Nanoscale Advances,
Journal Year:
2023,
Volume and Issue:
5(14), P. 3589 - 3605
Published: Jan. 1, 2023
Recent
strategies
for
the
controllable
encapsulation
of
nanoparticles
within
nanospaces
metal–organic
frameworks
(NPNS@MOF)
with
hierarchical
architectures,
intrinsic
properties,
superior
activities,
and
practical
applicabilities
are
summarized.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(27)
Published: April 17, 2024
Abstract
Ordered
pore
engineering
that
embeds
uniform
pores
with
periodic
alignment
in
electrocatalysts
opens
up
a
new
avenue
for
achieving
further
performance
promotion.
Hierarchically
ordered
porous
metal–organic
frameworks
(HOP‐MOFs)
possessing
multilevel
distribution
are
the
promising
precursors
exploration
of
electrocatalysts,
while
scalable
acquisition
HOP‐MOFs
editable
components
and
adjustable
size
regimes
is
critical.
This
review
presents
recent
progress
on
hierarchically
MOF‐based
materials
enhanced
electrocatalysis.
The
synthetic
strategies
different
regimes,
including
self‐assembly
guided
by
reticular
chemistry,
surfactant,
nanoemulsion,
nanocasting,
first
introduced.
Then
applications
as
exploring
summarized,
selecting
representatives
to
highlight
boosted
performance.
Especially,
intensification
molecule
ion
transport
integrated
optimized
electron
transfer
site
exposure
over
derivatives
emphasized
clarify
directional
integration
effect
endowed
engineering.
Finally,
remaining
scientific
challenges
an
outlook
this
field
proposed.
It
hoped
will
guide
nanocatalysts
boosting
catalytic
promoting
practical
applications.
Small,
Journal Year:
2024,
Volume and Issue:
20(26)
Published: Jan. 14, 2024
Abstract
Featured
with
the
attractive
properties
such
as
large
surface
area,
unique
atomic
layer
thickness,
excellent
electronic
conductivity,
and
superior
catalytic
activity,
layered
metal
chalcogenides
(LMCs)
have
received
considerable
research
attention
in
electrocatalytic
applications.
In
this
review,
approaches
developed
to
synthesize
LMCs‐based
electrocatalysts
are
summarized.
Recent
progress
composites
for
electrochemical
energy
conversion
applications
including
oxygen
reduction
reaction,
carbon
dioxide
evolution
hydrogen
overall
water
splitting,
nitrogen
reaction
is
reviewed,
potential
opportunities
practical
obstacles
development
of
high‐performing
active
substances
also
discussed.
This
review
may
provide
an
inspiring
guidance
developing
high‐performance
LMCs
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 12, 2024
Bifunctional
electrocatalysts,
capable
of
efficiently
driving
both
the
oxygen
reduction
reaction
(ORR)
and
evolution
(OER),
are
crucial
for
advancing
electrochemical
processes.
While
noble-metal-based
catalysts
widely
recognized
their
role
in
processes,
current
state-of-the-art
designs
limited
to
either
ORR
or
OER
activity,
presenting
a
notable
research
gap.
In
addressing
this
challenge,
we
have
developed
novel