Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
Language: Английский
Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(20), P. 7459 - 7511
Published: Jan. 1, 2024
This review provides a comprehensive overview on the mechanism of photoelectrochemical biomass conversion and highlights extension dual-function cells for valorization paired with more valuable half-reactions.
Language: Английский
Citations
12
New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(6), P. 2576 - 2583
Published: Jan. 1, 2024
An electrochemical method for thioetherification of NH-sulfoximines with disulfides is reported. The utilization electrochemistry facilitating these reactions eliminates the necessity external oxidants, bases, and metal catalysts.
Language: Английский
Citations
11
Chemical Communications, Journal Year: 2024, Volume and Issue: 60(24), P. 3226 - 3239
Published: Jan. 1, 2024
This feature article presents an overview of continuous flow chemistry, including photoflow and electroflow technologies in the preparation active pharmaceutical ingredients (APIs) fine chemical intermediates.
Language: Английский
Citations
10
Current Organic Chemistry, Journal Year: 2024, Volume and Issue: 28(2), P. 105 - 116
Published: Jan. 1, 2024
Abstract: Sodium sulfinates have been widely utilized as sulfonyl radical precursors for preparing a diverse array of value-added sulfur-containing compounds (sulfones, sulfonamides, sulfonates, thiosulfonates, etc.) through S-C, S-N, S-O and S-S bonds formation reactions. Organic electrosynthesis has become an attractive alternative to conventional methods redox reactions because it utilizes electric current instead chemical agents. As such, the electrochemical generation radicals from sodium their applications in organic attracted much attention. In this review, recent advances sulfonylation involving since 2015 were reviewed, along with related reaction mechanisms.
Language: Английский
Citations
9
Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(57)
Published: July 6, 2024
Electrophotocatalysis (EPC) has evolved as a new scientific discipline around the boundary of highly active fields: electrochemistry and photocatalysis. EPC allows us to combine energy light electric potential activate previously inaccessible compounds via single-electron transfer (SET). Herein, we review most essential applications C-H functionalization molecules. This work discusses mechanisms that can be encountered when designing such processes analyzes technical aspects performing reactions in laboratory.
Language: Английский
Citations
3
European Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 3, 2025
Abstract Dual functionalizations of arenes promise to remain a powerful and versatile strategy for the synthesis complex molecules with diverse applications in various fields. Dearomatization‐Functionalization‐rearomatization emerges as tool chemo‐ regioselective functionalization via 2,5‐cyclohexadienone/2,5‐cyclohexadienimines, which can be easily accessible from phenols or anilines. 2,5‐Cyclohexadienones serve an “aromatic be” synthon multiple electrophilic centres, providing opportunity towards their functionalization. While mono‐functionalization was widely explored covered literature, simultaneous dual two distinct coupling partners offer rapid molecular diversification around aromatic rings. Diverse functional groups/coupling have been introduced regio‐selectively. The synthetic processes adopted are generally sustainable free transition metals exotic conditions. This review showcased advancement developing phenols/anilines site‐selective multi‐functional through aromaticity‐destruction‐functionalization‐construction strategy.
Language: Английский
Citations
0
Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 111216 - 111216
Published: April 1, 2025
Language: Английский
Citations
0
The Chemical Record, Journal Year: 2023, Volume and Issue: 24(3)
Published: Dec. 8, 2023
Herein, we provide eco-friendly and safely operated electrocatalytic methods for the selective oxidation directly or with water, air, light, metal catalyst other mediators serving as only oxygen supply. Heavy metals, stoichiometric chemical oxidants, harsh conditions were drawbacks of earlier oxidative cleavage techniques. It has recently come to light that a crucial stage in deconstruction plastic waste utilization biomass is activation inert C(sp
Language: Английский
Citations
4
Asian Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 13(5)
Published: March 21, 2024
Abstract A direct selenylation of N ‐arylsulfonamides and anilides using environmentally friendly readily available copper promoted assisted by amide is presented. This method provided convenient access for various reactions, demonstrating a wide range substrates strong tolerance to functional groups. According the selection reaction substrates, products can be isolated obtain regioselectivity ortho ‐, para or unprecedented , ‐diselenylation products. Such transformation was elucidated proposed copper‐promoted amide‐assisted radical mechanism.
Language: Английский
Citations
1
Chemical Communications, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 23, 2024
Due to the special structure and physicochemical properties of sulfoximines, research on sulfoximines has achieved great progress in recent decades, especially chemical medicinal fields. This review highlights advancements N-functionalization NH-sulfoximines, focusing classical cross-coupling reactions with electrophilic agents oxidative coupling extensive organic compounds, including specific (hetero)arenes, alkenes (1,4-naphthoquinones), alkanes (cyclohexanes), nucleophiles (thiols, disulfides, sulfinates, diarylphosphine oxides), organyl boronic acids, arylhydrazines. Transition metal-catalyzed, metal-free, electrochemical radical are discussed. also reports discusses mechanistic pathways some typical reactions.
Language: Английский
Citations
1