Metal–Organic Frameworks and Derivative Materials in Perovskite Solar Cells: Recent Advances, Emerging Trends, and Perspectives DOI
Syed Afaq Ali Shah, Muhammad Hassan Sayyad, Zhongyi Guo

et al.

Solar RRL, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 30, 2024

The power conversion efficiency (PCE) of perovskite solar cells (PSCs) has reached an impressive value 26.1%. While several initiatives such as structural modification and fabrication techniques helped steadily increase the PCE stability PSCs in recent years, incorporation metal–organic frameworks (MOFs) stands out among other innovations emerged a promising path forward to make this technology front‐runner for realizing next‐generation low‐cost photovoltaic technologies. Owing their unique physiochemical properties extraordinary advantages large specific surface area tunable pore structures, incorporating them as/in different functional layers endows devices with optoelectronic properties. This article reviews latest research practices adapted integrating MOFs derivative materials into constituent blocks photoactive absorber, electron‐transport layer, hole‐transport interfacial layer. Notably, special emphasis is placed on aspect improvement by materials. Also, potential lead absorbents highlighted. Finally, outlook critical challenges faced future perspectives employing light commercialization provided.

Language: Английский

Bandgap-engineered MXene-g-C3N4 interfacial layer for enhanced charge carrier dynamics in perovskite solar cells DOI

Fadwa Alshaeer,

Laith K. Obeas,

Mohammed Zorah

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 178247 - 178247

Published: Dec. 1, 2024

Language: Английский

Citations

7

Application of Ultrafast Lasers: A Promising Route toward the Fabrication of Advanced Perovskite‐Based Devices DOI Open Access
Yuhao Zhang,

Youqin Lin,

Zongmin Lin

et al.

Advanced Optical Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 25, 2025

Abstract Perovskite materials have received considerable research attention owing to their high carrier mobility, photoluminescence quantum yield, and light absorption coefficient. Their excellent optoelectronic properties low material costs make them a strong competitive raw for future electronic high‐temperature superconducting materials. In particular, when applied light‐emitting diodes (LEDs) solar cells, conversion efficiency relatively simple preparation process revolutionary that may change the pattern of perovskite‐based devices overcome limits industrialization. However, with development technology, traditional treatment methods perovskites no longer meet increasing demands industry. Laser technology is widely used its remarkable compatibility perovskite Therefore, this review summarizes applications laser materials, including laser‐induced nucleation film formation, annealing, ablation, printing, patterning, discusses achievements researchers in using regulate recent years, highlights prospects technology.

Language: Английский

Citations

1

Optimized perovskite photodetector achieved through optical manipulation via biomimetic nanostructure DOI
Qian Hu, Chi Ma,

J. Y. Zhang

et al.

Applied Physics Letters, Journal Year: 2025, Volume and Issue: 126(4)

Published: Jan. 27, 2025

Photodetectors with high integration and detectivity are in great demand for the development of wearable flexible electronic devices. However, limited photoelectric conversion efficiency at low film thickness has significantly hindered further applications both traditional semiconductors newly emerged perovskite materials. In this study, we have incorporated a biomimetic nanostructure inspired by lotus leaf onto active layer using modified two-step room temperature low-pressure nanoimprinting technique. This approach greatly improved quality material during spatially crystallization process. By incorporating optical nanostructure, achieved synergistic effect between enhanced scattering local surface plasmon resonances, leading to significant improvement incident light utilization efficiency. With incorporation observed remarkable enhancement 1100% photogenerated current 39.6% response speed. strategy provides viable designing high-efficiency ultra-thin photodetectors.

Language: Английский

Citations

1

A Close-Space Fast Nucleation Strategy toward High-Efficiency Perovskite Light-Emitting Diodes DOI

Xinwen Sun,

Dongliang Ding,

Zhiguo Nie

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 23, 2025

Halide perovskite light-emitting diodes (PeLEDs), considered as potential candidates for future displays, face significant limitations in their external quantum efficiency (EQE) due to an uncontrollable nucleation and crystallization process. Herein, a close-space inverted annealing (CSIA) strategy is developed achieve fast obtain more uniform film with larger crystal domains much lower defect centers. The increased surficial temperature quick solvent evaporation the CSIA method result formation of numerous large nuclei solvate intermediates at initial stage, which effectively guide growth into domains, facilitated by residual solvent. CSIA-processed PeLED achieves peak EQE 25.8%, among best values near-infrared devices. Moreover, it applicable perovskite-emitting layers different passivation agents. This straightforward approach highlights great opportunity boost performance commercialization optoelectronic

Language: Английский

Citations

0

Vertically oriented micron-thick perovskite film enables efficient and stable inverted perovskite solar cells DOI

Bing‐Hao Lv,

Yongchun Ye, J Wang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161966 - 161966

Published: March 1, 2025

Language: Английский

Citations

0

Vacuum Processability of Self-Assembled Monolayers and Their Chemical Interaction with Perovskite Interfaces DOI Creative Commons
Hyeji Han, Siwon Yun, Zobia Irshad

et al.

