Phosphate ions detection by using an electrochemical sensor based on laser-scribed graphene oxide on paper DOI Creative Commons
Bernardo Patella, Antonino Parisi, Nadia Moukri

et al.

Electrochimica Acta, Journal Year: 2023, Volume and Issue: 461, P. 142600 - 142600

Published: May 18, 2023

In this work, electrodes based on laser-scribed reduced graphene oxide were fabricated using filter paper as the substrate. To fabricate electrodes, a water suspension of was filtered to produce continuous and uniform film surface. Subsequently, CO2 laser used "write" working, counter reference eelctroes by reducing in specific areas define complete sensors. Referecnce then coated with commercial Ag/AgCl conductive paste quasi reference. As devices employed electrochemical sensors for detection phosphate ions employing molybdenum blue method. This method exploits reaction between molybdate acidic media leading Keggin-type complex (PMo12O403−) which, being electrochemically active, enables indiret ions. Sensors exhibited high selectivity sensitive wide linear range, from 1 20 µM; limit 0.4 µM. demonstrate that could be utilized in-situ ion detection, substrate first pre-loaded sulphuric acid During analysis, these chemicals desorbed directly into test sample eliminating need any kind external manipulation or reagent addition. Thus, presents fabrication portable, easy-to-use, biodegradable fast sensor situ real-time monitoring quality.

Language: Английский

Water Peel-Off Transfer of Electronically Enhanced, Paper-Based Laser-Induced Graphene for Wearable Electronics DOI Creative Commons
Tomás Pinheiro, Ricardo Correia, Maria Morais

et al.

ACS Nano, Journal Year: 2022, Volume and Issue: 16(12), P. 20633 - 20646

Published: Nov. 16, 2022

Laser-induced graphene (LIG) has gained preponderance in recent years, as a very attractive material for the fabrication and patterning of graphitic structures electrodes, multiple applications electronics. Typically, polymeric substrates, such polyimide, have been used precursor materials, but other organic, more sustainable, accessible materials emerged viable alternatives, including cellulose substrates. However, these substrates lacked conductive chemical properties achieved by conventional LIG not translated into fully flexible, wearable scenarios. In this work, we expand paper-based LIG, boosting graphitization potential paper, through introduction external aromatic moieties meticulous control laser fluence. Colored wax printing over paper introduces structures, allowing synthesis with sheet resistances low 5 Ω·sq–1, translating to an apparent conductivity high 28.2 S·cm–1. Regarding properties, ID/IG ratios 0.28 showcase defect densities improve on previous reports where resistance limited values around 30 dense less crystalline structures. With improved simple transfer methodology was developed, based water-induced peel-off process that efficiently separates patterned from native conformable, flexible harnessing multifunctional capabilities toward Proof-of concept electrodes electrochemical sensors, strain in-plane microsupercapacitors were patterned, transferred, characterized, using high-value multiples scenarios technologies, sustainability accessibility applications.

Language: Английский

Citations

52

A wearable colorimetric sweat pH sensor-based smart textile for health state diagnosis DOI
Ji‐Hwan Ha, Yongrok Jeong, Junseong Ahn

et al.

Materials Horizons, Journal Year: 2023, Volume and Issue: 10(10), P. 4163 - 4171

Published: Jan. 1, 2023

Sweat pH is an important indicator for diagnosing disease states, such as cystic fibrosis. However, conventional sensors are composed of large brittle mechanical parts and need additional instruments to read signals. These have limitations practical wearable applications. In this study, we propose colorimetric sweat based on curcumin thermoplastic-polyurethane (C-TPU) electrospun-fibers diagnose states by monitoring. This sensor aids in monitoring changing color response chemical structure variation from enol di-keto form via H-atom separation. Its changes the visible due light absorbance reflectance changes. Furthermore, it can rapidly sensitively detect its superior permeability wettability. By O2 plasma activation thermal pressing, be easily attached various fabric substrates swaddling patient clothing surface modification interlocking C-TPU. diagnosable durable reusable enough neutral washing conditions reversible sensing performance restoring curcumin. study contributes development smart diagnostic fibrosis patients who require continuous

