Crosslinking‐Driven Chemical Homogeneity Enhances Performance of Pre‐Seeded Perovskite Solar Cells DOI
Xiaoyu Zhang, Linqing Wang,

Shafidah Shafian

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 24, 2024

Abstract Perovskite solar cells (PSCs) have achieved impressive efficiency, but their commercialization is limited by issues like chemical homogeneity within the perovskite films, leading to defects and phase segregation, which severely compromise stability performance of PSCs. This study presents a novel approach overcoming these barriers employing N,N ‐methylenebisacrylamide (MBA) as multifunctional crosslinking agent structure. MBA enhances uniformity both laterally vertically, improves crystallinity, boosts overall film forming robust crosslinked network that regulates nucleation growth dynamics during pre‐seeding process. modification ensures uniform distribution matrix significantly reduces defect densities. As result, MBA‐treated PSCs notable improvement in power conversion efficiency (PCE), reaching up 24.26%, compared 22.64% control devices. Additionally, MBA‐modified devices demonstrated remarkable stability, maintaining 90% initial after 1200 h continuous illumination, contrast 50% loss observed just 500 h. These findings underscore transformative potential an additive PSCs, offering viable pathway not only enhance also improve long‐term devices, thus bringing closer commercial viability.

Language: Английский

Melamine holding PbI2 with three “arms”: an effective chelation strategy to control the lead iodide to perovskite conversion for inverted perovskite solar cells DOI

Shizi Luo,

Shuguang Cao,

Tongjun Zheng

et al.

Energy & Environmental Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Herein, we have proposed a novel tridentate chelation strategy to manage the excessive amount of unreacted PbI 2 in perovskite films, achieving inverted PSC device with PCE 25.66% by sequential deposition method.

Language: Английский

Citations

3
Direct Ink Writing of Single‐Crystal‐Assembled Perovskite Thick Films for High‐Performance X‐ray Flat‐Panel Detectors DOI Open Access
Yulong Wang, Xiuwen Xu, Guansheng Xing

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

Abstract Halide perovskites hold great potential in developing next‐generation X‐ray detectors. However, preparing high‐quality and thick perovskite films a way compatible with thin‐film transistor (TFT)‐integrated flat‐panel detectors (XFPDs) remains challenging. Here, by engineering ink effective printability shape fidelity, direct writing (DIW) is developed as new approach to printing unique single‐crystal‐assembled (SCAP) film. In contrast polycrystalline grains consisting of randomly orientated crystal domains, the SCAP made tightly packed crystals well‐defined facets, showing 3–4 orders magnitude lower trap density (4.48 × 10 12 cm −3 ). Consequently, offers state‐of‐the‐art detection performance (sensitivity‐to‐dark current ratio: 1.26 11 µC Gy air −1 A ), low limit (114.2 nGy s negligible baseline drift (0.27 fA V Furthermore, XFPD based on 64 pixelated TFT array realizes high‐resolution digital radiography, opening avenue for further development

Language: Английский

Citations

2
Recent Progress and Advances of Perovskite Crystallization in Carbon‐Based Printable Mesoscopic Solar Cells DOI Open Access
Junwei Xiang,

Chuanzhou Han,

Yanjie Cheng

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Carbon-based printable mesoscopic solar cells (p-MPSCs) offer significant advantages for industrialization due to their simple fabrication process, low cost, and scalability. Recently, the certified power conversion efficiency of p-MPSCs has exceeded 22%, drawing considerable attention from community. However, key challenge in improving device performance is achieving uniform high-quality perovskite crystallization within mesoporous structure. This review highlights recent advancements p-MPSCs, with an emphasis on controlling kinetics regulating morphology confined mesopores. It first introduces offering a solid foundation understanding behavior. Additionally, summarizes mechanisms crystal nucleation growth, explaining how these processes influence quality perovskites. Furthermore, commonly applied strategies enhancing quality, such as additive engineering, solvent evaporation controlling, post-treatment techniques, are also explored. Finally, proposes several potential suggestions aimed at further refining crystallization, inspiring continued innovation address current limitations advance development p-MPSCs.

Language: Английский

Citations

2
Materials and methods for cost-effective fabrication of perovskite photovoltaic devices DOI Creative Commons
Chunyang Zhang, Nam‐Gyu Park

Communications Materials, Journal Year: 2024, Volume and Issue: 5(1)

Published: Sept. 18, 2024

Language: Английский

Citations

12
Manipulating the crystallization kinetics of halide perovskites for large-area solar modules DOI Creative Commons
Zhaojin Wang, Xiaoming Duan, Jing Zhang

et al.