Energies, Journal Year: 2025, Volume and Issue: 18(7), P. 1782 - 1782

Published: April 2, 2025

Self-assembled monolayers (SAMs) have gained significant attention as an interfacial engineering strategy for perovskite solar cells (PSCs) due to their efficient charge transport ability and work function tunability. While solution-based methods such dip-coating spin-coating are widely used SAM deposition, challenges non-uniform coverage, solvent contamination, limited control over molecular orientation hinder scalability reproducibility. In contrast, vacuum deposition techniques, including thermal evaporation, overcome these limitations by enabling the formation of highly uniform materials with precise thickness arrangement. Importantly, chemical interactions between layers, coordination bonding Pb2+ ions, play important role in passivating surface defects, modulating energy levels, promoting crystallization. These not only enhance wettability but also improve overall quality stability films. This review highlights advantages vacuum-deposited SAMs, strong layers improving properties critical scalable applications.

Language: Английский

Citations

0

Ordered charge transport in supramolecular assemblies for enhancing the performance of HTL-free carbon-based perovskite solar cells DOI

J. Šíma,

Yi Xu,

Xiaoqing Cao

et al.

Journal of Physics and Chemistry of Solids, Journal Year: 2025, Volume and Issue: unknown, P. 112760 - 112760

Published: April 1, 2025

Language: Английский

Citations

0

Thiourea derivative induced crystallization for enhanced efficiency and stability of perovskite solar cells over 25% DOI
You Liu,

Hanzhong Xu,

Shulei Ji

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0

High-Performance Perovskite Solar Cells Enabled by Reduced MACl Additives in NMP-Based Solvents DOI Creative Commons
Jun Gong, Simon MoonGeun Jung,

Gyu Min Kim

et al.

Energies, Journal Year: 2025, Volume and Issue: 18(10), P. 2542 - 2542

Published: May 14, 2025

Methylammonium chloride (MACl) in perovskite solar cells (PSCs) is a key additive known to enhance film quality dimethyl sulfoxide (DMSO)-based systems, where an optimal concentration of 50 mol% typically required. However, alternative solvent such as N-methyl-2-pyrrolidone (NMP), have shown potential reduce concentrations while maintaining high performance. This study explored the NMP/DMF (1:9) system and its impact on MACl optimization. The NMP-based systems was reduced 20–30 mol%, representing substantial decrease from required DMSO-based formulations. Films produced under these conditions exhibited superior crystallinity, evidenced by narrower full-width at half maximum (FWHM) values X-ray diffraction (XRD), defect densities. These structural improvements translated into enhanced optoelectronic properties, with devices achieving efficiency exceeding 23%, compared ~20% for counterparts. Furthermore, demonstrated improved long-term stability continuous illumination.

Language: Английский

Citations

0

Strategies and Methods for Upscaling Perovskite Solar Cell Fabrication from Lab-Scale to Commercial-Area Fabrication DOI Creative Commons
Mengna Sun,

Zhi‐Qiang Jiao,

Peng Wang

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(10), P. 2221 - 2221

Published: May 20, 2025

Perovskite, as a promising candidate for the next generation of photovoltaic materials, has attracted extensive attention. To date, power conversion efficiency (PCE) perovskite solar cells (PSCs) reached 26.7%, which is competitive with that commercial silicon cells. However, high PCE usually achieved in devices small surface area fabricated by spin-coating method. Perovskite thin films, most important layer, suffer from poor uniformity and crystallization caused large-area fabrication process, leads to dramatic drop exhibits reproducibility. Here, we summarize common architectures PSC modules (PSMs), well analyzing reasons loss on modules. Subsequently, review describes mechanism growth detail, then sums up recent research small-to-large-area devices. Large-area methods mainly include blade coating, slot-die spray-coating, inkjet printing, screen printing. Moreover, compare advantages disadvantages each method their corresponding mechanisms progress. The aims provide potential logical conclusions directions process.

Language: Английский

Citations

0