Plastic‐to‐Treasure: Innovative advances in photo/electro‐catalytic upcycling technologies for commodity chemicals and fuels DOI Creative Commons

Yu Xuan Leiu,

Kelvin O. Lim,

Zi‐Jing Chiah

et al.

EcoEnergy, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Abstract Plastics are one of the greatest inventions 20 th century that bring convenience to mankind. Owing commercialization plastics, plastic pollution has become a petrifying environmental issue as demand for products overwhelms recycling rates. However, conventional methods (i.e., pyrolysis and gasification) require high pressure temperature treat waste plastic, resulting in ineluctably energy‐waste secondary pollution. On contrary, selective catalylic technologies provide green approach degrade plastics whilst also reforming them into value‐added chemicals fuels. In this review, innovative approaches, including photocatalysis, electrocatalysis, photoelectrocatalysis, have been comprehensively reviewed from perspective sustainable use resources. Distinctive emphasis is placed on highlighting merits each technology enlightening state‐of‐the‐art modification strategies strengthen pillars catalytic activities. The transformation with above techniques elaborated terms reaction conditions various substrates. With feasibility breakdown displayed study, insights challenges prospects upcycling underscored well facilitate society moving toward circular economy.

Language: Английский

Microscale structure optimization of catalyst layer for comprehensive performance enhancement in proton exchange membrane fuel cell DOI
Yu Zhou, Mingyang Wu, Kai Meng

et al.

Energy, Journal Year: 2024, Volume and Issue: 301, P. 131738 - 131738

Published: May 24, 2024

Language: Английский

Citations

8
Mechanistic study of the competition between carbon dioxide reduction and hydrogen evolution reaction and selectivity tuning via loading single-atom catalysts on graphitic carbon nitride DOI

Joel Jie Foo,

Sue‐Faye Ng, Mo Xiong

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: 16(34), P. 16015 - 16025

Published: Jan. 1, 2024

We computationally screened metal-single-atom catalysts (M-SAC) on carbon nitride for selective CO 2 reduction. NiCN significantly lowered the rate-determining potential conversion to formic acid via *OCHO key intermediate.

Language: Английский

Citations

4
Fueling the future of clean energy with self‐supported layered double hydroxides‐based electrocatalysts: A step toward sustainability DOI Creative Commons

Man‐Kei Wong,

Jian Yiing Loh,

Feng Ming Yap

et al.

InfoMat, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 5, 2024

Abstract Amid the ongoing transition toward renewable fuels, self‐supported layered double hydroxides (LDHs) are envisioned as propitious electrocatalysts for reinvigorating electrocatalysis realm, thereby facilitating environmental remediation and bolstering sustainable global energy security. Exploiting appealing attributes such unique lamellar structure, abundant active sites, tunable intercalation spacing compositional flexibility, LDHs boast remarkable activity, selectivity stability across diverse energy‐related applications. By virtue of addressing technological time prominence excavating their renaissance, this review first encompasses facile state‐of‐the‐art synthetic approaches alongside intriguing modification strategies, deciphering authentic structure–performance correlations advancing more robust precise catalyst design. Aside from this, heterostructure engineering employing diversified ranges coupling materials is highlighted, to construct ground‐breaking binder‐free LDHs‐based heterostructures endowing with unprecedented activity stability. Subsequently, milestone gained experimental research theoretical modeling frontier in multifarious electrocatalytic applications, including HER, OER, UOR, AOR, seawater splitting other fundamental conversion reactions rigorously unveiled. As a final note, brief conclusion presented an outline future prospects. Essentially, aspires offer enlightenment incite wise inspiration evolution innovative resilient next‐generation catalysts. image

Language: Английский

Citations

4
Orientation-Dependent Oxygen Evolution Catalytic Performance and Mechanistic Insights of Epitaxial Co9S8 Thin Films DOI
Yong Wang, Yi Chen, Hongyuan Zhou

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 4, 2025

Cobalt sulfide (Co9S8) nanomaterials exhibit an efficient electrochemical catalytic performance due to their unique properties and electronic structure. The preparation of epitaxial Co9S8 thin films with varying crystal orientations the study kinetics mechanisms remain significant gaps. This addresses (100), (110), (111) on yttrium-doped zirconia (YSZ) substrates using pulsed laser deposition. Characterization confirmed single-crystalline nature consistent thickness. Electrochemical measurements revealed a similar hydrogen evolution reaction (HER) across all but differences in oxygen (OER) performance. orientation showed best OER activity, current density 24.2 mA cm-2 at 1.8 V vs RHE, outperforming (100) (110) orientations, which achieved 14.5 6.7 cm-2, respectively. Density functional theory (DFT) calculations indicated that favored traditional four-electron transfer mechanism, lower theoretical overpotential (0.37 V). In contrast, demonstrated more complex adsorption behaviors, resulting higher 0.49 0.29 V, These results highlight reactivity different provide valuable insights for optimizing catalyst design enhance

