ACS Omega,
Journal Year:
2024,
Volume and Issue:
9(47), P. 46698 - 46732
Published: Nov. 14, 2024
Immobilization
of
lipases
by
physical
adsorption
improves
their
stability,
recovery,
and
reusability
in
biotechnological
processes.
The
present
review
provides
an
advanced
bibliometric
analysis
a
comprehensive
overview
research
progress
this
field.
By
searching
Web
Science,
39,575
publications
were
analyzed,
325
relevant
articles
selected.
Key
journals,
countries,
institutions,
authors
identified.
most
cited
focus
on
biofuel
production
industrial
applications.
revealed
four
themes
with
the
biofuel.
method
is
effective
when
appropriate
support
used.
Despite
decrease
patent
applications,
interest
remains
high.
Future
studies
should
optimizing
materials
exploring
new
applications
technique.
detailed
understanding
immobilization
adsorption.
Environmental Chemistry Letters,
Journal Year:
2023,
Volume and Issue:
21(4), P. 2337 - 2398
Published: May 4, 2023
Access
to
drinkable
water
is
becoming
more
and
challenging
due
worldwide
pollution
the
cost
of
treatments.
Water
wastewater
treatment
by
adsorption
on
solid
materials
usually
cheap
effective
in
removing
contaminants,
yet
classical
adsorbents
are
not
sustainable
because
they
derived
from
fossil
fuels,
can
induce
secondary
pollution.
Therefore,
biological
sorbents
made
modern
biomass
increasingly
studied
as
promising
alternatives.
Indeed,
such
biosorbents
utilize
waste
that
would
otherwise
pollute
systems,
promote
circular
economy.
Here
we
review
biosorbents,
magnetic
sorbents,
other
cost-effective
with
emphasis
preparation
methods,
types,
mechanisms,
regeneration
spent
adsorbents.
Biosorbents
prepared
a
wide
range
materials,
including
wood,
bacteria,
algae,
herbaceous
agricultural
waste,
animal
waste.
Commonly
removed
contaminants
comprise
dyes,
heavy
metals,
radionuclides,
pharmaceuticals,
personal
care
products.
Preparation
methods
include
coprecipitation,
thermal
decomposition,
microwave
irradiation,
chemical
reduction,
micro-emulsion,
arc
discharge.
Adsorbents
be
classified
into
activated
carbon,
biochar,
lignocellulosic
clays,
zeolites,
peat,
humic
soils.
We
detail
isotherms
kinetics.
Regeneration
supercritical
fluid
desorption.
also
discuss
exhausted
adsorbent
management
disposal.
found
agro-waste
remove
up
68–100%
while
wooden,
herbaceous,
bacterial,
marine-based
55–99%
metals.
Animal
waste-based
1–99%
The
average
removal
efficiency
modified
around
90–95%,
but
some
treatments,
cross-linked
beads,
may
negatively
affect
their
efficiency.
Coordination Chemistry Reviews,
Journal Year:
2024,
Volume and Issue:
514, P. 215900 - 215900
Published: May 8, 2024
Catalysis
stands
as
a
cornerstone
in
chemical
synthesis,
pivotal
advancing
sustainable
manufacturing
pathways.
The
evolution
from
energy-intensive
to
catalytic
processes
has
marked
transformative
shift,
notably
exemplified
by
low-energy
methods.
These
processes,
operating
under
milder
conditions
and
emphasizing
selectivity
recyclability,
represent
the
forefront
of
chemistry.
This
review
navigates
through
an
array
reactions,
highlighting
their
diverse
applications
culminating
exploration
recent
strides
within
processes.
For
example,
explores
uses
such
enzyme
mimicking,
biodiesel
production,
carbon
dioxide
capture,
organic
synthesis.
Additionally,
it
covers
enzymatic
catalysis
photocatalysis
for
transformations,
energy
applications,
water
treatment.
Notably,
emphasizes
capabilities
single-atom
(SAC)
diatomic
catalysts
(DACs),
recognizing
exceptional
performance
catalyzing
reactions
at
minimal
activation
energies
while
maintaining
high
efficiency
mild
conditions.
By
elucidating
modulation
electronic
structure
offering
microelectronic
perspective,
aims
elucidate
mechanisms
underlying
activity
SAC
DACs.
Emphasizing
interplay
between
coordination
chemistry
principles
efficacy,
elucidates
indispensable
role
complexes
fortifying
sustainability
these
spotlighting
fusion
with
catalysis,
this
underscore
collective
influence
shaping
landscape
production.
