Synthesis of Cyclic (Alkyl)(amino)carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration DOI
Ankita Sharma, Vikas Tiwari, Ritu Yadav

et al.

Organometallics, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic (alkyl)(amino)carbenes (CAAC EtBICAAC) [(Me2CAAC)CuFe(η5-C5H5)(CO)2](1) [(EtBICAAC)CuFe(η5-C5H5)(CO)2] (2), respectively, featuring an iron–copper bond. Complex 1 demonstrates catalytic activity for selective 1,4-hydroboration reactions of pyridine derivatives. Detailed computational studies provide additional insights into the electronic structure 2 elucidate pathway.

Language: Английский

Recent advances in heavier Group 15 (P, As, Sb, Bi) radical chemistry – frameworks, small molecule reactivity, and catalysis DOI Creative Commons

Deana L. G. Symes,

Jason D. Masuda

Dalton Transactions, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

New developments in the area of heavier pnictogen-based radicals continue to be reported, along with small molecule reactivity and newly discovered catalytic reactions.

Language: Английский

Citations

0
Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications DOI
Ankita Sharma,

Unnikrishnan Nair K,

Subrata Kundu

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This review covers the synthesis, characterization, and reactivity of bicyclic(alkyl)(amino)carbenes (BICAACs) outlines diverse applications BICAACs in organometallic chemistry, metal-free catalysis, main-group chemistry.

Language: Английский

Citations

1
Synthesis of Cyclic (Alkyl)(amino)carbene-Stabilized Copper–Iron Heterobimetallic Complexes and Their Application in Pyridine Hydroboration DOI
Ankita Sharma, Vikas Tiwari, Ritu Yadav

et al.

Organometallics, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

In this report, we synthesized heterobimetallic complexes supported by cyclic and bicyclic (alkyl)(amino)carbenes (CAAC EtBICAAC) [(Me2CAAC)CuFe(η5-C5H5)(CO)2](1) [(EtBICAAC)CuFe(η5-C5H5)(CO)2] (2), respectively, featuring an iron–copper bond. Complex 1 demonstrates catalytic activity for selective 1,4-hydroboration reactions of pyridine derivatives. Detailed computational studies provide additional insights into the electronic structure 2 elucidate pathway.

Language: Английский

Citations

0