The
optoelectronic
memristor
integrates
the
multifunctionalities
of
image
sensing,
storage,
and
processing,
which
has
been
considered
as
leading
candidate
to
construct
novel
neuromorphic
visual
system.
In
particular,
memristive
materials
with
all-optical
modulation
complementary
metal
oxide
semiconductor
(CMOS)
compatibility
are
highly
desired
for
energy-efficient
perception.
As
a
p-type
material,
Cu
Macromolecular Rapid Communications,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 12, 2024
Abstract
Surface
covalent
modification
of
black
phosphorus
(BP)
with
organic
polymers
represents
a
promising
strategy
to
enhance
its
stability
and
tailor
electronic
properties.
Despite
this
potential,
developing
memristive
materials
through
suitable
polymer
structures,
grafting
pathways,
polymerization
techniques
remains
challenging.
In
study,
polyaniline
(PANI)‐covalently
grafted
nanosheets
(BPNS)
are
successfully
prepared
redox
functionalities
via
the
in
situ
aniline
on
surface
4‐aminobenzene‐modified
BPNS.
The
PANI
coating
protects
BP
from
direct
exposure
oxygen
water,
it
endows
material
analog
properties,
characterized
by
continuously
adjustable
resistance
within
limited
voltage
scan
range.
When
subjected
broader
scan,
Al/PANI‐g‐BPNS/ITO
device
demonstrates
typical
bistable
digital
behavior.
integration
both
single
paves
way
for
development
high‐density,
multifunctional
components.
The
optoelectronic
memristor
integrates
the
multifunctionalities
of
image
sensing,
storage,
and
processing,
which
has
been
considered
as
leading
candidate
to
construct
novel
neuromorphic
visual
system.
In
particular,
memristive
materials
with
all-optical
modulation
complementary
metal
oxide
semiconductor
(CMOS)
compatibility
are
highly
desired
for
energy-efficient
perception.
As
a
p-type
material,
Cu