19.5%‐Efficiency Organic Solar Cells with High Thickness Tolerance and Exceptional Device Stability Enabled by TEMPO‐Functionalized Perylene Diimide as a Cathode Interface Layer DOI Open Access
Yawen Guo, Xueqing Ma,

Haoming Song

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 15, 2024

Abstract The cathode interface material is pivotal for achieving excellent photovoltaic performance and device stability in organic solar cells (OSCs). However, currently, few materials can simultaneously satisfy multiple criteria such as low cost, high efficiency, insensitivity to film thickness, good stability. To address this challenge, a novel perylene diimide (PDI) derivative, P‐C3T designed synthesized, by incorporating stable free radical unit TEMPO polar quaternary ammonium salt side chains. facile synthesize cost‐effective, while also exhibiting conductivity ohmic contact characteristics OSCs. When utilized the material, based on D18:L8‐BO achieves remarkable power conversion efficiency (PCE) of 19.52%, which one highest levels reported binary single‐junction Notably, devices exhibit with PCE remaining at 95% initial even thickness 40 nm. Furthermore, ‐based OSCs demonstrate exceptional storage improved light In summary, its PCE, insensitivity, stability, anticipated be promising candidate large‐area roll‐to‐roll processing

Language: Английский

Ligand Impacts on Band Edge Energies and Excited State Splittings of Silicane DOI Creative Commons
Guoying Yao, Ekadashi Pradhan, Zhenyu Yang

et al.

Physical Chemistry Chemical Physics, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Ligand functionalization leads to enormous ranges of band edge energies silicanes. The can be predicted by empirical functions.

Language: Английский

Citations

1
19.5%‐Efficiency Organic Solar Cells with High Thickness Tolerance and Exceptional Device Stability Enabled by TEMPO‐Functionalized Perylene Diimide as a Cathode Interface Layer DOI Open Access
Yawen Guo, Xueqing Ma,

Haoming Song

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 15, 2024

Abstract The cathode interface material is pivotal for achieving excellent photovoltaic performance and device stability in organic solar cells (OSCs). However, currently, few materials can simultaneously satisfy multiple criteria such as low cost, high efficiency, insensitivity to film thickness, good stability. To address this challenge, a novel perylene diimide (PDI) derivative, P‐C3T designed synthesized, by incorporating stable free radical unit TEMPO polar quaternary ammonium salt side chains. facile synthesize cost‐effective, while also exhibiting conductivity ohmic contact characteristics OSCs. When utilized the material, based on D18:L8‐BO achieves remarkable power conversion efficiency (PCE) of 19.52%, which one highest levels reported binary single‐junction Notably, devices exhibit with PCE remaining at 95% initial even thickness 40 nm. Furthermore, ‐based OSCs demonstrate exceptional storage improved light In summary, its PCE, insensitivity, stability, anticipated be promising candidate large‐area roll‐to‐roll processing

Language: Английский

Citations

3