Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177093 - 177093
Published: Oct. 1, 2024
Language: Английский
Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: unknown, P. 177093 - 177093
Published: Oct. 1, 2024
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 510, P. 215836 - 215836
Published: April 12, 2024
Language: Английский
Citations
42Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103477 - 103477
Published: May 18, 2024
Language: Английский
Citations
18Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 665, P. 702 - 710
Published: March 26, 2024
Language: Английский
Citations
10Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 669, P. 126 - 136
Published: April 30, 2024
Language: Английский
Citations
10ChemSusChem, Journal Year: 2024, Volume and Issue: 17(14)
Published: March 5, 2024
The pursuit of efficient host materials to address the sluggish redox kinetics sulfur species has been a longstanding challenge in advancing practical application lithium-sulfur batteries. In this study, amorphous carbon layer loaded with ultrafine CoP nanoparticles prepared by one-step situ carbonization/phosphating method enhance inhibition 2D black phosphorus (BP) on LiPSs shuttle. coating facilitates accelerated electron/ion transport, enabling active involvement BP conversion soluble lithium polysulfides (LiPSs). Concurrently, ultra-fine chemical anchoring ability and introduce additional catalytic sites. As result, S@BP@C-CoP electrodes demonstrate exemplary cycling stability (with minimal capacity decay 0.054 % over 500 cycles at 1 C) superior rate performance (607.1 mAh g
Language: Английский
Citations
9Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1005, P. 176146 - 176146
Published: Aug. 24, 2024
Language: Английский
Citations
9Small, Journal Year: 2023, Volume and Issue: 20(17)
Published: Dec. 4, 2023
Abstract Lithium–sulfur batteries (LSBs) with ultra‐high energy density (2600 W h kg −1 ) and readily available raw materials are emerging as a potential alternative device low cost for lithium‐ion batteries. However, the insulation of sulfur unavoidable shuttle effect leads to slow reaction kinetics LSBs, which in turn cause various roadblocks including poor rate capability, inferior cycling stability, coulombic efficiency. The most effective way solve issues mentioned above is rationally design control synthesis cathode host LSBs. Transition metal phosphides (TMPs) good electrical conductivity dual adsorption‐conversion capabilities polysulfide (PS) regarded promising hosts new‐generation In this review, main obstacles commercializing LSBs development processes their first elaborated. Then, fixation principles, methods TMPs briefly summarized recent progress reviewed detail. Finally, perspective on future research directions provided.
Language: Английский
Citations
20Small, Journal Year: 2023, Volume and Issue: 20(2)
Published: Sept. 5, 2023
Abstract Single‐atom catalysts (SACs) with specific N‐coordinated configurations immobilized on the carbon substrates have recently been verified to effectively alleviate shuttle effect of lithium polysulfides (LiPSs) in lithium–sulfur (Li─S) batteries. Herein, a versatile molten salt (KCl/ZnCl 2 )‐mediated pyrolysis strategy is demonstrated fabricate Zn SACs composed well‐defined Zn‐N 4 sites embedded into porous sheets rich pyridine‐N defects (Zn─N/CS). The electrochemical kinetic analysis and theoretical calculations reveal critical roles active surrounding enhancing adsorption toward LiPS intermediates catalyzing their liquid–solid conversion. It confirmed by reducing overpotential rate‐determining step Li S energy barrier for decomposition, thus Zn─N/CS guarantees fast redox kinetics between LiPSs products. As proof concept demonstration, assembled Li─S batteries Zn─N/CS‐based sulfur cathode deliver high capacity 1132 mAh g −1 at 0.1 C remarkable retention 72.2% over 800 cycles C. Furthermore, considerable areal 6.14 cm −2 0.2 can still be released loading 7.0 mg , highlighting practical applications as‐obtained
Language: Английский
Citations
15Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 672, P. 287 - 298
Published: May 22, 2024
Language: Английский
Citations
6Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 676, P. 521 - 531
Published: July 20, 2024
Language: Английский
Citations
6