Language: Английский

Citations

0
Tailoring g-C3N4 properties through P and K co-doping: advancing photocatalytic CO2 reduction to CH4 DOI
Ahmed Ismail, Muhammad Zahid, Tanveer Bilal Pirzadah

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163023 - 163023

Published: April 1, 2025

Language: Английский

Citations

0
Cyclo[16]carbon through the lens of density functional theory: Role of impurity decoration in hydrogen evolution reaction DOI

Ashvin Kanzariya,

Shardul Vadalkar,

L. K. Saini

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 71, P. 400 - 410

Published: May 22, 2024

Language: Английский

Citations

2
Strategic facet engineering of bismuth‐based photocatalysts for the applications in solar‐to‐chemical conversion DOI Creative Commons

Joel Jie Foo,

Zi‐Jing Chiah,

Sue‐Faye Ng

et al.

InfoScience., Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 5, 2024

Abstract Semiconductor photocatalysis is a promising tactic to simultaneously overcome global warming and the energy crisis as it can directly convert inexhaustible solar into clean fuels valuable chemicals, hence being employed in various applications. However, current performance of largely impeded by fast recombination photogenerated charge carriers insufficient light absorption. Among materials, bismuth‐based photocatalysts have stood out excellent candidates for efficient due their unique controllable crystal structures relatively narrow band gap. These features endow selective exposure active facets (facet engineering) wide absorption range, resulting tunable photocatalytic activity, selectivity, stability. Therefore, great potential use facet‐engineered applications (e.g., water splitting, CO 2 reduction, N fixation, H O production) achieve sustainable development. Herein, introduction provides overview this research, while synthesis, modification strategy, latest progress application were summarized highlighted review paper. Lastly, conclusion outlooks topic concluded give some insights direction focus future research.

Language: Английский

Citations

2
Review of 2-D support-based nanocomposites for electrocatalytic detection of pharmaceutical drugs DOI

Chellapandi Bhuvaneswari,

Sundaram Ganesh Babu

Journal of Materials Science, Journal Year: 2024, Volume and Issue: 59(26), P. 11687 - 11717

Published: June 20, 2024

Language: Английский

Citations

1
Ampere‐Level Hydrogen Generation via 1000 H Stable Seawater Electrolysis Catalyzed by Pt‐Cluster‐Loaded NiFeCo Phosphide DOI

Linlin Zhou,

Tong Wan,

Zhong Yang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

Abstract Seawater electrolysis can generate carbon‐neutral hydrogen but its efficiency is hindered by the low mass activity and poor stability of commercial catalysts at industrial current densities. Herein, Pt nanoclusters are loaded on nickel‐iron‐cobalt phosphide nanosheets, with obtained Pt@NiFeCo‐P electrocatalyst exhibiting excellent evolution reaction (HER) in alkaline seawater ampere‐level The catalyst delivers an ultralow HER overpotential 19.7 mV −10 mA cm −2 seawater‐simulating solutions, along a Pt‐mass 20.8 times higher than Pt/C under same conditions, while dropping to 8.3 upon five‐fold NaCl concentrated natural seawater. Remarkably, offers stable operation for over 1000 h 1 A brine electrolyte, demonstrating potential efficient long‐term electrolysis. X‐ray photoelectron spectroscopy (XPS), situ electrochemical impedance (EIS), Raman studies revealed fast electron charge transfer from NiFeCo‐P substrate enabled strong metal‐support interaction, which increased coverage H * accelerated water dissociation high valent Co sites. This study represents significant advancement development electrocatalysts sustainable generation

Language: Английский

Citations

1
Plastic‐to‐Treasure: Innovative advances in photo/electro‐catalytic upcycling technologies for commodity chemicals and fuels DOI Creative Commons

Yu Xuan Leiu,

Kelvin O. Lim,

Zi‐Jing Chiah

et al.

EcoEnergy, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Abstract Plastics are one of the greatest inventions 20 th century that bring convenience to mankind. Owing commercialization plastics, plastic pollution has become a petrifying environmental issue as demand for products overwhelms recycling rates. However, conventional methods (i.e., pyrolysis and gasification) require high pressure temperature treat waste plastic, resulting in ineluctably energy‐waste secondary pollution. On contrary, selective catalylic technologies provide green approach degrade plastics whilst also reforming them into value‐added chemicals fuels. In this review, innovative approaches, including photocatalysis, electrocatalysis, photoelectrocatalysis, have been comprehensively reviewed from perspective sustainable use resources. Distinctive emphasis is placed on highlighting merits each technology enlightening state‐of‐the‐art modification strategies strengthen pillars catalytic activities. The transformation with above techniques elaborated terms reaction conditions various substrates. With feasibility breakdown displayed study, insights challenges prospects upcycling underscored well facilitate society moving toward circular economy.

Language: Английский

Citations

0