Decatungstate-Photocatalyzed Transformations of 2-Bromo-3,3,3-trifluoropropene for Selective Synthesis of Z/E-β-CF3-Enones DOI

Xiao-Ya Yuan,

Zhimin Lü,

Xianqiang Huang

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 2, 2024

Condition-controlled switchable and divergent transformations of cost-effective 2-bromo-3,3,3-trifluoropropene (BTP) aldehydes were realized using a decatungstate (TBADT)-photocatalyzed strategy. The hydroacylated products, i.e., β,β-Br,CF

Language: Английский

Potassium-modified carbon nitride photocatalyzed-aminoacylation of N‑sulfonyl ketimines DOI

Cailing Wu,

Shaojie Wu, Qifei Huang

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: 36(2), P. 110250 - 110250

Published: July 17, 2024

Language: Английский

Citations

8
Functionalization of 1,3‐Butadiene Derivatives under Photo/Electrocatalysis DOI

Yinghui Huang,

Linhui Shen,

Chunhua Ma

et al.

European Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 27(28)

Published: May 20, 2024

Abstract In recent years, the functionalization of 1,3‐butadiene has become an attractive strategy for constructing allyl compounds with molecular and structural complexity, current research focuses on synthetic chemistry organic synthesis. Compared traditional synthesis method, methods promoted by photochemistry or electrochemistry represent environmentally friendly mild strategy. this review, reactions under photochemical/electrochemical processes in years are reviewed according to classification systems, particular emphasis corresponding reaction mechanism, which lays a foundation further exploration new catalytic methods.

Language: Английский

Citations

5
Photocatalytic synthesis of polyfluoroalkylated dihydropyrazoles and tetrahydropyridazines DOI

Ling-Li Liu,

Chengli Xiang,

Changduo Pan

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 60(77), P. 10764 - 10767

Published: Jan. 1, 2024

A photocatalytic trifluoromethylation/cyclization reaction of

Language: Английский

Citations

4
Electroreductively driven C–H functionalization of arenes DOI
Pengfei Xie,

Anzai Shi,

Youai Qiu

et al.

Chem Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 101359 - 101359

Published: April 1, 2025

Language: Английский

Citations

0
Bichromophoric Ruthenium Complexes for Photocatalyzed Late-Stage Synthesis of Trifluoromethylated Indolizines DOI Creative Commons

Kevin Klaus Stefanoni,

Matthias Schmitz,

Johanna Treuheit

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Indolizines are a promising class of biologically active compounds. However, photocatalytic methods for their selective derivatization scarce in the literature. Herein, mild, simple, and chemoselective protocol synthesis 3-(trifluoromethyl)indolizine has been developed. The desired products were obtained good to excellent yields can be easily on gram scale. By tuning redox properties Ru-based photocatalyst, it is possible achieve competitive further apply optimized conditions broad variety substrates. This method tolerates many functional groups and, therefore, used late-stage functionalization. Our combined theoretical spectroscopic findings revealed that superior dyad-like ruthenium catalyst developed this study completely different electronic nature both key species crucial efficient photoredox catalysis compared commonly homoleptic complexes.

Language: Английский

Citations

0
Nd@g-C3N4 dual-functional photosynthesis and antitumor activities of 3-fluoroalkylated quinoxalin-2(1H)-ones DOI

Qiong-Hui Peng,

Ningbo Li,

Jia-Cheng Hou

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 111402 - 111402

Published: May 1, 2025

Language: Английский

Citations

0
CeCl3-Catalyzed C–H Alkylation of N-Sulfonyl Ketimines with Alkanes and Ether via Photoinduced Ligand-to-Metal Charge Transfer DOI
Bin Zhou, Min Dong, Wei Wang

et al.

The Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 89(24), P. 18337 - 18343

Published: Dec. 9, 2024

A cerium-catalyzed C–H alkylation of N-sulfonyl ketimines with low-cost and readily available alkanes as alkyl sources was developed. This transformation proceeded through the synergy photoinitiated ligand-to-metal charge transfer (LMCT) using a chlorine radical an HAT reagent air green oxidant. series alkylated were synthesized moderate to good yields in highly atom-economic manner under chemical oxidant-free conditions.

Language: Английский

Citations

2
Synthesis of Terminal Vinyl Phosphine Oxides via Desulfonative C—P Formation from Alkenyl Sulfonium Salts DOI

Jiangzhen An,

Qi‐Yan Lv, Kai Sun

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(12), P. 3747 - 3747

Published: Jan. 1, 2024

Language: Английский

Citations

2
Efficient Trifluoromethylation of Halogenated Hydrocarbons Using Novel [(bpy)Cu(O2CCF2SO2F)2] Reagent DOI Creative Commons

Xiong Wu,

Xin Qiu,

Wenrun Lou

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(12), P. 2849 - 2849

Published: June 14, 2024

This study introduces a novel trifluoromethylating reagent, [(bpy)Cu(O2CCF2SO2F)2], notable for not only its practical synthesis from cost-effective starting materials and scalability but also nonhygroscopic nature. The reagent demonstrates high efficiency in facilitating trifluoromethylation reactions with various halogenated hydrocarbons, yielding products good yields exhibiting broad functional group compatibility. development of [(bpy)Cu(O2CCF2SO2F)2] represents an advancement the field organic synthesis, potentially serving as valuable addition to arsenal existing agents.

Language: Английский

Citations

1
Catalyst-Free Synthesis of Novel α-Trifluoromethylated Tertiary Alcohols Bearing Azaarenes as Potential Antifungal Agents DOI
Nan Yang, Zhuang Wu, Mingxin Wang

et al.

Journal of Molecular Structure, Journal Year: 2024, Volume and Issue: unknown, P. 140042 - 140042

Published: Sept. 1, 2024

Language: Английский

Citations

1