Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 23, 2024
Abstract
The
fundamental
challenge
in
electron‐transporting
organic
mixed
ionic‐electronic
conductors
(OMIECs)
is
simultaneous
optimization
of
electron
and
ion
transport.
Beginning
from
Y6‐type/U‐shaped
non‐fullerene
solar
cell
acceptors,
we
systematically
synthesize
characterize
molecular
structures
that
address
the
aforementioned
challenge,
progressively
introducing
increasing
numbers
oligoethyleneglycol
(OEG;
g)
sidechains
1
g
to
3
g,
affording
OMIECs
1gY,
2gY,
3gY,
respectively.
crystal
structure
1gY
preserves
key
structural
features
Y
n
series:
a
U‐shaped/planar
core,
close
π–π
stacking,
interlocked
acceptor
groups.
Versus
inactive
Y6
Y11,
all
new
glycolated
compounds
exhibit
ion‐electron
transport
both
conventional
electrochemical
transistor
(cOECT)
vertical
OECT
(vOECT)
architectures.
Notably,
3gY
with
highest
OEG
density
achieves
high
transconductance
16.5
mS,
an
on/off
current
ratio
~10
6
,
turn‐on/off
response
time
94.7/5.7
ms
vOECTs.
Systematic
optoelectronic,
electrochemical,
architectural,
crystallographic
analysis
explains
superior
3gY‐based
performance
terms
denser
gY
content,
increased
crystallite
dimensions
decreased
long‐range
crystalline
order,
enhanced
film
hydrophilicity
which
facilitates
efficient
redox
processes.
Finally,
demonstrate
small‐molecule‐based
complementary
inverter
using
vOECTs,
showcasing
bioelectronic
applicability
these
small‐molecule
OMIECs.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 8, 2024
Abstract
The
rapid
advancement
of
wearable
electronics
over
recent
decades
has
led
to
the
development
stretchable
strain
sensors,
which
are
essential
for
accurately
detecting
and
monitoring
mechanical
deformations.
These
sensors
have
widespread
applications,
including
movement
detection,
structural
health
monitoring,
human–machine
interfaces.
Resistive‐type
gained
significant
attention
due
their
simple
design,
ease
fabrication,
adaptability
different
materials.
Their
performance,
evaluated
by
metrics
like
stretchability
sensitivity,
is
influenced
choice
strain‐sensitive
This
review
offers
a
comprehensive
comparison
evaluation
materials
used
in
resistive
metal
semiconductor
films,
low‐dimensional
materials,
intrinsically
conductive
polymers,
gels.
also
highlights
latest
applications
motion
healthcare
interfaces
examining
device
physics
material
characteristics.
comparative
analysis
aims
support
selection,
application,
tailored
specific
applications.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 31, 2025
With
the
advancement
of
electronics,
there
is
a
growing
need
to
effectively
combine
rigid,
flexible,
and
stretchable
materials
build
hybrid
electronics.
However,
interfacial
transition
between
rigid/flexible
substrates
presents
considerable
challenges,
mainly
due
differences
in
elastic
moduli,
complicating
their
integration
for
practical
usage.
Here,
bioinspired
omnidirectional
interfacial-engineered
flexible
islands
(BOIEFI)
are
introduced
robust
from
substrates.
These
BOIEFIs
enable
creation
highly
durable
capable
withstanding
diverse
physical
deformations
such
as
stretching,
twisting,
even
poking.
Inspired
by
plant
roots,
designed
with
primary
secondary
root
structures
that
provide
mechanical
interlocking
different
moduli.
Through
experimental
computational
methods,
optimized
exhibit
significantly
enhanced
stretchability
improved
fatigue
life.
To
demonstrate
broad
applicability,
light-emitting
diodes
(LEDs)
integrated
into
establish
display.
In
addition,
human-machine
interface
device
soft
pressure
sensors
an
LED
array
fabricated
implementation
This
approach
facilitates
harmonious
substrates,
leading
soft,
stretchable,
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 9, 2025
Abstract
Stretchable
serpentine
electrodes
have
garnered
significant
attention
in
diverse
fields
such
as
embodied
artificial
intelligence,
electronic
skin,
free‐form
displays,
stretchable
integrated
circuits,
etc.
