Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160532 - 160532
Published: Feb. 1, 2025
Language: Английский
ACS Energy Letters, Journal Year: 2024, Volume and Issue: 9(5), P. 2037 - 2056
Published: April 9, 2024
Aqueous zinc-based batteries (AZBs) based on the conversion-type mechanism have become a hot spot now due to their low cost, high safety, and large capacity, which provides significant opportunity for large-scale energy storage. However, conversion reactions in AZBs face serious thermodynamic kinetic challenges. Rather than common advances, this review focuses fundamental aspects of reaction thermodynamics kinetics that lack systematic attention understanding. The mechanisms including anode reaction, manganese-based, chalcogenide-based, halogen-based, copper-based, iron-based were discussed. issues perspectives battery system are further highlighted. final section proposes directions discuss how better understand design effective systems via combining kinetics.
Language: Английский
Citations
41
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 16, 2024
Abstract The cost‐effectiveness and environmental benefits of aqueous zinc‐ion batteries (ZIBs) have attracted considerable attention. However, practical applications are hindered by side processes including dendritic growth hydrogen evolution corrosion. Herein, gallium ions (Ga 3+ ) been chosen as a multifunctional electrolyte additive to improve the reversibility (ZIBs). Remarkably, Ga adhere anode surface, establishing dynamic electrostatic shielding layer that modulates Zn 2+ deposition prevents reactions. Typically, preferentially adsorb onto (002) (110) planes Zn, facilitating preferential on (100) plane, resulting in dendrites‐free zinc anode. Consequently, Zn||Zn symmetrical cell with ‐modified demonstrates prolonged lifespan 4000 h, while Zn||Ti asymmetric exhibits an impressive coulombic efficiency 99.12% for stripping plating at 2 mA cm −2 . Additionally, Zn||VO maintains high capacity retention after 1500 cycles 5 A g −1 This work presents additive, development durable effect plane electroplating, ensuring free from dendrite formation. Such discoveries form basis future investigations into novel materials propel advancements metal battery technology.
Language: Английский
Citations
25
Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 123788 - 123788
Published: Jan. 1, 2025
Language: Английский
Citations
3
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 686, P. 960 - 969
Published: Feb. 5, 2025
Language: Английский
Citations
2
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(32)
Published: June 5, 2024
Abstract Aqueous zinc metal batteries (AZMBs) have emerged as a focal point of interest in academic research and industrial strategic planning. Zinc powder (ZP) is poised to assume prominent position both future practical applications due its high Zn utilization rate processability. However, critical challenges need be addressed before realizing substantial progress. Notably, severe voltage polarization gas production ZP electrodes stand out the primary causes battery failure, differing with foil where short circuits caused by dendrites contribute failure. While numerous comprehensive reviews offered effective strategies for foil, systematic summary still lacking. For ZP, electrode preparation dictates performance. This review summarizes criteria optimal electrodes, covering components, methods, technique parameters. It emphatically introduces underlying water‐related side reactions briefly analyzes stripping/plating behaviors electrodes. The status quo ZP‐based then discussed categories current collector, conductive scaffold, binder, electrolytes. Finally, potential avenues are proposed from three aspects enhance focus on facilitate application AZMBs.
Language: Английский
Citations
15
ACS Energy Letters, Journal Year: 2024, Volume and Issue: 9(7), P. 3269 - 3289
Published: June 7, 2024
Zinc metal batteries have emerged as promising candidates for next-generation energy storage devices due to their high capacities, safety, and cost-effectiveness. However, the implementation of Zn anodes (ZMAs) faces significant challenges, including uncontrollable dendrite growth, pronounced corrosion, notable side reactions. To address these issues, extensive research efforts are underway, focusing on tailored structures, compositions, interfaces ZMAs, supported by multi-level engineering approaches. Various efficient solutions been proposed verified, homogenizing ion flux/electric field, enriching nucleation site number, reducing barriers, providing sufficient space deposition. This Review provides a thorough summary recent advancements in innovative design from viewpoints structural interfacial strategies. Key concepts functional mechanisms resolving aforementioned issues ZMAs highlighted. Furthermore, remaining challenges discussed, future directions also identified.
Language: Английский
Citations
13
Advanced Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 12, 2024
The space charge layer (SCL) dilemma, caused by mobile anion concentration gradient and the rapid consumption of cations, is fundamental reason for generation zinc dendrites, especially under high-rate discharge conditions. To address issue, a physical (PbTiO
Language: Английский
Citations
13
Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(18), P. 8980 - 9028
Published: Jan. 1, 2024
As one of the most promising electrochemical energy storage systems, aqueous batteries are attracting great interest due to their advantages high safety, sustainability, and low costs when compared with commercial lithium-ion batteries, showing promise for grid-scale storage. This invited tutorial review aims provide universal design principles address critical challenges at electrode-electrolyte interfaces faced by various multivalent battery systems. Specifically, deposition regulation, ion flux homogenization, solvation chemistry modulation proposed as key tune inter-component interactions in corresponding interfacial strategies underlying working mechanisms illustrated. In end, we present a analysis on remaining obstacles necessitated overcome use under different practical conditions future prospects towards further advancement sustainable systems long durability.
Language: Английский
Citations
12
ChemElectroChem, Journal Year: 2024, Volume and Issue: 11(13)
Published: April 11, 2024
Abstract Aqueous zinc‐ion batteries (AZIBs) are highly promising for grid‐scale energy storage due to their high‐safety and low‐cost characteristics. Nevertheless, the progress in AZIBs has been impeded challenges encompassing corrosion, hydrogen evolution reaction, formation of dendrites on Zn anodes. These issues arise from decomposition active water molecules 2+ solvation structure electrolyte. Various strategies have proposed regulate electrode/electrolyte interface effectively address these problems. In spite remarkable headway, an inadequacy comprehensive studies addressing mechanisms evolutionary dynamics is evident within scientific literature. This overview aims provide a regulating interface, focusing dendrite‐free side reactions‐suppressed AZIBs. include introduction metal ion additives, inorganic surfactant polymer additives organic additives. Furthermore, detailed examination made effects underlying associated with modifying electrolyte at between electrode Moreover, appraisal provided performance metrics diverse prospective research directions recommended as well.
Language: Английский
Citations
10
Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103513 - 103513
Published: May 24, 2024
Language: Английский
Citations
10