Language: Английский

Citations

43

Advanced Nanomaterials-Based Electrochemical Biosensors for Catecholamines Detection: Challenges and Trends DOI Creative Commons
Zina Fredj, Mohamad Sawan

Biosensors, Journal Year: 2023, Volume and Issue: 13(2), P. 211 - 211

Published: Jan. 31, 2023

Catecholamines, including dopamine, epinephrine, and norepinephrine, are considered one of the most crucial subgroups neurotransmitters in central nervous system (CNS), which they act at brain’s highest levels mental function play key roles neurological disorders. Accordingly, analysis such catecholamines biological samples has shown a great interest clinical pharmaceutical importance toward early diagnosis diseases as Epilepsy, Parkinson, Alzheimer diseases. As promising routes for real-time monitoring catecholamine neurotransmitters, optical electrochemical biosensors have been widely adopted perceived dramatically accelerating development last decade. Therefore, this review aims to provide comprehensive overview on recent advances main challenges biosensors. Particular emphasis is given biosensors, reviewing their sensing mechanism unique characteristics brought by emergence nanotechnology. Based specific biosensors’ performance metrics, multiple perspectives therapeutic use nanomaterial future trends also summarized.

Language: Английский

Citations

41

Laser-Induced Graphene Microsupercapacitors: Structure, Quality, and Performance DOI Creative Commons
Andrés Velasco, Yu Kyoung Ryu,

Assia Hamada

et al.

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(5), P. 788 - 788

Published: Feb. 21, 2023

Laser-induced graphene (LIG) is a graphenic material synthesized from polymeric substrate through point-by-point laser pyrolysis. It fast and cost-effective technique, it ideal for flexible electronics energy storage devices, such as supercapacitors. However, the miniaturization of thicknesses which important these applications, has still not been fully explored. Therefore, this work presents an optimized set conditions to fabricate high-quality LIG microsupercapacitors (MSC) 60 µm thick polyimide substrates. This achieved by correlating their structural morphology, quality, electrochemical performance. The fabricated devices show high capacitance 22.2 mF/cm2 at 0.05 mA/cm2, well power densities comparable those similar that are hybridized with pseudocapacitive elements. performed characterization confirms composed multilayer nanoflakes good continuity optimal porosity.

Language: Английский

Citations

34

Portable glucose sensing analysis based on laser-induced graphene composite electrode DOI Creative Commons
Zhaokang Zhang, Lu Huang, Yiting Chen

et al.

RSC Advances, Journal Year: 2024, Volume and Issue: 14(2), P. 1034 - 1050

Published: Jan. 1, 2024

In this work, a portable electrochemical glucose sensor was studied based on laser-induced graphene (LIG) composite electrode. A flexible electrode prepared using LIG technology. Poly(3,4-ethylene dioxythiophene) (PEDOT) and gold nanoparticles (Au NPs) were deposited the surface by potentiostatic deposition to obtain with good conductivity stability. Glucose oxidase (GOx) then immobilized glutaraldehyde (GA) create an LIG/PEDOT/Au/GOx micro-sensing interface. The concentration of solution is directly related current value chronoamperometry. Results show that can detect solutions within range 0.5 × 10-5 2.5 10-3 mol L-1. modified provides resulting excellent sensitivity 341.67 μA mM-1 cm-2 ultra-low limit detection (S/N = 3) 0.2 exhibits high sensitivity, stability, selectivity, making it suitable for analyzing biological fluid samples. user-friendly, be built into biosensor device through smartphone detection. Thus, developed has potential applied in point-of-care platforms such as environmental monitoring, public health, food safety.

Language: Английский

Citations

17

SPOOC (Sensor for Periodic Observation of Choline): An Integrated Lab‐on‐a‐Spoon Platform for At‐Home Quantification of Choline in Infant Formula DOI
Abdulrahman Al‐Shami, Farbod Amirghasemi, Ali Soleimani

et al.

