Interfacial engineering design induces enriched-defects expediting catalytic conversion kinetics of polysulfides DOI
Guixin Zhang, Xiaorong Chen,

Xinmeng Yu

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(15), P. 8927 - 8939

Published: Jan. 1, 2024

The functionalized separators of CoS 2 –MoS /CNT with enriched-defects and enhanced-activity are used to accelerate the redox kinetics lithium polysulfides (LiPSs) in lithium–sulfur (Li–S) batteries.

Language: Английский

Co/Mon Invigorated Bilateral Kinetics Modulation for Advanced Lithium–Sulfur Batteries DOI

Yueyue Kong,

Lu Wang,

Muhammad Mamoor

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(13)

Published: Dec. 22, 2023

Abstract Sluggish sulfur redox kinetics and Li‐dendrite growth are the main bottlenecks for lithium–sulfur (Li–S) batteries. Separator modification serves as a dual‐purpose approach to address both of these challenges. In this study, Co/MoN composite is rationally designed applied modifier modulate electrochemical on sides cathode lithium anode. Benefiting from its adsorption‐catalysis function, decorated separators (Co/MoN@PP) not only effectively inhibit polysulfides (LiPSs) shuttle accelerate their conversion but also boost Li + flux, realizing uniform plating/stripping. The accelerated LiPSs excellent reversibility triggered by modified evidenced performance, in‐situ Raman detection theoretical calculations. batteries with Co/MoN@PP achieve high initial discharge capacity 1570 mAh g −1 at 0.2 C low decay rate 0.39%, transportation 1 mA cm −2 over 800 h. Moreover, areal 4.62 achieved under mass loadings 4.92 mg . This study provides feasible strategy rational utilization synergistic effect multifunctional microdomains solve problems anode S toward long‐cycling Li–S

Language: Английский

Citations

69
Recent advances and strategies of metal phosphides for accelerating polysulfide redox and regulating Li plating DOI

Yi Yang,

Bowen Sun, Zhiqiang Sun

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 510, P. 215836 - 215836

Published: April 12, 2024

Language: Английский

Citations

44
Review on current development of polybenzimidazole membrane for lithium battery DOI

Yonggui Deng,

Arshad Hussain, Waseem Raza

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 91, P. 579 - 608

Published: Jan. 11, 2024

Language: Английский

Citations

22
Advancements in functionalized high-performance separators for lithium-sulfur batteries DOI
Shuang Xia, Xuming Xu, Wenzhuo Wu

et al.

Materials Science and Engineering R Reports, Journal Year: 2025, Volume and Issue: 163, P. 100924 - 100924

Published: Jan. 16, 2025

Language: Английский

Citations

7
Dependence of Interlayer or Sulfur Host on Hollow Framework of Lithium–Sulfur Battery DOI
Qilan Chen, Junhao Li, Jiajie Pan

et al.

Small, Journal Year: 2024, Volume and Issue: 20(32)

Published: March 19, 2024

Abstract Lithium–sulfur batteries are recognized as the next generation of high‐specific energy secondary owing to their satisfactory theoretical specific capacity and density. However, commercial application is greatly limited by a series problems, including disordered migration behavior, sluggish redox kinetics, serious shuttle effect lithium polysulfides. One most efficient approaches physically limit rational design hollow framework sulfur host. influence structure on interlayers has not been clearly reported. In this study, Mo 2 C/C catalysts with hollow(H‐Mo C/C) solid(S‐Mo frameworks rationally designed explore dependence interlayer or contrast physical limitations host, inhibited lithium‐ion diffusion, resulting in poor electrochemical properties at high current densities. Based superiority various frameworks, H‐Mo C/C@S | S‐Mo C/C@PP Li cells assembled displayed excellent performance. This work re‐examines requirements principles catalyst different battery units.

Language: Английский

Citations

14
Crystalline-amorphous heterostructure on the phosphatized P-CoS2/CNT for augmenting the catalytic conversion kinetics of Li-S batteries DOI
Guixin Zhang, Xiaorong Chen,

Xinmeng Yu

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 150696 - 150696

Published: March 25, 2024

Language: Английский

Citations

14
α‐MnO2/RuO2 Heterostructure‐Modified Polypropylene Separator for High‐Performance Lithium–Sulfur Battery DOI
Zhiyuan Ma, Zhengqiu Qi,

Guihao Song

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: April 30, 2024

Abstract Lithium–sulfur (Li–S) battery is a promising next‐generation energy storage system. However, the poor cyclability caused by shuttle effect still key challenge for its practical application. Here, polypropylene separator modified with α‐MnO 2 /RuO heterostructure presented to facilitate transformation of lithium polysulfides (LiPSs) and optimize rate‐determining step in both reduction oxidation processes sulfur electrode. The unique effectively suppresses dissolution shuttling soluble LiPSs Li–S batteries. Ru content ≈8 wt% enables high areal capacity over 5.0 mAh cm −2 after 55 cycles at 0.2C coin cell, resultant pouch cell retains 78.2% initial 200 0.1C, suggesting considerable potential commercial applications. This work provides new insights into regulation electrochemical reactions

Language: Английский

Citations

14
Spodumene nanosheets@ZrO2-SiO2 heterostructure nanofibers modified separator for long-cycle lithium-sulfur batteries DOI
Lin Li,

Bin Yue,

Yingying Bao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 495, P. 153619 - 153619

Published: June 29, 2024

Language: Английский

Citations

11
New flexible separators for modification of high-performance lithium–sulfur batteries DOI

Anjie Chen,

Jiaojiao Xue,

Jinhai He

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1005, P. 176146 - 176146

Published: Aug. 24, 2024

Language: Английский

Citations

10
Nanostructured MnFe2O4/MnO heterojunctions as highly-efficient bi-functional catalyst for complementary conversions of polysulfides toward robust lithium-sulfur batteries DOI

Feiyang Teng,

Ling Zhu, Jie Ma

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159216 - 159216

Published: Jan. 1, 2025

Language: Английский

Citations

2