Communications Materials, Journal Year: 2024, Volume and Issue: 5(1)

Published: July 23, 2024

Abstract In the last decade, laboratory-scale single-junction perovskite solar cells have achieved a remarkable power conversion efficiency exceeding 26.1%. However, transition to industrial-scale production has unveiled significant gap. The central challenge lies in difficulty of achieving uniform, high-quality films on large scale. To tackle this issue, various innovative strategies for manipulating crystallization emerged recent years. Based an in-depth fundamental understanding nucleation and growth mechanisms large-area prepared through blade/slot-die coating methods, review offers critical examination manipulation modules. Lastly, we explore future avenues aimed at enhancing stability PSMs, thereby steering field toward commercially viable applications.

Language: Английский

Citations

9
Surface Engineering of Perovskite Films via Sequential Moisture Cooling and Passivation for Efficient Solar Cells DOI Open Access
Can Wang,

Zeping Ou,

Yi Pan

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Abstract Defect density on the perovskite film surface significantly exceeds that found in bulk, primarily due to presence of dangling bonds and excessive strain. Herein, a synergistic engineering is reported aimed at reducing defects films. This method involves subjecting thermally‐annealed films controlled cooling condition involving an ambient environment with regulated humidity, as opposed nitrogen environment, followed by phenethylammonium iodide (PEAI) passivation. The treated moisture (MC) exhibit enhanced radiative recombination, prolonged charge carrier lifetime, improved hole transport extraction when contact layer (HTL), alongside significant reduction Notably, passivation effect PEAI MC‐treated amplified compared subjected (NC) treatment, evidenced more uniform potential mapping markedly extended lifetime. may arise from higher ratio newly‐formed 2D phase PEA 2 FAPb I 7 PbI 4 film. Consequently, MC‐based solar cell (PSC) achieves champion power conversion efficiency (PCE) 25.28%, surpassing NC‐treated device, which exhibits PCE only 24.01%.

Language: Английский

Citations

1
Next-generation solar energy: Progress, stability, and prospects of polymer-modified Perovskite solar cells; A review DOI
Pei Zhang,

Huanggen Yang,

Qi Zheng

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 106, P. 1088 - 1113

Published: Feb. 8, 2025

Language: Английский

Citations

1
An energy-saving photo-rechargeable lithium-ion battery based on lead-free hybrid perovskite DOI
Xiaojing Yin,

Guangran Di,

Ye Liu

et al.

Science China Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 28, 2025

Language: Английский

Citations

1
Comprehensive Review on Slot‐Die‐Based Perovskite Photovoltaics: Mechanisms, Materials, Methods, and Marketability DOI Creative Commons
Ko Ko Shin Thant, Chaowaphat Seriwattanachai,

Thantham Jittham

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 5, 2024

Abstract As the world edges closer to perovskite solar cell (PSC) commercialization, state‐of‐the‐art materials and processes become publicized a much lesser degree. From current insights into industry standards, slot‐die coating is number one method for fabricating layer. Other significant layers can be done using varying techniques. Hence, in this review article, all 115 existing slot‐die‐based PSC publications date together with related literature are crystallized set stages future scalable research. Through investigation of effects materials, processes, structures on performance, stability, cost presented. In end, power output x operating lifetime per most influential factor market consideration. The roll‐to‐roll compatibility low‐cost lean present cost‐effective strategy successful commercialization.

Language: Английский

Citations

4
Colloidal Ink Engineering for Slot‐Die Processes to Realize Highly Efficient and Robust Perovskite Solar Modules DOI Open Access

Sushil S. Sangale,

Hyeji Son,

Sang Wook Park

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Abstract Perovskite solar cells (PSCs) have emerged as a promising alternative to silicon cells, but challenges remain in developing perovskite inks and processes suitable for large‐scale production. This study introduces novel approach using colloidal incorporating toluene chlorobenzene co‐antisolvents PSC fabrication via slot‐die process. It is found that are strategically engineered can significantly improve the rheological properties of inks, leading enhanced wettability high‐quality film formation. The formation large colloids such α cubic perovskite, δ hexagonal transition intermediate phases promotes heterogeneous nucleation lowers activation energy crystallization, resulting superior crystal growth improved morphology. Notably, co‐solvent enhances FA‐PbI 3 binding weakens dimethyl sulfoxide coordination, which more thermodynamically favorable crystallization. strategy yields devices with maximum efficiency 21.32% remarkable long‐term stability, retaining 77% initial over 10115 h. demonstrates scalability this approach, achieving 20.26% lab‐scale minimodules 19.15% larger convergence minimodules. These findings provide an understanding complex relationship between ink composition, properties, quality, crystallization kinetics, device performance.

Language: Английский

Citations

0