However,
current
micro/nano
fabrication
processes
often
struggle
with
compatibility
issues
on
substrates
or
face
challenges
related
to
scalability,
fidelity,
and
resolution.
Here,
the
study
has
developed
an
orientation‐controlled
surface
energy‐directed
assembly
(SEDA)
process
for
fabricating
high‐fidelity,
high‐resolution
a
linewidth
of
600
nm.
This
involves
pulling
out
patterns
from
nanomaterial
suspensions
alignment
their
axial
orientation,
ensuring
that
enclosed
hydrophobic
regions
between
hydrophilic
three‐phase
contact
line
(TPCL)
do
not
form.
Consequently,
TPCL
can
freely
recede,
facilitating
high
selectivity
assembly.
In
addition
length‐to‐spacing
(
L/S
)
ratio
pattern
speed
also
play
crucial
roles
determining
fidelity.
Specifically,
at
slow
speeds
low
ratios,
lateral
receding
time
is
shorter
than
its
longitudinal
time,
leading
excellent
selectivity.
To
demonstrate
versatility
SEDA
process,
are
assembled
various
nanomaterials,
including
silver
nanoparticles,
nanowires,
carbon
nanotubes,
liquid
metal,
silicon,
paper,
polydimethylsiloxane,
thermoplastic
polyurethane.
The
exhibit
distinct
strain‐resistive
performance,
been
applied
fields,
mechanical
strain‐gated
transistors,
speech
recognition
micromotion
sensors,
interconnect
circuits
light‐emitting
diode
human‐machine
interaction
gloves.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 14, 2025
Abstract
Elastomer‐based
resistive
super‐thin
film
strain
sensors
show
great
application
potentials
in
electronic
skins,
human–machine
interaction
systems,
wearable
devices
for
healthcare,
and
machine
learning
algorithms.
However,
it
is
challenging
to
accurately
monitor
the
deformation
of
human
body
joints
organs
with
curved
surfaces
(e.g.,
knees,
throats,
finger
joints)
by
only
taking
advantage
material
thickness
elasticity
conventional
2D
sensors.
Herein,
a
simple
strategy
developed
fabricate
conformal
elastomeric
thin
periodic
3D
microstructure
inspired
ridges
valleys
skin
accurate
signal
acquisition.
Specifically,
an
8‐micrometer‐thick
elastic
sensor
fabricated
via
thermoforming
followed
situ
chemical
growth
silver
nanoparticles.
The
exhibit
excellent
linearity
(R
2
=
0.99)
relatively
high
sensitivity
(gauge
factor
14)
over
wide
range
(≈43%),
ultra‐low
detection
limit
0.025%,
enabling
potential
applications
healthcare
monitoring
air
leakage
detection.
Thus,
this
study
unveils
methodology
process
microstructure‐enabled
conformable
sensors,
which
good
conformability
multiple
mechanical
sensing
functions
advancing
development
next‐generation
flexible
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
34(44)
Published: June 21, 2024
Abstract
The
quest
for
stretchable
properties
is
at
the
forefront
of
research
dedicated
to
on‐skin
light–emitting
devices.
Inspired
by
natural
wonders
bioluminescence,
electrochemiluminescent
devices
(ECLDs)
are
distinguished
straightforward
design
and
reduced
operating
voltage,
marking
a
departure
from
traditional
current‐driven
electroluminescent
(ACELDs).
primary
challenge
fully‐stretchable
ECLDs
lies
in
crafting
electrodes
that
simultaneously
satisfy
demands
conductivity,
transparency,
stretchability,
oxidation
resistance,
interface
stability.
This
introduces
groundbreaking
wrinkled
polymer‐gold
composite
electrode.
It
extends
50%
offers
outstanding
conductivity
10
Ω
sq
−1
,
achieves
transparency
above
60%,
withstands
over
000
stretching
cycles.
Employing
this
material,
alongside
electrospinning
fiber
luminescent
layers,
enabled
creation
ECLDs.
These
not
only
shine
brightly
30
Cd
m
−2
but
also
retain
more
than
90%
luminosity
when
stretched
up
50%.
Furthermore,
work
has
engineered
featuring
singular
patterns
multi‐dot
arrays.
