Combination of Site-Wide and Real-Time Optimization for the Control of Systems of Electrolyzers DOI Creative Commons
Vincent Henkel, Lukas Peter Wagner, Felix Gehlhoff

et al.

Energies, Journal Year: 2024, Volume and Issue: 17(17), P. 4396 - 4396

Published: Sept. 2, 2024

The integration of renewable energy sources into an grid introduces volatility, challenging stability and reliability. To address these challenges, this work proposes a two-stage optimization approach for the operation electrolyzers used in green hydrogen production. This method combines site-wide real-time to manage fluctuating supply effectively. By leveraging dual use existing model, it is applied both optimization, enhancing consistency efficiency control strategy. Site-wide generates long-term operational plans based on forecasts, while adjusts response immediate fluctuations availability. validated through case study showing that can accommodate forecast deviations up 15%, resulting production 6.5% higher than initially planned during periods increased framework not only optimizes electrolyzer operations but also be other flexible resources, supporting sustainable economically viable management.

Language: Английский

Bifunctional Oxygen‐Defect Bismuth Catalyst toward Concerted Production of H2O2 with over 150% Cell Faradaic Efficiency in Continuously Flowing Paired‐Electrosynthesis System DOI
Qiqi Zhang,

Changsheng Cao,

Shenghua Zhou

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 4, 2024

The electrosynthesis of hydrogen peroxide (H

Language: Английский

Citations

10

Molybdate‐Modified NiOOH for Efficient Methanol‐Assisted Seawater Electrolysis DOI Creative Commons
Zhengquan Li, Youbin Zheng,

Wenhan Zu

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Abstract Seawater electrolysis holds great promise for sustainable, green hydrogen production but faces challenges of high overpotentials and competing chlorine evolution reaction (CER). Replacing the oxygen with methanol oxidation (MOR) presents a compelling alternative due to its lower anodic potential which mitigates risk CER. While NiOOH is known MOR activity, performance limited by sluggish non‐electrochemical kinetics Cl‐induced degradation. Herein, MoO 4 2− ‐modified electrocatalyst reported that significantly enhances MOR‐assisted seawater splitting efficiency. In situ leached from heterojunction optimizes adsorption facilitates proton migration, thereby accelerating steps in MOR. Additionally, adsorbed effectively repels Cl − , protecting electrodes ‐induced corrosion. The electrolyzer using NiMo||Ni(OH) 2 /NiMoO₄ requires only 1.312 V achieve 10 mA cm −2 substantially than conventional alkaline (1.576 V). Furthermore, it demonstrates remarkable stability, sustaining current densities (up 1.0 A ) over 130 h. This work promising strategy designing high‐performance electrocatalysts efficient sustainable seawater.

Language: Английский

Citations

1

Interface-engineering enhanced photocatalytic conversion of CO2 into solar fuels over S-type Co-Bi2WO6@Ce-MOF heterostructured photocatalysts DOI

Jiale Ren,

Qianfei Ma,

Hua Yang

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 691, P. 137452 - 137452

Published: March 29, 2025

Language: Английский

Citations

1

Copper-organic frameworks for electrocatalytic carbon dioxide reduction DOI
Fan Yang,

Deyu Zhu,

Chenfeng Xia

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 517, P. 216021 - 216021

Published: June 19, 2024

Language: Английский

Citations

7

Electrosynthesis of adipic acid with high faradaic efficiency within a wide potential window DOI Creative Commons
Xiang Liu, Yu‐Quan Zhu, Jing Li

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Sept. 3, 2024

Language: Английский

Citations

6

Accelerating electrocatalyst design for CO2 conversion through machine learning: Interpretable models and data-driven innovations DOI Creative Commons

Zijing Li,

Yingchuan Zhang, Tao Zhou

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: 1(3), P. 100029 - 100029

Published: July 19, 2024

Electrocatalytic conversion of CO2 into valuable products is a promising approach toward mitigating climate change and energy crisis. However, the product diversity multi-electron transfer pathways drive development numerous strategies for catalyst component active site modifications, leading to long journey rational electrocatalyst design. The integration machine learning (ML) with experimental workload provides an opportunity speed up materials discovery by automatically exploiting trends patterns from database. This review focuses on interpretability ML models in design, demonstrates reliable workflow based adequate catalytic data refined descriptors, satisfactory configuration model appropriate human intervention. Moreover, combination data-driven techs cutting-edge methodologies also discussed, which can serve as bridge between contemporary catalysis quantum chemistry. may provoke more ML-based innovations rationalization design novel net-zero industries.

Language: Английский

Citations

4

Microenvironment modulation induced by ethylene-glycol modification enables high activity in selective CO2 electroreduction over lead-based catalysts DOI

Yingying Shu,

Zhihao Wang, Zichen Song

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161963 - 161963

Published: April 1, 2025

Language: Английский

Citations

0

Regulating p-orbital of metallic bismuth nanosheets via transition-metal oxides enables advanced CO2 electroreduction DOI

Weibo Yin,

Bowen Liu, Xiaolei Wang

et al.

Science China Materials, Journal Year: 2024, Volume and Issue: 67(6), P. 1965 - 1974

Published: May 11, 2024

Language: Английский

Citations

2

Constructing a Stable Built-In Electric Field in Bi/Bi2Te3 Nanowires for Electrochemical CO2 Reduction Reaction DOI

Tingjie Mao,

Jiadong Chen,

Ren Wang

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(23), P. 10809 - 10816

Published: May 30, 2024

Electrochemically converting carbon dioxide (CO

Language: Английский

Citations

1

Microfluidic Reactors for Paired Electrosynthesis: Fundamentals, Applications and Future Prospects DOI Creative Commons
Xue Hao, Zhihao Zhao, Menglei Yuan

et al.

Green Energy & Environment, Journal Year: 2024, Volume and Issue: unknown

Published: June 1, 2024

Paired electrosynthesis has received considerable attention as a consequence of simultaneously synthesizing target products at both cathode and anode, whereas the related synthetic efficiency in batch reactors is still undesirable under certain circumstances. Encouragingly, laminar microfluidic reactor offers prospective options that possess controllable flow characteristics such enhanced mass transport, precise control ability to expand production scale progressively. In this comprehensive review, underlying fundamentals paired are initially summarized, followed by categorizing including parallel electrosynthesis, divergent convergent sequential linear electrosynthesis. Thereafter, holistic overview equipment, integral research methodology well channel extension scale-up strategies proposed. The established evaluated metrics further inspired applications This work stimulated overwhelming investigation mechanism discovery, material screening strategies, device assemblies.

Language: Английский

Citations

1