MetalMat,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 1, 2024
Abstract
The
use
of
green
renewable
energy
to
convert
carbon
dioxide
(CO
2
)
into
valuable
chemicals
and
fuels
through
CO
electrolysis
technology
(also
known
as
electrochemical
reduction
reaction,
eCO
RR)
is
an
advantageous
technology,
which
could
greatly
aid
the
global
carbon‐neutral
goal.
Although
progress
has
been
made
in
alkaline/neutral
media,
low
conversion
efficiency
target
products,
carbonate/bicarbonate
salt
precipitation,
blockage
electrode
holes
caused
by
are
not
conducive
industrial
applications.
Acidic
media
address
these
issues;
however,
conditions,
there
other
challenges
that
need
be
addressed,
such
hydrogen
evolution,
poor
tolerance
electrocatalysts,
electrolysers.
This
review
discusses
recent
advances
industrial‐level
acidic
electrolysis,
including
reaction
mechanisms,
device
design,
aiming
promote
its
commercialization.
In
addition,
a
comprehensive
evaluation
strategy
RR
system
proposed,
perspectives
provided
based
on
related
discussion.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(14)
Published: Feb. 7, 2024
Abstract
Rising
carbon
dioxide
(CO
2
)
levels
in
the
atmosphere
are
recognized
as
a
threat
to
atmospheric
stability
and
life.
Although
this
greenhouse
gas
is
being
produced
on
large
scale,
there
solutions
reduction
indeed
utilization
of
gas.
Many
these
involve
costly
or
unstable
technologies,
such
air‐sensitive
metal–organic
frameworks
(MOFs)
for
CO
capture
“non‐green”
systems
amine
scrubbing.
Conjugated
microporous
polymers
(CMPs)
represent
simpler,
cheaper,
greener
solution
utilization.
They
often
easy
synthesize
at
scale
(a
one
pot
reaction
many
cases),
chemically
thermally
stable
(especially
comparison
with
their
MOF
covalent
organic
framework
(COF)
counterparts,
owing
amorphous
nature),
and,
result,
cheap
manufacture.
Furthermore,
surface
areas,
tunable
porous
chemical
structures
mean
they
reported
highly
efficient
motifs.
In
addition,
provide
dual
pathway
utilize
captured
via
conversion
electrochemical
into
industrially
valuable
products.
Recent
studies
show
that
all
attractive
properties
can
be
realized
metal‐free
CMPs,
presenting
truly
green
option.
The
promising
results
two
fields
CMP
applications
reviewed
explored
here.
Carbon Energy,
Journal Year:
2024,
Volume and Issue:
6(2)
Published: Feb. 1, 2024
Abstract
Electrochemical
C–C
and
C–N
coupling
reactions
with
the
conversion
of
abundant
inexpensive
small
molecules,
such
as
CO
2
nitrogen‐containing
species,
are
considered
a
promising
route
for
increasing
value
reduction
products.
The
development
high‐performance
catalysts
is
key
to
both
electrocatalytic
reactions.
In
this
review,
we
present
systematic
summary
reaction
systems
reduction,
along
mechanisms
bonds
over
outstanding
materials
recently
developed.
intermediate
species
pathways
related
well
catalyst‐structure
relationship
will
be
also
discussed,
aiming
provide
insights
guidance
designing
efficient
systems.
Advanced Science,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 27, 2025
MXenes,
a
novel
member
of
the
2D
material
family,
shows
promising
potential
in
stabilizing
isolated
atoms
and
maximizing
atom
utilization
efficiency
for
catalytic
applications.
This
review
focuses
on
role
MXenes
as
support
single-atom
catalysts
(SACs)
various
electrochemical
reactions,
namely
hydrogen
evolution
reaction
(HER),
oxygen
(OER),
reduction
(ORR),
carbon
dioxide
(CO2RR),
nitrogen
(NRR).
First,
state-of-the-art
characterization
synthesis
methods
MXene-supported
SACs
are
discussed,
highlighting
how
unique
structure
tunable
functional
groups
enhance
performance
pristine
contribute
to
SAs.
Then,
recent
studies
different
electrocatalytic
areas
examined,
including
experimental
theoretical
studies.
Finally,
this
discusses
challenges
outlook
field
electrocatalysis.
Frontiers in Energy Research,
Journal Year:
2024,
Volume and Issue:
12
Published: March 19, 2024
Despite
the
huge
efforts
devoted
to
development
of
electrochemical
reduction
CO
2
(ECO2R)
in
past
decade,
still
many
challenges
are
present,
hindering
further
approaches
industrial
applications.
This
paper
gives
a
perspective
on
these
from
Process
Systems
Engineering
(PSE)
standpoint,
while
at
same
time
highlighting
opportunities
for
advancements
field
European
context.
The
connected
with:
coupling
processes
with
renewable
electricity
generation;
feedstock
(in
particular
);
itself;
and
different
products
that
can
be
obtained.
PSE
determine
optimal
interactions
among
components
such
systems,
allowing
educated
decision
making
designing
best
process
configurations
under
uncertainty
constrains.
opportunities,
other
hand,
stem
stronger
collaboration
between
experimental
communities,
possibility
integrating
ECO2R
into
existing
productions
process-wide
optimisation
studies,
encompassing
whole
production
cycle
chemicals
exploit
possible
synergies.
Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(35), P. 16491 - 16506
Published: Aug. 20, 2024
Herein,
a
series
of
[ONSN]-type
iron(III)
complexes
were
synthesized.
A
binary
catalytic
system
in
combination
with
iron
and
tetrabutylammonium
bromide
(TBAB)
exhibited
high
activity
for
the
synthesis
cyclic
carbonates
from
CO