Small, Journal Year: 2024, Volume and Issue: 20(31)

Published: April 8, 2024

Choline is an essential micronutrient for infants' brain development and health. To ensure that infants receive the needed daily dose of choline, U.S. Food Drug Administration (FDA) has set requirements choline levels in commercialized infant formulas. Unfortunately, not all families can access well-regulated formulas, leading to potential inadequacies intake. Economic constraints or difficulties obtaining exacerbated by situations like COVID-19, prompt stretch Accurate measurement formulas becomes imperative guarantee necessary nutritional support. Yet, accessible tools this purpose are lacking. An innovative integrated sensor periodic observation (SPOOC) designed at-home quantification milk powders reported. This system composed a potentiometric ionic-liquid reference electrode developed on laser-induced graphene (LIG) into spoon-like device. SPOOC includes micro-potentiometer conducts measurements transmits results wirelessly parents' mobile devices. demonstrated rapid accurate assessment directly pre-consuming without any sample treatment. work empowers parents with user-friendly tool monitoring promoting informed decision-making care infants.

Language: Английский

Citations

15

Electrodeposited Silver Dendrites on Laser‐Induced Graphene for Electrochemical Detection of Nitrate with Tunable Sensor Properties DOI Creative Commons
Anurag Adiraju,

Aditya Jalasutram,

Junfei Wang

et al.

Advanced Materials Interfaces, Journal Year: 2024, Volume and Issue: 11(19)

Published: April 9, 2024

Abstract Laser‐induced graphene (LIG) is a promising technology enabling cost‐effective, scalable, and high surface area 3D‐porous electrodes for electrochemical applications. Nitrate in water bodies harmful contaminant to humans the ecosystems. Its detection by sensors challenging due interference from nitrite. Herein, first time, LIG‐based sensor modified with electrodeposited silver dendrites (EdAg/LIG) without using surfactants proposed of nitrate tunable selectivity sensitivity. The electrode extensively characterized spectroscopic methods underlying mechanism formation substantiated. developed EdAg dendrites/LIG shows excellent sensing properties at pH 2. nitrite acidic media eliminated implementing novel strategy shift working 7. achieved both values surpass other limit 0.46 2 5.53 µ m also good recovery characteristics mineral, tap, groundwater across wide range concentrations demonstrates stability under temperature fluctuations deformations.

Language: Английский

Citations

14

Laser-Induced Graphene for Advanced Sensing: Comprehensive Review of Applications DOI
Sikandar Aftab, Ganesh Koyyada, Maria Mukhtar

et al.

ACS Sensors, Journal Year: 2024, Volume and Issue: 9(9), P. 4536 - 4554

Published: Sept. 16, 2024

Laser-induced graphene (LIG) and Laser-scribed (LSG) are both advanced materials with significant potential in various applications, particularly the field of sustainable sensors. The practical uses LIG (LSG), which include gas detection, biological process monitoring, strain assessment, environmental variable tracking, thoroughly examined this review paper. Its tunable characteristics distinguish is developed from accurate laser beam modulation on polymeric substrates, they essential advancing sensing technologies many applications. recent advances applications energy storage, biosensing, electronics by steadily efficiency versatility. remarkable flexibility its transformative regard to sensor manufacturing utilization highlighted manuscript. Moreover, it examines fabrication methods used production, highlighting precision adaptability. This navigates difficulties that encountered implementing sensors looks ahead future developments will propel industry forward. paper provides a comprehensive summary latest research elucidates innovative material's elements.

Language: Английский

Citations

14

One-step laser-induced Cu-embedded graphene for non-enzymatic glucose sensing in beverages DOI
Yanke Zhang, Chi Zhang, Wei Chen

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 992, P. 174563 - 174563

Published: April 21, 2024

Language: Английский

Citations

12

Modification-free bionic superhydrophobic laser-induced graphene (LIG) wearable strain sensor with superior anti-icing performance DOI
Liyong Wang,

Jinlei Hu,

Xiaodong Zhou

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161140 - 161140

Published: Feb. 1, 2025

Language: Английский

Citations

1