Science China Materials,
Journal Year:
2024,
Volume and Issue:
68(1), P. 21 - 38
Published: Nov. 8, 2024
Abstract
The
conversion
of
carbon
dioxide
(CO
2
)
to
the
reduced
chemical
compounds
offers
substantial
environmental
benefits
through
minimizing
emission
greenhouse
gas
and
fostering
sustainable
practices.
Recently,
unique
properties
metal-organic
frameworks
(MOFs)
make
them
attractive
candidates
for
electrocatalytic
CO
reduction
reaction
RR),
providing
many
opportunities
develop
efficient,
selective,
environmentally
processes
mitigating
emissions
utilizing
as
a
valuable
raw
material
synthesis
fuels
chemicals.
Here,
recent
advances
in
MOFs
efficient
catalysts
RR
are
summarized.
detailed
characteristics,
mechanisms,
practical
approaches
improving
efficiency,
selectivity,
durability
under
realistic
conditions
also
clarified.
Furthermore,
outlooks
on
prospects
MOF-based
electrocatalysts
provided.
Polymer-Plastics Technology and Materials,
Journal Year:
2024,
Volume and Issue:
63(8), P. 939 - 974
Published: Feb. 5, 2024
Recently
emerging
nanotechnological
advancements
has
facilitated
the
embedment
of
metal-organic
framework
(MOFs)
also
referred
as
porous
co-ordination
polymers
(PCPs),
within
conducting
polymeric
(CP)
matrices
(polyaniline,
polypyrrole,
poly(3,4-ethylenedioxythiophene)
and
so
on),
resulting
in
fabrication
multifunctional
MOF@CP
nanoarchitectures
for
multifarious
applications
especially
electrochemical
energy
storage
due
to
garnered
enhanced
features
(low
density,
manipulatable
architectures,
elevated
specific
surface
areas,
aligned
crystalline
architectur)e,
well
controllable
constitution
at
molecular
level.
Therefore,
this
paper
presents
recently
trends
supercapacitors,
lithium-sulfur
batteries,
metal-ion
lithium-oxygen
zinc-air
batteries
cover
other
segments.
Small,
Journal Year:
2024,
Volume and Issue:
20(33)
Published: April 4, 2024
Exploitation
of
metal-organic
framework
(MOF)
materials
as
active
electrodes
for
energy
storage
or
conversion
is
reasonably
challenging
owing
to
their
poor
robustness
against
various
acidic/basic
conditions
and
conventionally
low
electric
conductivity.
Keeping
this
in
perspective,
herein,
a
3D
ultramicroporous
triazolate
Fe-MOF
(abbreviated
Fe-MET)
judiciously
employed
using
cheap
commercially
available
starting
materials.
Fe-MET
possesses
ultra-stability
chemical
environments
(pH-1
pH-14
with
varied
organic
solvents)
highly
electrically
conductive
(σ
=
0.19
S
m
Science China Materials,
Journal Year:
2024,
Volume and Issue:
68(1), P. 21 - 38
Published: Nov. 8, 2024
Abstract
The
conversion
of
carbon
dioxide
(CO
2
)
to
the
reduced
chemical
compounds
offers
substantial
environmental
benefits
through
minimizing
emission
greenhouse
gas
and
fostering
sustainable
practices.
Recently,
unique
properties
metal-organic
frameworks
(MOFs)
make
them
attractive
candidates
for
electrocatalytic
CO
reduction
reaction
RR),
providing
many
opportunities
develop
efficient,
selective,
environmentally
processes
mitigating
emissions
utilizing
as
a
valuable
raw
material
synthesis
fuels
chemicals.
Here,
recent
advances
in
MOFs
efficient
catalysts
RR
are
summarized.
detailed
characteristics,
mechanisms,
practical
approaches
improving
efficiency,
selectivity,
durability
under
realistic
conditions
also
clarified.
Furthermore,
outlooks
on
prospects
MOF-based
electrocatalysts
provided.
