous Zinc‐Ion Batteries DOI Open Access

Junkang Xu,

Yiran Zhu, Qinghua Gui

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract This study presents a novel anti‐fatigue hydrogel electrolyte with slip‐ring structure for next‐generation flexible wearable energy storage systems. Conventional quasi‐solid aqueous zinc‐ion batteries (ZIBs) electrolytes often suffer from mechanical degradation under repeated stress, limiting practical use. To overcome this, dual‐Polyrotaxane (DPR)‐polyacrylic acid (PAA) unique architecture is synthesized, that enhances durability, self‐healing, and adhesion. The interwoven DPR PAA networks distribute stress evenly, ensuring high ionic conductivity while preventing zinc dendrites parasitic reactions uniform deposition during cycling.When applied to quasi‐solid‐state Zn‐MnO₂ battery, this achieves specific capacity of 295 mAh g⁻¹ MnO₂ at 0.5C, retains 147 5C, shows 81.52% retention after 1000 cycles. battery also demonstrates exceptional stability, pairs lasting over 1750 h 5 mA cm⁻ 2 . Furthermore, it maintains reliable operation stresses like pressing, folding, twisting, making ideal applications. work advances design, offering durable, high‐performance solution

Language: Английский

Citations

1
Injectable, rapid self-healing, antioxidant and antibacterial nanocellulose-tannin hydrogels formed via metal-ligand coordination for drug delivery and wound dressing DOI
Min Li,

Yongxiang Mu,

Qinghua Xu

et al.

Industrial Crops and Products, Journal Year: 2023, Volume and Issue: 208, P. 117876 - 117876

Published: Dec. 2, 2023

Language: Английский

Citations

18
Long‐lifespan Zinc‐ion Capacitors Enabled by Anodes Integrated with Interconnected Mesoporous Chitosan Membranes through Electrophoresis‐driven Phase Separation DOI
Ruoyu Wang, Wenqiang Wang, Ming Sun

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(10)

Published: Jan. 18, 2024

Abstract The advancement of highly secure and inexpensive aqueous zinc ion energy storage devices is impeded by issues, including dendrite growth, hydrogen evolution corrosion anodes. It essential to modify the interface anodes that homogenizes flux facilitates reversible planarized deposition stripping. Herein, coupling coordination with acid‐base neutralization under driving electrophoresis, manageable mesoscopic phase separation for constructing chitosan frameworks was achieved, thereby fabricating interconnected mesoporous membranes based heterogeneous quasi‐solid‐state electrolytes integrated framework constructed twisted nanofiber bundles, forming a three‐dimensional continuous spindle‐shaped pore structure. With this framework, electrolyte provides exceptional conductivity 25.1 mS cm −1 , puncture resistance strength 2.3 GPa. In addition, amino groups molecule can make surface positively charged. Thus, successfully induced synergistic effect stress constraint electrostatic modulation. As result, as‐assembled capacitor has an excellent cycle life sustains capacity over 95 % after 20000 cycles at current density 5 A g . This research presents constructive strategy stable electrolytes‐integrated

Language: Английский

Citations

7