Carbon Quantum Dots with Room Temperature Phosphorescence for Information Encryption and Anticounterfeiting DOI

Zhi-Qing Zhao,

Long Tan,

Tong-Bao Lv

et al.

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(11), P. 13736 - 13744

Published: May 31, 2024

Although carbon dots (CDs) have been widely investigated as the fluorescence material, research on room temperature phosphorescence (RTP) CDs is still limited. In this work, diethylenetriaminepentaacetic acid (DTPA) was employed raw material to synthesize quantum (denoted CQDs-1) by a hydrothermal method. The resulting CQDs-1 inherited C═O groups and N atoms from DTPA, which promoted formation of triplet excitons under light excitation. On basis, were dispersed in poly(vinyl alcohol) (PVA) matrix prepare CQDs-1-PVA composites that exhibited an optimal emission peak at ∼466 nm emitted visible afterglow lasting for 8 s. Moreover, tartaric (TA) combined with DTPA CQDs-2, induced π–π conjugated areas CQDs. As result, wavelength slightly red-shifted, duration time CQDs-2-PVA composite increased 9 Due ultralong-lifetime RTP properties CQDs-based composites, their applications fields information encryption anticounterfeiting also investigated. Overall, our work offered convenient avenue synthesis high-quality

Language: Английский

The afterglow of carbon dots shining in inorganic matrices DOI

Xiao-Yan He,

Yihao Zheng, Chaofan Hu

et al.

Materials Horizons, Journal Year: 2023, Volume and Issue: 11(1), P. 113 - 133

Published: Oct. 5, 2023

This is a comprehensive and systematic review focusing on CDs@IMs from multiple perspectives of construction, performance, mechanism, multifunctional applications.

Language: Английский

Citations

21

Multicolor Afterglow from Carbon Dots: Preparation and Mechanism DOI

Zhun Ran,

Jinkun Liu, Jianle Zhuang

et al.

Small Methods, Journal Year: 2023, Volume and Issue: 8(1)

Published: Oct. 27, 2023

Abstract Carbon dots (CDs), as emerging long afterglow luminescent material, have attracted the attention of researchers and become one hot topics in materials. In recent years, obtained a series CDs‐based materials with different properties utilizing matrix‐assisted self‐protective methods. To meet diverse application needs, development multicolor is focus challenge this field. Most previously reported generally emit blue or green afterglow. Recently, some systems been discovered, emission range can extend from ultraviolet to near‐infrared. However, there lack systematic in‐depth analysis regarding preparation strategy luminescence mechanism Based on this, review summarizes strategies raw reaction parameters. Then, mechanisms are analyzed seven factors, including carbonization degree, surface state, aggregation temperature dependence, excitation multi‐emission center, energy transfer. Moreover, applications introduced. Finally, problems challenges field discussed, future directions analyzed.

Language: Английский

Citations

21

Recent advances in red-emissive carbon dots and their biomedical applications DOI

Weixia Qin,

Meiyan Wang,

Yan Li

et al.

Materials Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 8(4), P. 930 - 955

Published: Dec. 7, 2023

This review mainly summarizes the research advances in synthetic strategies, optical properties, and biomedical applications of red-emissive carbon dots recent years.

Language: Английский

Citations

17

Sulfur doping pyrene-based carbon dots with multicolor room temperature phosphorescence for information encryption DOI
Zelin Zhang, Fengshan Liu, Yang Xu

et al.

Dyes and Pigments, Journal Year: 2024, Volume and Issue: 224, P. 111998 - 111998

Published: Feb. 1, 2024

Language: Английский

Citations

8

Carbon Quantum Dots with Room Temperature Phosphorescence for Information Encryption and Anticounterfeiting DOI

Zhi-Qing Zhao,

Long Tan,

Tong-Bao Lv

et al.

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(11), P. 13736 - 13744

Published: May 31, 2024

Although carbon dots (CDs) have been widely investigated as the fluorescence material, research on room temperature phosphorescence (RTP) CDs is still limited. In this work, diethylenetriaminepentaacetic acid (DTPA) was employed raw material to synthesize quantum (denoted CQDs-1) by a hydrothermal method. The resulting CQDs-1 inherited C═O groups and N atoms from DTPA, which promoted formation of triplet excitons under light excitation. On basis, were dispersed in poly(vinyl alcohol) (PVA) matrix prepare CQDs-1-PVA composites that exhibited an optimal emission peak at ∼466 nm emitted visible afterglow lasting for 8 s. Moreover, tartaric (TA) combined with DTPA CQDs-2, induced π–π conjugated areas CQDs. As result, wavelength slightly red-shifted, duration time CQDs-2-PVA composite increased 9 Due ultralong-lifetime RTP properties CQDs-based composites, their applications fields information encryption anticounterfeiting also investigated. Overall, our work offered convenient avenue synthesis high-quality

Language: Английский

Citations

8