Identification of Ni3Fe Alloy as a Candidate Catalyst for Quinoline Selective Hydrogenation with Computations DOI
Zhaochun He, Y.H. Liu, Tao Wang

et al.

Catalysis Science & Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

We computationally identified Ni 3 Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.

Language: Английский

Single-Atom Fe-Catalyzed Acceptorless Dehydrogenative Coupling to Quinolines DOI

Yanze Lu,

Zhu Meiling,

Sanxia Chen

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(33), P. 23338 - 23347

Published: Aug. 6, 2024

A single-atom iron catalyst was found to exhibit exceptional reactivity in acceptorless dehydrogenative coupling for quinoline synthesis, outperforming known homogeneous and nanocatalyst systems. Detailed characterizations, including aberration-corrected HAADF-STEM, XANES, EXAFS, jointly confirmed the presence of atomically dispersed centers. Various functionalized quinolines were efficiently synthesized from different amino alcohols a range ketones or alcohols. The achieved turnover number (TON) up 10

Language: Английский

Citations

12
Bifunctional Electrodes Enable Efficient Electrochemical Cycling of Quinoline DOI
Zhenye Zhang,

Xinliang Guo,

Li Yang

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Harnessing photocatalytic activity of mesoporous graphitic carbon nitride decorated by copper single-atom catalysts for oxidative dehydrogenation of N-heterocycles DOI
Rahul P. Gaikwad, Indrajeet R. Warkad, Dinesh S. Chaudhari

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 676, P. 485 - 495

Published: July 9, 2024

Language: Английский

Citations

3
Development of a Cobalt Catalyst from ZIF‐67 and Application in the Hydrogenation of N‐Heteroarenes DOI

Xinya Yuan,

Guangbin Zhou, Tianyi Zhou

et al.

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(25)

Published: May 18, 2024

Abstract Hydrogenation of N‐heteroarenes to saturated N‐heterocycles is an important reaction in organic synthesis. Hydrogen a green reducing reagent and has been widely applied industrial production. The development appropriate catalyst realize hydrogenation at low pressure temperature desired. In this study, we developed cobalt‐based derived from ZIF‐67 that exhibits high activity for N‐heteroarene under 5–20 bar hydrogen, which relatively as compared reported catalytic systems. This nano‐cobalt shows broad substrate scope can be reused without obvious loss.

Language: Английский

Citations

2
Colloidal Bimetallic RuNi Particles and their Behaviour in Catalytic Quinoline Hydrogenation DOI Creative Commons
Miquel Cardona-Farreny, Hiroya Ishikawa,

Abolanle Olatilewa Odufejo Ogoe

et al.

ChemPlusChem, Journal Year: 2024, Volume and Issue: 89(12)

Published: Sept. 13, 2024

Abstract Colloidal metal nanoparticles exhibit interesting catalytic properties for the hydrogenation of (hetero)arenes. Catalysts based on precious metals, such as Ru and Rh, promote this reaction efficiently under mild conditions. In contrast, heterogeneous catalysts earth‐abundant metals can selectively hydrogenate (hetero)arenes but require harsher Bimetallic that combine are materials to mitigate drawbacks each component. To end, RuNi bearing a phosphine ligand were prepared through decomposition [Ru(η 4 ‐C 8 H 12 )(η 6 10 )] [Ni(η ) 2 ] by at 85 °C. Wide angle X‐ray scattering confirmed bimetallic segregated structure, with Ni predominantly surface. Spectroscopic analyses revealed coordinated surface both suggesting, well, partial shell covering core. The RuNi‐based nanomaterials used in quinoline assess impact metallic composition stabilizing agent their performance.

Language: Английский

Citations

1
Acceptorless ambient-temperature dehydrogenation and reversible hydrogenation of N-heterocycles over single-atom Co-N-C catalysts DOI
Qingqing Li, Zhiwei Sun,

Yilin Wei

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 351, P. 123959 - 123959

Published: April 24, 2024

Language: Английский

Citations

0
Nanoparticles of Cobalt for the Reversible (De)Hydrogenation and Oxidative Dehydrogenation of N-Heterocycles under Mild Conditions DOI
Adarsha Mandal,

Manoj Pradhan,

Ankur Maji

et al.

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(9), P. 10182 - 10193

Published: April 29, 2024

Employing a same catalyst, the reversible acceptorless dehydrogenation–hydrogenation and oxidative dehydrogenation of N-heterocycles have rarely been explored in literature. Herein, we synthesized an earth-abundant, cheap, robust cobalt heterogeneous nanoparticles for hydrogenation as well under mild reaction conditions, which makes it attractive hydrogen storage purposes. easy-to-synthesize reusable library molecules was reversibly hydrogenated dehydrogenated presence several other reducible functional groups good to excellent yields. Notably, practical applicability protocol demonstrated by gram-scale synthesis few biologically important such angustureine, galipinine, aspernigerin. This inexpensive catalyst can be recycled up five times without considerable loss catalytic activity, inductively coupled plasma mass spectrometry (ICP-MS) analysis filtrate showed only trace amount leaching. Several control experiments kinetic studies were carried out understand mechanism.

Language: Английский

Citations

0
Harnessing Photocatalytic Activity of Mesoporous Graphitic Carbon Nitride Decorated by Copper Single-Atom Catalysts for Oxidative Dehydrogenation of N-Heterocycles DOI
Manoj B. Gawande, Rahul P. Gaikwad, Indrajeet R. Warkad

et al.

Published: Jan. 1, 2024

This work describes the application of Cu single-atom catalysts (SACs) in photocatalytic oxidative dehydrogenation N-heterocyclic amines to respective N-heteroaromatics through environmentally benign and sustainable pathways. The catalyst support, a mesoporous graphitic carbon nitride (mpg-C3N4) is synthesized one-step pyrolysis method, decoration over mpg-C3N4 support was achieved by simple microwave-assisted preparation method. decorated on (Cu@mpg-C3N4) characterized various characterization techniques, including XRD, UV-visible spectrometry, HRTEM, HAADF-STEM with EDS mapping, AC-STEM, elemental ICP-OES, XANES, EXAFS, BET surface area. These studies confirmed that Cu@mpg-C3N4 exhibited high area, nature, medium band gap, low metal loading. as-synthesized well-characterized photocatalyst then evaluated for its efficacy converting N-heterocycles into corresponding N-heteroaromatic compounds excellent selectivity (>99%). transformation using water as green solvent 30 W white light visible source, demonstrating catalyst's potential reactions.

Language: Английский

Citations

0
Identification of Ni3Fe Alloy as a Candidate Catalyst for Quinoline Selective Hydrogenation with Computations DOI
Zhaochun He, Y.H. Liu, Tao Wang

et al.

Catalysis Science & Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

We computationally identified Ni 3 Fe as a promising catalyst for the quinoline (QL) selective hydrogenation to 1,2,3,4-tetrahydroquinoline (py-THQL) using density functional theory calculations and microkinetic modeling.

Language: Английский

Citations

0