The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(22), P. 16553 - 16563
Published: Oct. 28, 2024
Defluorinative cyclization of CF
Language: Английский
The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(22), P. 16553 - 16563
Published: Oct. 28, 2024
Defluorinative cyclization of CF
Language: Английский
Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(15), P. 4214 - 4218
Published: Jan. 1, 2024
A [3 + 1 1] cascade annulation reaction for the divergent construction of trisubstituted indolizines using sulfoxonium ylides, BrCF 2 CO Me and pyridinium salts as readily available substrates has been developed.
Language: Английский
Citations
5Organic Letters, Journal Year: 2024, Volume and Issue: 26(20), P. 4340 - 4345
Published: May 14, 2024
An unconventional [1 + 1 1] annulation process was developed for the construction of β,β-dithioketones by merging C–C and C–S bond cleavage. In this reaction, rongalite concurrently served as triple C1 units, dual sulfur(II) synthons, a reductant first time. Mechanism investigation indicated that reaction involved self-mediated valence state change rongalite. By performing step-economical method, challenging C5-substituted 1,3-dithiane can be achieved under mild simple conditions.
Language: Английский
Citations
3Organic Letters, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 27, 2024
A three-component annulation reaction and trifluoromethylation for the construction of 3-(trifluoromethyl)-4
Language: Английский
Citations
3Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: May 28, 2025
Comprehensive Summary A desulfonylative thiolation between heteroaryl sulfones and thiosulfonates for the efficient synthesis of sulfides was developed. The cross‐electrophile couplings proceeded effectively via old C–SO 2 bond cleavage new C–S formation in presence cheapest widely available iron powder as mediator under transition metal catalyst‐free conditions, leading to a wide array derived from benzo[ d ]thiazole, ]oxazole, thiazole, 1,3,4‐thiadiazole, 1 H ‐tetrazole modest excellent yields. In addition, reaction exhibited good functional group compatibility, protocol could also be applicable use selenosulfonate substrate subjected scale‐up with equal ease. Notably, unreacted readily recovered after by resorting attracting property magnetic stir bar iron.
Language: Английский
Citations
0The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(22), P. 16553 - 16563
Published: Oct. 28, 2024
Defluorinative cyclization of CF
Language: Английский
Citations
0