Ionics, Journal Year: 2024, Volume and Issue: unknown
Published: May 28, 2024
Language: Английский
Ionics, Journal Year: 2024, Volume and Issue: unknown
Published: May 28, 2024
Language: Английский
Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(31)
Published: June 4, 2024
Abstract In advancing aqueous zinc‐ion batteries (AZIBs) toward commercial viability, vanadium (V)‐based cathodes are pivotal, offering broad redox ranges, and compatibility with water's electrochemical limits. Despite their great potentials, V‐based face challenges in transitioning from lab to commercialization. Defect engineering is exploited as a pivotal technique that endows the unexpected physical chemical properties break intrinsic bottleneck and, turn, enhance performances. This review delves into role of defect on materials, underscoring its potential mitigating critical challenges. It starts by encapsulating current characteristics AZIBs. Research efforts related various defects, such oxygen vacancies, cation cationic doping, anionic water intercalation, lattice disorders/amorphization, then rationalized discussed. The fabrication characterization techniques also summarized. By integrating conclusions existing works tailoring strategies, few perspectives provided for systematically employing pave way more efficient transition these promising materials laboratory breakthroughs commercially viable energy storage solutions.
Language: Английский
Citations
27Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 690, P. 137295 - 137295
Published: March 11, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162148 - 162148
Published: March 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
The cathode materials set the limitation of aqueous zinc ion batteries (AZIBs) in capacity and restrict their development. Vanadium-based show unsatisfactory conductivity strong interactions with Zn2+ as well a narrow voltage window. Herein, an integrated network structure is obtained by modulating window to phase transition from VO2 HXV2O5. This has multiple advantages: low crystallinity abundant active sites; good electrolyte wetting; two-electron transfer for high specific capacity. AZIBs exhibit impressive rate performance (545 mAh g-1 at 0.1 A 185 20 g-1) cycling (179 after 15 000 cycles g-1), stable operation even -20 °C (391 1 g-1, 97 10 g-1). have power density energy based on mass material (405 Wh kg-1 74 W 102 11 127 kg-1). pouch-type cell can run over 500 h, maximum 45.5 kg-1. mechanism storage are identified, which conducive promoting development cathodes AZIBs.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 163387 - 163387
Published: May 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154788 - 154788
Published: Aug. 18, 2024
Language: Английский
Citations
2Journal of Power Sources, Journal Year: 2024, Volume and Issue: 622, P. 235370 - 235370
Published: Sept. 4, 2024
Language: Английский
Citations
2Energy storage materials, Journal Year: 2024, Volume and Issue: unknown, P. 103799 - 103799
Published: Sept. 1, 2024
Language: Английский
Citations
2ACS Omega, Journal Year: 2024, Volume and Issue: 9(49), P. 47920 - 47938
Published: Nov. 26, 2024
Rechargeable aqueous zinc-ion batteries (ZIBs) are poised as a promising solution for large-scale energy storage and portable electronic applications. Their appeal lies in their affordability, abundant materials, high safety standards, acceptable density, eco-friendliness. Vanadium-based compounds stand out potential cathode materials due to versatile phases variable crystal structures, empowering design flexibility affect the theoretical capacity. However, challenges, such V dissolution substantial capacity degradation, have hindered widespread use. Recent breakthroughs crafting innovative V-based ZIBs, by preintercalating guest species, significantly bolstered structural stability facilitated faster charge migration, leading enhanced stable cycling. This review delves into latest advancements vanadium-based cathodes with preintercalated examining altered structures mechanisms involved Zn
Language: Английский
Citations
1Ionics, Journal Year: 2024, Volume and Issue: unknown
Published: May 28, 2024
Language: Английский
Citations
0