They
exhibit
consistent
output
under
bending,
twisting,
applied
skin.
findings
highlight
potential
overcoming
challenges
faced
electronic
provide
new
ideas
wearable
technology
seamlessly
integrates
with
human
body.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 23, 2024
The
fundamental
challenge
in
electron-transporting
organic
mixed
ionic-electronic
conductors
(OMIECs)
is
simultaneous
optimization
of
electron
and
ion
transport.
Beginning
from
Y6-type/U-shaped
non-fullerene
solar
cell
acceptors,
we
systematically
synthesize
characterize
molecular
structures
that
address
the
aforementioned
challenge,
progressively
introducing
increasing
numbers
oligoethyleneglycol
(OEG;
g)
sidechains
1
g
to
3
g,
affording
OMIECs
1gY,
2gY,
3gY,
respectively.
crystal
structure
1gY
preserves
key
structural
features
Yn
series:
a
U-shaped/planar
core,
close
π-π
stacking,
interlocked
acceptor
groups.
Versus
inactive
Y6
Y11,
all
new
glycolated
compounds
exhibit
ion-electron
transport
both
conventional
electrochemical
transistor
(cOECT)
vertical
OECT
(vOECT)
architectures.
Notably,
3gY
with
highest
OEG
density
achieves
high
transconductance
16.5
mS,
an
on/off
current
ratio
~10
Conductive
composite
textiles
(CCTs)
as
multifunctional
integrated
platform
provide
an
effective
path
for
developing
flexible
electromagnetic
interference
(EMI)
shielding
composites.
However,
conventional
CCTs
suffer
from
EMI
performance
failure
or
the
loss
of
textile's
intrinsic
properties
under
large
tensile
strain.
Hence,
in
this
work,
a
stretchable
CCT
that
retains
inherent
attributes
textile
is
proposed
via
weft-knitting
and
in-situ
chemical
Ag
deposition.
The
complete
continuous
silver
nanoparticles
(AgNPs)
conductive
networks
bring
excellent
conductivity
(38560
S/m)
ultrahigh
(80.1
dB)
unstretched
state.
When
strain
applied,
fibers
are
gradually
straightened
flexural
state
within
40%
strain,
then
begin
to
be
stretched
at
bigger
strains,
which
benefits
structure.
Therefore,
on
fiber
surfaces
well
protected
damage
initial
range,
resulting
stable
(51.7
even
after
1000
cycles
100%
Crucially,
preserves
good
air
permeability,
softness
lightness
though
series
modifications
strains
applied.
Other
than
perforamnce,
superhydrophobicity
(the
contact
angle
158°)
imparts
with
capability
tackle
complex
environments
easily.
Moreover,
can
readily
heated
73.4
°C
low
voltage
0.5V,
showing
outstanding
Joule
heating
performance.
Even
long
period
(3600
s),
maintains
superior
thermal
stability,
indicating
potential
applications
wearable
heaters.
In
brief,
has
comprehensive
expected
further
expand
textiles.
Polymers,
Journal Year:
2024,
Volume and Issue:
16(18), P. 2623 - 2623
Published: Sept. 17, 2024
With
the
development
of
science
and
technology,
wearable
electronics
are
increasingly
widely
used
in
medical,
environmental
monitoring,
other
fields.
Thus,
demand
for
flexible
electrodes
is
increasing.
The
two-dimensional
material
Ti3C2Tx
has
attracted
much
attention
manufacture
due
to
its
excellent
mechanical
electrical
properties.
However,
brittleness
pure
films
become
a
major
obstacle
their
use
as
devices.
Therefore,
solving
problem
based
on
while
maintaining
performance
an
urgent
problem.
To
solve
this
problem,
was
compounded
with
waterborne
polyurethane
(WPU),
Ti3C2Tx-WPU
composite
film
hierarchical
structure
constructed
by
evaporation-assisted
self-assembly.
not
only
retains
conductivity
(100
S
m−1)
but
also
flexibility
(20
MJ
m−3).
Furthermore,
applied
functional
devices
such
contact
pressure
sensors
non-contact
proximity
sensors.
Finally,
device
demonstrates
practical
application
potential
field