Single-crystal-to-single-crystal MOF encapsulation of copper azide to prepare laser-sensitive primary explosives DOI

Ruibing Lv,

Pengyang Pan,

Zhenghang Luo

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(23), P. 8235 - 8245

Published: Jan. 1, 2024

A novel 2D energetic MOF [Cu(ATRZ)(N 3 ) 2 ] n was prepared by single-crystal-to-single-crystal transformation to encapsulating N − , which is a new copper azide variant with excellent safety and laser initiation performance.

Language: Английский

Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation DOI
Congcong Huang, Chuanqi Zhao, Qingqing Deng

et al.

Nature Catalysis, Journal Year: 2023, Volume and Issue: 6(8), P. 729 - 739

Published: Aug. 10, 2023

Language: Английский

Citations

63
Recent progress of metal-organic framework-derived composites: Synthesis and their energy conversion applications DOI
Yongteng Qian, Fangfang Zhang,

Shengxian Zhao

et al.

Nano Energy, Journal Year: 2023, Volume and Issue: 111, P. 108415 - 108415

Published: April 5, 2023

Language: Английский

Citations

50
Electrochemical Synthesis of High-Efficiency Water Electrolysis Catalysts DOI Creative Commons

Yang Wu,

Boxin Xiao,

Kunlong Liu

et al.

Electrochemical Energy Reviews, Journal Year: 2025, Volume and Issue: 8(1)

Published: Feb. 6, 2025

Language: Английский

Citations

2
Core‐Shell Hetero‐Framework derived Copper Azide Composites as Excellent Laser‐Ignitable Primary Explosives DOI
Chao Wang,

Hui‐Min Guo,

Rui Pang

et al.

Advanced Functional Materials, Journal Year: 2022, Volume and Issue: 32(46)

Published: Sept. 7, 2022

Abstract Laser initiation has attracted increasing interest owing to its extraordinary safety and high reliability. However, traditional metal complex‐based laser‐ignitable primary explosives are limited by input laser energy low detonation ability. In this study, an efficient explosive‐based copper azide is prepared constructing core‐shell hetero‐framework Cu‐MOF@COF as the precursor. The pyrolysis of hybrid material affords (CA) nanoparticle confined in a porous carbon shell, referred CA@C Shell. evenly coated shell functions light‐to‐heat conversion layer efficiently promoting process inside CA. Consequently, Shell can be initiated at lower thresholds (0.80 mJ 1064 nm). This value significantly than typical ignitable complex tetraamine‐cis‐bis(5‐nitro‐2H‐tetrazolato‐N 2 )cobalt(III)perchlorate (726 808 Moreover, successfully detonates secondary CL‐20 when it assembled micro‐detonator system. study offers unique method for performance applications.

Language: Английский

Citations

32
Sensitive structural motifs separately distributed in azide-based 3D EMOFs: a primary explosive with an excellent initiation ability and enhanced stability DOI

Yun‐Fan Yan,

Jian‐Gang Xu, Fei Wen

et al.

Inorganic Chemistry Frontiers, Journal Year: 2022, Volume and Issue: 9(22), P. 5884 - 5892

Published: Jan. 1, 2022

The unique type of molecular architectures with a remarkable initiation ability and enhanced stability is proposed. relationship between the structure sensitivity Cu(N 3 ) 2 -based primary explosive revealed.

Language: Английский

Citations

29
Ice templated honeycomb-like porous copper foam to improve the anisotropic thermal transfer property of phase change composites DOI

Pan Guo,

Chengzhi Zhao, Xu Wang

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 991, P. 174536 - 174536

Published: April 17, 2024

Language: Английский

Citations

7
Copper Azide-based Complexes without Repulsive Steric Clashes between Azides for Advanced Primary Explosives DOI

Yun‐Fan Yan,

Qian‐You Wang,

Meng Cui

et al.

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 472, P. 144982 - 144982

Published: July 22, 2023

Language: Английский

Citations

16
In-situ synthesis of MEMS compatible Al/Cu2HIO6/PVDF Metastable composites film with high combustion performance DOI
De-Yun Tang, Chuanhao Xu, Heng Ding

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 150773 - 150773

Published: March 28, 2024

Language: Английский

Citations

5
Energetic properties of copper azide nanoparticles encapsulated within a conductive porous matrix via electrosynthesis DOI
Chunpei Yu, Wenchao Zhang,

Mingchun Xian

et al.

Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 450, P. 138131 - 138131

Published: July 16, 2022

Language: Английский

Citations

20
A three-dimensional energetic coordination compound (BLG-1) with excellent initiating ability for lead-free primary explosives DOI
Guorong Lei,

Wenchuan Cheng,

Zujia Lu

et al.

Materials Horizons, Journal Year: 2023, Volume and Issue: 10(12), P. 5775 - 5781

Published: Jan. 1, 2023

Exploration of advanced lead-free primary explosives is a challenging issue in the field energetic materials. Herein, we designed and synthesized novel N-rich copper bromate coordination compound (ECC) [Cu(ATRZ)(BrO3)2]n (BLG-1, ATRZ: 4,4'-azo-1,2,4-triazole) by simple one-step reaction. BLG-1 first reported three-dimensional (3D) ECC. Its interesting 3D reticular architecture contributed to its highest thermal decomposition temperature (Td: 226 °C) crystal density (ρ: 2.69 g cm-3) among ECCs. More importantly, charge as little 3 mg could reliably detonate compressed RDX, 1 CL-20. These incredible values indicated that had an ultra-powerful initiating ability far superior previously explosives. improved mechanical sensitivities (IS: 13 J; FS: N) electrostatic sensitivity (EDS: 240 mJ) compared with those typical lead-based explosive, lead azide 4J; 0.75N; EDS: 5 mJ). In particular, low laser-initiation threshold mJ at 808 nm, suggesting it serve laser-ignitable explosive. This work suggests promising candidate engreat practical application prospects for

Language: Английский

Citations

13