Synthesis of N-Arylpyrrolidines Using CO2 as C1 Source DOI
Yujia Zhou,

Qiao Kong,

Dao-Yong Zhu

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(10), P. 3185 - 3185

Published: Jan. 1, 2024

Language: Английский

Advances and challenges in the electrochemical reduction of carbon dioxide DOI Creative Commons

Jingyi Han,

Xue Bai,

Xiaoqin Xu

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(21), P. 7870 - 7907

Published: Jan. 1, 2024

This review highlights the structure–activity relationship of ECO 2 RR, provides a detailed summary advanced materials by analyzing electrocatalytic applications and reaction mechanisms, discusses challenges in both devices.

Language: Английский

Citations

49
MOF-based materials for electrochemical reduction of carbon dioxide DOI

Jian-Mei Huang,

Xiang‐Da Zhang,

Jiayi Huang

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 494, P. 215333 - 215333

Published: July 28, 2023

Language: Английский

Citations

45
Rare earth nanomaterials in electrochemical reduction of carbon dioxide DOI

Yingshan Xue,

Ping Wang,

Miao He

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 516, P. 215983 - 215983

Published: May 28, 2024

Language: Английский

Citations

14
Advances in rare earth catalysts for small molecule electrosynthesis☆ DOI

Junfeng Du,

Jing Yu,

Chaohui Guan

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 1, 2025

Language: Английский

Citations

1
Promoting Electrocatalytic CO2 Reduction to CO via Sulfur‐Doped Co‐N‐C Single‐Atom Catalyst† DOI Open Access
Zhiming Wei, Yuhang Liu, Jie Ding

et al.

Chinese Journal of Chemistry, Journal Year: 2023, Volume and Issue: 41(24), P. 3553 - 3559

Published: Aug. 16, 2023

Comprehensive Summary Electrocatalytic reduction of CO 2 to fuels and chemicals possesses huge potential alleviate current environmental crisis. Heteroatom doping in metal‐nitrogen‐carbon (M‐N‐C) single‐atom catalysts (SACs) has been found be capable promote the electrocatalytic reaction (CO RR). However, origin enhanced activity is still elusive. Here, we report that sulfur‐doped cobalt‐nitrogen‐carbon catalyst (Co 1 ‐SNC) exhibits superior RR performance compared sulfur‐free counterpart ‐NC). On basis situ attenuated total reflectance surface‐enhanced infrared absorption spectroscopy (ATR‐SEIRAS), kinetic isotope effect (KIE) theoretical calculation, it demonstrated sulfur can water activation, elevate d‐band center Co active site, reduce free energy *COOH intermediate formation. This work deepens understanding chemistry over heteroatom‐doped SACs for designing efficient processes.

Language: Английский

Citations

17
Long‐Range Confinement‐Driven Enrichment of Surface Oxygen‐Relevant Species Promotes C−C Electrocoupling in CO2 Reduction DOI
Fuping Pan, Xinyi Duan, Lingzhe Fang

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 14(7)

Published: Dec. 24, 2023

Abstract CO 2 reduction is a highly attractive route to transform into useful feedstocks, of which C products are more desired than 1 , yet face high kinetic barriers C−C electrocoupling. Here, the engineering pore‐enabled local confinement reaction environments reported for tuning enrichment surface‐adsorbed oxygen‐relevant species and establishment their pronounced benefits in promoting coupling over oxide‐derived Cu‐based catalysts. A new approach utilizing microphase separation block copolymer developed fabricate bicontinuous mesoporous CuO nanofibers (CuO‐BPNF). The enhanced from long‐range mesochannels enables adsorption OH ad /O on Cu surface at wide negative potential range −0.7 – −1.3 V reduction, cannot be achieved conventional deficient short‐range pores. Constant‐potential DFT calculations reveal that surface‐bound oxygen weakens *CO affinity with (111) lowers both *CO−CO dimerization hydrogenation enable *CO−CHO coupling. Accordingly, ‐to‐C Faradaic efficiency 74.7% CuO‐BPNF shown, significantly larger counterparts This work offers general design principle manage reactive steering pathways interfacial catalysis.

Language: Английский

Citations

14
Active hydrogen-controlled CO<sub>2</sub>/N<sub>2</sub>/NO<sub>x</sub> electroreduction:From mechanism understanding to catalyst design DOI Creative Commons

Hanle Liu,

Shunhan Jia, Limin Wu

et al.

The Innovation Materials, Journal Year: 2024, Volume and Issue: 2(1), P. 100058 - 100058

Published: Jan. 1, 2024

<p>The development of renewable-energy-powered electrocatalysis meets the need for sustainable society. With water as proton source, it enables efficient production chemicals and fuels from renewable resources like CO<sub>2</sub>, N<sub>2</sub>, NO<sub>x</sub> under ambient conditions. Hydrogen generated via dissociation is a crucial participant in transforming reactants into desired products, but also serves direct source undesired reactions when excess. In this review, we first present an overview functional mechanisms active hydrogen electroreduction CO<sub>2</sub>/N<sub>2</sub>/NO<sub>x</sub>. We then introduce range methods to enhance our understanding these mechanisms. Furthermore, detailed discussion design strategies aimed at regulating reduction CO<sub>2</sub>/N<sub>2</sub>/NO<sub>x</sub> provided. Finally, outlook on critical challenges remaining research area promising opportunities future considered.</p>

Language: Английский

Citations

5
Engineering Coordination Environment of Cobalt Center in Molecular Catalysts for Improved Photocatalytic CO2 Reduction DOI Open Access
Yuchen Wang, Jihong Zhang, Wei Yang

et al.

Chinese Journal of Chemistry, Journal Year: 2023, Volume and Issue: 41(23), P. 3305 - 3310

Published: Aug. 16, 2023

Comprehensive Summary The creation of effective and inexpensive catalysts is essential for photocatalytic CO 2 reduction. Homogeneous molecular catalysts, possessing definite crystal structures, are desirable to study the relationship between catalytic performance coordination microenvironment around center. In this report, we elaborately developed three Co(II)‐based with different microenvironments reduction, named [CoN 3 O]ClO 4 , ]ClO S]ClO respectively. optimal photocatalyst has a maximum TON 5652 in reduced which 1.28 1.65 times greater than that high electronegativity oxygen L 1 ( N ‐bis(2‐pyridylmethyl)‐ ‐(2‐hydroxybenzyl)amine) provides Co(II) centers low reduction potentials more stable *COOH intermediate, facilitates ‐to‐CO conversion accounts activity . This work researchers new insights development

Language: Английский

Citations

11
Rare‐earth Element‐based Electrocatalysts Designed for CO2 Electro‐reduction DOI

Hengan Wang,

Xinchen Kang, Buxing Han

et al.

ChemSusChem, Journal Year: 2023, Volume and Issue: 17(7)

Published: Dec. 18, 2023

Electrochemical CO

Language: Английский

Citations

11
Asymmetrically coordinated main group atomic In-S1N3 interface sites for promoting electrochemical CO2 reduction DOI
Yan Gao,

Jinlong Ge,

Jingqiao Zhang

et al.

Nano Research, Journal Year: 2024, Volume and Issue: 17(6), P. 5011 - 5021

Published: March 7, 2024

Language: Английский

Citations

3