Ligand-Controlled C2- or C3-Selectivity Switching in the Palladium-Catalyzed C–H Arylation of Nonsubstituted 1H-Pyrrole DOI
Miyuki Yamaguchi,

Kazutaka Nakai,

Kengo Morioka

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 27(1), P. 141 - 146

Published: Dec. 30, 2024

The C2- or C3-selective direct C–H arylation of nonsubstituted 1H-pyrrole with aryl chlorides/nonaflates was achieved using catalysts derived from palladium and appropriate phosphine ligands. site selectivity the can be switched by changing ligands, realized for first time. tBuOLi played an important role in suppressing N-arylation accelerating C3-arylation.

Language: Английский

Binding Thermodynamics of 1,3-bis(((E-1H-pyrrol-2-yl) methylene) amino) propan-2-ol palladium(II) with HSA and Its Intercalative Behaviour in ctDNA DOI Creative Commons
Sheldon Sookai,

Ayanda Majoka,

Manuel A. Fernandes

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: 1334, P. 141880 - 141880

Published: Feb. 26, 2025

Language: Английский

Citations

1
Integrated Synthesis, Characterization, and Computational Analysis of 1H Pyrrole-1,2,4-Oxadiazole Hybrids as Anticancer Agents DOI
Sachin M. Sitapara, Jignesh H. Pandya, Khushal Patel

et al.

Journal of Molecular Structure, Journal Year: 2025, Volume and Issue: unknown, P. 142575 - 142575

Published: May 1, 2025

Language: Английский

Citations

0
Ligand-Controlled C2- or C3-Selectivity Switching in the Palladium-Catalyzed C–H Arylation of Nonsubstituted 1H-Pyrrole DOI
Miyuki Yamaguchi,

Kazutaka Nakai,

Kengo Morioka

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 27(1), P. 141 - 146

Published: Dec. 30, 2024

The C2- or C3-selective direct C–H arylation of nonsubstituted 1H-pyrrole with aryl chlorides/nonaflates was achieved using catalysts derived from palladium and appropriate phosphine ligands. site selectivity the can be switched by changing ligands, realized for first time. tBuOLi played an important role in suppressing N-arylation accelerating C3-arylation.

Language: Английский

Citations

0