Environmental Chemistry Letters,
Journal Year:
2023,
Volume and Issue:
22(1), P. 373 - 418
Published: Aug. 25, 2023
Abstract
The
presence
of
pharmaceuticals
in
ecosystems
is
a
major
health
issue,
calling
for
advanced
methods
to
clean
wastewater
before
effluents
reach
rivers.
Here,
we
review
adsorption
remove
ibuprofen,
with
focus
on
ibuprofen
occurrence
and
toxicity,
adsorbents,
kinetics,
isotherms.
Adsorbents
include
carbon-
silica-based
materials,
metal–organic
frameworks,
clays,
polymers,
bioadsorbents.
Carbon-based
adsorbents
allow
the
highest
from
10.8
408
mg/g
activated
carbon
2.5–1033
biochar.
Metal–organic
frameworks
appear
promising
due
their
high
surface
areas
tunable
properties
morphology.
95%
published
reports
reveal
that
kinetics
follow
pseudo-second-order
model,
indicating
predominantly
governed
by
chemical
adsorption.
70%
disclose
Langmuir
model
describes
isotherm,
suggesting
involves
monolayer
International Journal of Green Energy,
Journal Year:
2023,
Volume and Issue:
21(6), P. 1383 - 1397
Published: Aug. 4, 2023
ABSTRACTEnergy
is
the
linchpin
for
economic
development
despite
its
generation
deficit
worldwide.
Hydrogen
can
be
used
as
an
alternative
energy
source
to
meet
requirement
that
it
emits
zero
near-zero
impurities
and
safe
environment
humans.
Because
of
growing
greenhouse
gas
emissions
fast-expanding
usage
renewable
sources
in
power
production
recent
years,
interest
hydrogen
resurging.
may
utilized
a
storage,
stabilizing
entire
system
assisting
decarbonization
system,
particularly
industrial
transportation
sectors.
The
main
goal
this
study
describe
several
methods
producing
based
on
principal
utilized.
Moreover,
financial
ecological
outcomes
three
key
colors
(gray,
blue,
green)
are
discussed.
Hydrogen's
future
prosperity
heavily
reliant
technology
advancement
cost
reductions,
along
with
objectives
related
legislation.
This
research
might
improved
by
developing
new
methods,
novel
storage
systems,
infrastructure,
carbon-free
generation.KEYWORDS:
energyGrey,
green
hydrogengreenhouse
gasecological
outcomescarbon-free
AcknowledgementsThe
authors
would
like
thank
Energy
Conversion
Laboratory
at
Department
Petroleum
Mining
Engineering
Jashore
University
Science
Technology,
Jashore,
Bangladesh
completing
review
work.Disclosure
statementNo
potential
conflict
was
reported
author(s).Nomenclature
ISO=International
organization
standardization.RES=Renewable
sourceHCF=Hydrogen
content
factorGF=Greenization
factorEIF=Environmental
impact
factorGHG=Greenhouse
gasesLCA=Life
cycle
assessmentHPP=Hydrogen
pathwaysCCS=Carbon
capture
storageSOFC=Solid
oxide
fuel
cellCCS=Carbon
sequestration
(environmental
impact)GWP=Global
warming
potentialAP=Acidification
potentialLCIA=Life
assessingLHV=Lower
heating
valueHHV=Higher
valueH2=HydrogenCO2=Carbon
dioxideCESAR=Canada
systems
analysis
researchCCUS=Carbon
use
storageSMR=Steam
methane
reformingHER=Hydrogen
evolution
reactionOER=Cathode
oxygen
reactionTML=Technology
maturity
levelRES=Renewable
sourcesHighlights
Grey,
blue
reviewed
energyColor
pathways
using
primary
discussedChallenges
emission
reviewedCost
prospects
discussedAdditional
informationFundingThe
work
supported
Universiti
Malaysia
Pahang
International
Publication
Grant
[Grant
No.
RDU
213305].
Environmental Chemistry Letters,
Journal Year:
2024,
Volume and Issue:
22(4), P. 1623 - 1663
Published: April 20, 2024
Abstract
The
global
hydrogen
demand
is
projected
to
increase
from
70
million
tons
in
2019
more
than
200
2030.
Methane
decomposition
a
promising
reaction
for
H
2
production,
coupled
with
the
synthesis
of
valuable
carbon
nanomaterials
applicable
fuel
cell
technology,
transportation
fuels,
and
chemical
synthesis.
Here,
we
review
catalytic
methane
decomposition,
focus
on
catalyst
development,
deactivation,
reactivation,
regeneration,
economics.
Catalysts
include
mono-,
bi-,
trimetallic
compounds
carbon-based
compounds.
Catalyst
deactivation
induced
by
coke
deposition.
Despite
remarkable
strides
research,
industrialization
remains
at
an
early
stage.